• Structural Engineering and Mechanics
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• 제53권2호
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• pp.297-309
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• 2015

The purpose of this work is to analyze the effect of structure parameter disturbance on the dynamic characteristics of a hydropower station powerhouse. A vibration model with a head-cover system is established, and then the general disturbance problem analysis methods are discussed. Two new formulae based on two types of disturbances are developed from existing methods. The correctness and feasibility of these two formulae are validated by analyzing the hydropower station powerhouse vibration model. The appropriate calculation method for disturbance of the hydropower station powerhouse vibration dynamic characteristics is derived.

• 한국기계가공학회지
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• 제13권6호
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• pp.104-110
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• 2014

This paper presents a non-contact inspection system for automatically measuring the thickness of an aircraft wing rip product. In order to conduct the inspection of the wing rib thickness automatically, a non-contact laser displacement sensor, end-effector, and a robot were selected for use. The non-contact type inspection system was evaluated by measuring the measurement deviation of the rotation direction of a C-type yoke end-effector and the transfer direction of a V-slim end-effector. In addition, the non-contact inspection system for wing rib thickness measurements was validated through thickness measurements of a web, flange, and stiffener.

• 대한안전경영과학회지
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• 제4권2호
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• pp.155-168
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• 2002

As the market and the organizations of an enterprise expand globally, the rapid and accurate communication gets more important for product manufacturing. The manufacturing information flow among the designers, the process planners and the shop floors is characterized and modelled. Its methods are constructed using distributed objects. Their introduction to the network-based CAPP system offers speed and safety for the system and makes the reconstruction and distribution of the application programs easy. The manufacturing processes are generated based on the feature information of a designed part, then the manufacturing resources are selected using the process planning logic which is implemented by distributed objects. The databases and distributed objects are integrated under the recent internet environments. The developed system makes it possible to manipulate and to transfer the process planning and manufacturing data everywhere in the world.

• 대한화학회지
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• 제34권1호
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• pp.102-107
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• 1990

Thiazoline-azetidinone(7) 화합물은 $CH_2Cl_2-H_2O$ 용매에서 요오드와 반응하면 직접 3-iodo-3-methylcepham(4)을 준다. 이 반응은 상이동 촉매를 사용하면 훨씬 빨라지며 0.1당량의 요오드를 사용하면 약산성 존건하의 가수분해 반응과 비슷하게 thiazole(10)이 주생성물이었다. 고리화 반응과 가수분해 반응차이는 사용된 요오드량 및 thiazoline-azetidinone 화합물에 따라 설명될 수 있다.

• Nuclear Engineering and Technology
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• 제50권6호
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• pp.849-853
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• 2018

Mechanistic calculations for wet scrubbing of aerosol/vapor from gas bubble rising in liquid pool are essential to safety of sodium-cooled fast reactor. Hence, scrubbing of volatile fission product from mixed gas bubble rising in sodium pool is presented in this study. To understand this phenomenon, a theoretical model has been setup based on classical theories of aerosol/vapor removal from bubble rising through liquid pools. The model simulates pool scrubbing of sodium iodide aerosol and cesium vapor from a rising mixed gas bubble containing xenon as the inert species. The scrubbing of aerosol and vapor are modeled based on deposition mechanisms and Fick's law of diffusion, respectively. Studies were performed to determine the effect of various key parameters on wet scrubbing. It is observed that for higher vapor diffusion coefficient in gas bubble, the scrubbing efficiency is higher. For aerosols, the cut-off size above which the scrubbing efficiency becomes significant was also determined. The study evaluates the retention capability of liquid sodium used in sodium-cooled fast reactor for its safe operation.

• 한국가금학회지
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• 제7권1호
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• pp.13-22
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• 1980

On the Chicago Meracntile Exchange, individuals and firms buy and sell contracts for specified amounts of products that are to be delivered at a time period in the future at a price arrived at through openly competitive bidding. The transfer of ownership of these delivery promises takes place in a particular trading pit, for each commodity, on the floor of the Exchange. Trades are officially made by qualified members of the Exchange who act as brokers for their customers. For his services, the broker is paid a nominal round- turn commission fee by the customer. Although each commodity contract carefully describes the particular standards that product must meet in order to be a acceptable for delivery, actually fewer than three percent of the contracts traded are consummated by delivery. For the most part, contract obligations ions art offset, and thereby liquids. before the termination of the delivery month. The trader liquidates his position in the market after analyzing price trends, his timing, and his calculated price objectives. (omitted)

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2013년도 추계학술대회 논문집
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• pp.519-524
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• 2013

The purpose of this study is that developing the index which evaluate sound quality of door latch and improving its sound quality through that results. For that, various operating sound of door latch was used for jury test. Loudness and sharpness related metrics are dominant in sound quality index we developed. This research investigate the main transfer path of its operating sound through sound field visualization and get conclusion that could reduce the impact sound of door latch. Therefore, we could verify sound quality improvement of modified product by using sound quality index.

• Bulletin of the Korean Chemical Society
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• 제15권10호
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• pp.896-900
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• 1994

The pH-dependent reduction behavior of N-monosubstituted-4,4'-bipyridinium ions ($RBPY^+: R=methyl(C_1)$; benzyl; n-octyl; n-dodecyl) has been investigated by electrochemical and spectroelectrochemical techniques. At acidic condition, $RBPY^+$ is protonated and the protonated species are reduced by two consecutive one-electron processes. The $2e^-$ reduced species undergoes a chemical reaction with $H^+$. The second-order rate constant $(k_H)$ of the homogeneous chemical process is $(3.7{\pm}0.3){\times}10^3M^{-1}s^{-1}$ for the two electron reduction product of $C_1BPY^+$. At high pH, the electrode reduction of $RBPY^+$ is one-step $2e^-$ transfer process with concomitant addition of $H^+$, which is confirmed by cyclic voltammetric study using a microdisk electrode.

• Bulletin of the Korean Chemical Society
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• 제15권11호
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• pp.957-961
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• 1994

Epoxidation of olefins catalyzed by iron-tetraarylporphyrins were studied to see the shape selectivity in the competing reaction between cis-and trans- or internal and external olefins. Cis-olefins were more reactive than trans-olefins in the competing reaction between cis-and trans-olefins. Interestingly, in the epoxidation of $cis-{\beta}-methystyrene$ by ${\alpha}{\beta}{\alpha}{\beta}$ atropisomer of Fe(III)TNPPPCl and iodosylbenzene, 27% of total product was phenylacetone. The unusually large amount of phenylacetone may be produced by hydride rearrangement of carbocationic intermediate. Regioselectivity of the reaction was also studied by using the most sterically hindered Fe(III)TTPPPCl. In the epoxidation of limonene with Fe(III)TTPPPCl, the disubstituted double bond was more reactive than trisubstituted double bond. This is in contrast to the results obtained with other iron-tetraarylporphyrins. Similar trend was also observed in the competing reaction between mono-and di-substituted olefins.

• Bulletin of the Korean Chemical Society
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• 제8권6호
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• pp.444-449
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• 1987

Solvent effects on gas phase reactions of methoxide ion with substituted ethylenes, $CH_2$ = CHR where R = CN, CHO and $NO_2$, are investigated theoretically using the AM1 method. Results show that the methoxide approaches in-plane in all reactions, but subsequently rotate out-of-plane to form tetrahedral complexes in additon reactions. All reactions of a bare methoxide are found to be exothermic, the exothermicity being the greatest in the ${\beta}$-addition, in which the excess energy is forced to be contained within the ${\beta}$-adduct rendering extreme instability. However a part of the excess energy can be removed by a solvate molecule giving a stable complex prior to the product formation. The hydride transfer processes were found to be unfavorable due to the high activation barriers. The ${\alpha}-H^+$ abstraction process from acrylonitrile becomes endothermic as a result of monosolvation of the methoxide, in agreement with experimental results.