• Title/Summary/Keyword: toxic substance

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Adsorption Characteristics of Malachite Green on Zeolite (제올라이트에 의한 말라카이트 그린의 흡착특성)

  • Lee, Jong-Jib;Um, Myeong-Heon
    • Clean Technology
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    • v.18 no.3
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    • pp.312-319
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    • 2012
  • Malachite green is used a dye but malachite green is harmful toxic substance. In this study, the adsorption characteristics of zeolite has been investigated for the adsorption of malachite green dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of malachite green by a fixed amount of zeolite have been studied in batch adsorber and fixed bed. The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 25 to $45^{\circ}C$. The estimated values of k and ${\beta}$ are 23.60-46.88, 0.225-0.347, respectively. The mechanism of the adsorption process was determined from the intraparticle diffusion model. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet concentration and initial flow rate of malachite green are increased, the corresponding adsorption breaktime appears to decrease. Breaktime increased with increasing bed height and length of adsorption zone showed similar patterns.

Statistical Optimization for Monacolin K and Yellow Pigment Production and Citrinin Reduction by Monascus purpureus in Solid-State Fermentation

  • Jirasatid, Sani;Nopharatana, Montira;Kitsubun, Panit;Vichitsoonthonkul, Taweerat;Tongta, Anan
    • Journal of Microbiology and Biotechnology
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    • v.23 no.3
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    • pp.364-374
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    • 2013
  • Monacolin K and yellow pigment, produced by Monascus sp., have each been proven to be beneficial compounds as antihypercholesterolemic and anti-inflammation agents, respectively. However, citrinin, a human toxic substance, was also synthesized in this fungus. In this research, solidstate fermentation of M. purpureus TISTR 3541 was optimized by statistical methodology to obtain a high production of monacolin K and yellow pigment along with a low level of citrinin. Fractional factorial design was applied in this study to identify the significant factors. Among the 13 variables, five parameters (i.e., glycerol, methionine, sodium nitrate, cultivation time, and temperature) influencing monacolin K, yellow pigment, and citrinin production were identified. A central composite design was further employed to investigate the optimum level of these five factors. The maximum production of monacolin K and yellow pigment of 5,900 mg/kg and 1,700 units/g, respectively, and the minimum citrinin concentration of 0.26 mg/kg were achieved in the medium containing 2% glycerol, 0.14% methionine, and 0.01% sodium nitrate at $25^{\circ}C$ for 16 days of cultivation. The yields of monacolin K and yellow pigment were about 3 and 1.5 times higher than the basal medium, respectively, whereas citrinin was dramatically reduced by 36 times.

Sterilization of Seawater for the Ballast Water Management System (선박평형수 관리시스템을 위한 해수 살균법)

  • YUN, YONGSUP;CHOI, JONGBEOM;KANG, JUN;LEE, MYEONGHOON
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.172-172
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    • 2016
  • The International Maritime Organization(IMO) adopted the International Convention for the Control and Management of Ships' Ballast Water and Sediments in 2004 to prevent the transfer of aquatic organisms via ballast water. Forty ballast water treatment systems were granted final approval. A variety of techniques have been developed for ballast water treatment including UV treatment, indirect or direct electrolysis, ozone treatment, chemical compounds and plasma-arc method. In particular, using plasma and ozone nano-bubble treatments have been attracted in the fields. However, these treatment systems have a problem such as remained toxic substance, demand for high power source, low efficiency, ets. In this paper, we present our strilization results obtained from membrane type electrolytic-reduction treatment system The core of an electrolysis unit is an electrochemical cell, which is filled with pure water and has two electrodes connected with an external power supply. At a certain voltage, which is called critical voltage, between both electrodes, the electrodes start to produce hydrogen gas at the negatively biased electrode and oxygen gas at the positively biased electrode. The amount of gases produced per unit time is directly related to the current that passes through the electrochemical cell. From the results, we could confirm the sterilization effect of bacteria such as S. aureus, E. Coli and demonstrate the mechanism of sterilization phenomena by electrolytic-reduction treatment system.

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Selection Method of Eco-friendly Finishing Materials Considering Cost Efficiency for the Aged Housing Remodeling Projects (노후 공동주택 리모델링의 경제성을 고려한 친환경 실내 마감재료 선정 방안)

  • Kim, Ki-Hyun;Kim, Kyung-Rai;Hwang, Young-Gyu
    • Korean Journal of Construction Engineering and Management
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    • v.9 no.4
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    • pp.84-91
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    • 2008
  • "Eco-friendly construction" is an emerging issue in the building industry. Main purpose of the eco-friendly construction is to sustain the health and environment of building residents and to minimize the harmful effect on their environment. Apartment residents have great concern on eco-product, since many cases are reported that Sick Building Syndrome is caused by toxic substance from building materials. Environmental performance is to meet through using the highest grade eco-friendly materials. However, generally eco-friendly materials are more expensive than normal materials, Therefore, using eco-friendly materials at public housing project is limited to economical aspect. The purpose of this paper is development of eco-friendly material selection model considered cost efficiency. The selection of Eco-friendly finishing materials and their methods are constructed to consider environmental performance level and cost index compositively. Development of eco-friendly material selection method is economic and reasonable one when public housing is constructed.

Selection Method of Eco-friendly Finishing Materials Considering Cost Efficiency for the Aged Housing Remodeling Projects (노후 공동주택 리모델링의 경제성을 고려한 친환경 실내 마감재료 선정방안)

  • Kim, Ki-Hyun;Kim, Kyung-Rai;Han, Ju-Yeoun
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.953-956
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    • 2007
  • "Eco-friendly construction"is an emerging issue in the building industry. Main purpose of the eco-friendly construction is to sustain the health and environment of building residents and to minimize the harmful effect on their environment. Apartment residents have great concern on eco-product, since many cases are reported that Sick Building Syndrome is caused by toxic substance from building materials. Environmental performance is to meet through using the highest grade eco-friendly materials. However, generally eco-friendly materials are more expensive than normal materials. Therefore using eco-friendly materials at public housing project is limited to economical aspect. The purpose of this paper is development of eco-friendly material selection model considered cost efficiency. The selection of Eco-friendly finishing materials and their methods are constructed to consider environmental performance level and cost index compositively. Development of eco-friendly material selection method is economic and reasonable one when public housing is constructed.

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Effect of Insulin, Transferrin and Platelet-Derived Growth Factor Supplemented to Synthetic Oviduct Fluid Medium on In Vitro Development of Bovine Embryos Matured and Fertilized In Vitro (합성난관배양액에 첨가된 Insulin, Transferrin 및 Platelet-Derived Growth Factor (PDGF)가 소 수정란의 체외발육에 미치는 영향)

  • 이은송
    • Journal of Embryo Transfer
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    • v.12 no.3
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    • pp.283-291
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    • 1997
  • In vitro development of bovine embryos is affected by many factors such as energy substrates, amino acids, and some growth factors. It has been reported that mRNA of insulin, PDGF and their receptors are detected in cow embryos, and that some chelating agents such as EDTA and transferrin have beneficial role on mouse and bovine embryos. The author hypothesized that insulin, transferrin arid PDGF added to a culture medium increase in vitro development of bovine embryos by chelating toxic substance(s) or increasing cell growth and metabolism. Immature oocytes from slaughtered ovaries of Holstein cows and heifers were matured for 24 hours in a TCM199 containing 10% fetal calf serum, FSH, LH and estradiol with granulosa cells in vitro. Matured oocytes were coincubated with sperm for 30 hours in a modified Tyrode's medium (IVF). Embryos cleaved to 2- to 4-cell at 30 hours after IVF were selected and cultured in a 30-$\mu$l drop of a synthetic oviduct fluid medium (SOFM) containing 0.8% BSA, Minimum Essential Medium essential and non-essential amino acids, and insulin, transferrin or PDGF for 9 days. Supplementation of a SOFM with insulin, and /or transferrin did not increase develop-mental rate to expanding and hatching blastocyst of 2- to 4-cell bovine embryos compared with control. The highest developmental rate to hatching blastocyst was shown when PDGF was added at the concentration of 10 ng /ml among the supplementing doses tested in the present study (p<0.05). Addition of PDGF without insulin to a SOFM could not increase embrye development, but combined addition of PDGF with insulin significantly increased (p<0.05) embryo development to hatching blastocyst (50%) compared with control (38%). In conclusion, insulin and PDGF supplemented to a SOFM may act synergistically and have beneficial effect on in vitro development of 2- to 4-cell bovine embryos matured and fertilized in vitro.

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Equilibrium Kinetics and Thermodynamic Parameters Studies for Eosin Yellow Adsorption by Activated Carbon (활성탄에 의한 Eosin Yellow의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3319-3326
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    • 2014
  • Eosin yellow is used a dye and colorant but it is harmful toxic substance. In this paper, batch adsorption studies were carried out for equilibrium, kinetics and thermodynamic parameters for eosin yellow adsorption by activated carbon with varying the operating variables like pH, initial concentration, contact time. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. By estimated Langmuir constant value, $R_L$=0.067-0.083, and Freundlich constant value, $\frac{1}{n}=0.237-0.267$, this process could be employed as effective treatment for removal of eosin yellow. From calculated Temkin constant, value, B=1.868-2.855 J/mol, and Dubinin-Radushkevich constant, value, E=5.345-5.735 kJ/mol, this adsorption process is physical adsorption. From kinetic experiments, the adsorption process were found to confirm to the pseudo second order model with good correlation coefficient($r^2$=0.995-0.998). The mechanism of the adsorption process was determined two step like as boundary and intraparticle diffusion.

A Study on the Spatiotemporal Characteristics of a Hazard-based Index using the Pollutant Release and Transfer Register Data (화학물질 배출·이동량 자료를 이용한 유해기반 지수의 시공간 특성 연구)

  • Kim, Shijin;Lim, Yu-ra;Bae, Hyun-Joo
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.144-154
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    • 2021
  • Objectives: This study was intended to identify hazard contribution by region, media, and chemical by calculating a hazard-based index using pollutant release and transfer register (PRTR) data. Methods: PRTR data for the period 2011 to 2016 was analyzed to examine the regional trends in toxic releases in terms of quantity and to create a corresponding hazard-based index. For the hazard-based index, the Risk-Screening Environmental Indicators (RSEI) Model was used. Results: The results of the trend analysis show that total releases decreased slightly, but health hazard levels increased consistently. According to the outcome of regional contribution analysis of the hazard-based index, Chungcheongnam-do, Jeollabuk-do and Gyeonggi-do Provinces showed a high ratio in the index for air and water release pollutants, while Gyeongsangbuk-do and Gyeongsangnam-do Provinces showed a high ratio in the index of soil release and waste transfer pollutants. Also, as a result of the analysis of the top ranked substances in the hazard-based index, it was found that chromium, cobalt and its compounds, and ethylene oxide contributed greatly to air release substances, while chromium, benzene, and lead and its compounds contributed greatly to water release substances. Conclusion: These results showed considerable disparities between total release and health hazard levels, especially in the analysis of contribution by regions and by chemical substance. Therefore, the hazard-based index should be used both to support a more comprehensive and robust approach to screening of chemicals for environmental health policy and for management.

Inhibitory Effect of Cymbopogon Citratus Ethanol Extracts on Adipogenesis in 3T3-L1 Preadipocytes (레몬그라스 에탄올 추출물의 3T3-L1 지방세포 분화 억제효과)

  • Jo, Yong Seok;Ju, Sung Min;Hwang, Keum Hee;Kim, Min Sook;Kim, Kwang Sang;Jeon, Byung Hun
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.33 no.1
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    • pp.17-24
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    • 2019
  • Cymbopogon citratus, commonly know as lemongrass, prossesses strong antioxidant, anti-tumor and anti-inflammatory properties. Howerver, its anti-obesity activity remains to be elucidated. This study investigated the effect of ethanol extract of Cymbopogon citratus on adipogenesis, and its underlying mechanism, in 3T3-L1 preadipocytes. The results demonstrated that ethanol extracts of Cymbopogon citratus effectively suppressed intercellular lipid accumulation at non-toxic concentrations, and was associated with the down-regulation of adipocyte-specific transcription factors, including $C/EBP{\alpha}$ and $PPAR{\gamma}$, and phosphorylation of $AMPK{\alpha}$. Furthermore, ethanol extracts of Cymbopogon citratus increased p21 and p21 expression, while the expression of CDK2, cyclin A and cyclin B1 was reduced. As a result, ethanol extracts of Cymbopogon citratus seems to induce G0/G1 cell cycle arrest of 3T3-L1 cells. On the other hand, ERK and Akt signaling pathways were not involved in anti-adipogenesis by ethanol extracts of Cymbopogon citratus. Taken together, theses results suggest that ethanol extracts of Cymbopogon citratus inhibits adipocyte differentiation in 3T3-L1 cells and can be used as a safe and efficient natural substance to manage anti-obesity.

Current Status of Recycling of LED Waste (LED 폐자원의 재활용 현황)

  • Lee, Duk-Hee;Shin, Dongyoon;Kim, Tae-Hyung;Lee, Chan-Gi;Park, Kyung-Soo;Lee, Ki Woong;Lee, Jaeryeong
    • Resources Recycling
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    • v.28 no.2
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    • pp.14-22
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    • 2019
  • Development of technology makes LED an economical option because of lower energy consumption and better environmental impact. Because higher consumer demand the LED market is expanding rapidly due to its environment-friendly advantages. Expansion of LED application, development of various fusion technologies, the emergence of new markets, and the large-scale expansion of markets would lead to a large volume of e-waste generation with valorization potential. Currently, most of the generated waste being that landfilled and incinerated due to the absence of technology and management system. In this paper, we review the current status of LED waste recycling and analyzes the available recycling technologies.