• Title/Summary/Keyword: toxic material

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Development of Environmental-friendly Nontoxic Flame Retardant Paint (친환경 무독성 난연도료 개발연구)

  • Do, Young-Woong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1354-1358
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    • 2008
  • Environmental-friendly nontocxic flame retardant paint which can overcomes the restriction of harmful materials for human body and environments such as Pb, Hg, Cd, $C^{+6}$, PBB/PBDE by EU and domestic Ministry of Environment was developed. Developed paint is the water-soluble organic inorganic hybrid material that VOC(volatility organic compound) discharge is low, and that human riskiness and environmental pollution is minimized not using the kinds of halogen materials. $Mg(OH)_2$, $Sb_{2}O_{3}$, and Zinc borate were used as flame retardant materials, 2% Micell and water were used as binder and solvent, respectively. Results showed the optimum activity was obtained when the ratio of those frame retardant agents($Mg(OH)_2$, $Sb_{2}O_{3}$, Zinc borate made by 1: 2: 2), binder(2% Micell) and water was 1: 0.5: 0.5.

Composition and Structure of Marine Benthic Community Regarding Conditions of Chronic Barbour Pollution

  • Fadeeva, N.P.;Bezverbnaja, I.P.;Tazaki, Kazue;Watanabe, Hiroaki;Fadeev, V.I.
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.21-30
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    • 2003
  • Seasonal fluctuations of physico-chemical and biological aspects of the environment were studied in Vladivostok harbour (Golden Horn Bay, the East Sea/Sea of Japan). The benthic community structure was described with a focus on size-spectra (bacteria, meio- and macrofauna) related with the chemical environment and chemical fluxes in sediment and to reveal their possible ecological role in the process of bioremediation of the environment. Samples from two sites with different concentrations of heavy metals (Fe, Zn, Cu, Pb, Mn, Cr, Ni Cd, Co) and petroleum hydrocarbon were assessed by a number of methods. These included plate counts of culturable bacteria, observation through a scanning electron (SEM) and transmission electron microscope (TEM). These approaches were complemented with microscopic assessments of the diversity of the benthic community. The specific communities had a limited number of species, tolerant to abnormally high levels of toxic compounds. The dominant species were presented by several sho.1-lived small polychaetes (Capitella capitata) and nematodes (Oncholaimium ramosum). The highest population density was recorded in microbenthos, in various diatoms, various physiological groups of bacteria which participate in biomineralization: marine heterotrophic bacteria, which oxidized oil, black oil in addition to groups resistant to heavy metals. They have the entire set of mechanisms for neutralizing the negative effect of those compounds, forming the detrital food web and biogeochemical circulation of material in sediments, which results in the biological self-recycling of sea basins. Macro- and meiobenthic organisms were more sensitive to a greater extent of $H_2S$ and petroleum hydrocarbons than to metal content, but the within-site rankings were the same as those achieved for microbiological analyses.

A Study on the Ventilation Schemes for Gas Leakage and Dispersion Controlling at the Backfilled Working Face in Large-Opening Underground Mine (대단면 지하광산 갱도내 뒷채움 작업장 가스유출 및 확산제어 통기방안 연구)

  • Nguyen, Vanduc;Lee, Changwoo
    • Tunnel and Underground Space
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    • v.28 no.4
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    • pp.372-386
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    • 2018
  • The air quality near the backfilled site area is significantly deteriorated during and even after the curing period of the backfill materials. Hazardous gases such as NH3 and CO2 may leak out prolongedly from the mined-out sites backfilled with the composite carbonate-based material; leakage can be observed at the underground working sites as well as on the surface. At operating mines, underground gas leakage will severely aggravate the workplace environment. The ventilation schemes should supply sufficient air to dilute the contaminated air, and control the toxic gas leakage and dispersion. This study shows the applicability of pressurization ventilation system to control gas leakage and dispersion at the backfilled underground mine site.

Effect of Corynebacterium glutamicum and Bacillus licheniformis on livestock material burial treatment (매몰된 가축 사체의 부패 촉진 및 토양 비옥화를 위한 Corynebacterium glutamicum과 Bacillus licheniformis 처리 효과)

  • Shin, You-Jeong;Heo, Geon-Young;Kim, Ju-Hyung;Kim, Bit-Na;Min, Jiho;Cho, Ho-Seong
    • Korean Journal of Veterinary Service
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    • v.40 no.1
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    • pp.53-59
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    • 2017
  • Foot and mouth disease (FMD) is highly infectious disease of cloven-hoofed animals, particularly problematic in cattle, sheep, pigs and goats for economic reasons. Last FMD outbreak in February, 2017 caused tremendous social and economical impacts. The Korean FMD policy aims to vaccinate intact animals and euthanize and bury infected animals to prevent the disease spread. However, there was a problem that the buried livestock did not decompose after several years. Therefore, the study was purposed to investigate the effect of Corynebacterium glutamicum and Bacillus licheniformis on the degradation of buried cow carcasses and on the soil condition; such as temperature, decomposition course of carcasses, composition of amino acids in the soil around carcasses, and plant root elongation to measure soil conditions. As a result, the composition of amino acids in the soil treated with C. glutamicum and B. licheniformis was generally higher than those in the untreated soil. Plant roots in soil treated with C. glutamicum and B. licheniformis grew longer than in non-treated soil. The results suggested that the toxic effect on a grave land buried with FMD infected livestock is reduced when treated with C. glutamicum and B. licheniformis in regard of odor reduction, promoted decaying process, and soil fertilization.

A Real Time Monitoring for Water Quality of River (수질자동모니터링시스템의 설치 현황과 전망)

  • Ryu, Jae-Kuen
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.1-11
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    • 2004
  • Water quality is monitored at 1,837 points which are streams and sources for water supply in Karea. The monitoring carry out the measurement of 16 parameters of pH, BOD, SS, DO and so on with once a month, and of other parameters such like heavy metal with once a quarter. But most of the monitoring is carried out uncontinuously, so it is very difficult to understand exactly the changes of water quality compared with continuous monitoring. Therefore, real time monitoring system was equipped with basic parameters such as pH, temperature, DO, turbidity and electric conductivity at 25 major sources of water supply after installation of Noryangjin and Dukdo in 1974. But the systems have some problems which cannot be considered the sampling sites to represent for water quality of stream of lake, and can be caused a change of water quality by long distance from analyzer to intake pipe. Therefore, it has carefully to evaluate selection of sample sites for real time monitoring system. Also, problems on the area has been to identify which parameters are best suited to monitoring stream of lake water and the differences, of analyzing results compared with manual analyzing. This paper presents some approaches to handle such problems, namely selection of sampling site and measurable parameters, to connect with bio-monitoring system solving a Limitation of measurable parameters, The bio-monitoring system of an early alarm that is desirable to perceive a toxic material inflow into stream can be applied to continuos water quality monitoring system effectively. Also, this paper presents to build a on line system transmitting immediately from a mobile analyzer house or container to main monitoring center the results of analyzer by a telemeter.

A Case of Non-cardiogenic Pulmonary Edema caused by Nitrogen Dioxide Poisoning after Cutting Copper Pipe with an Oxyethylene Torch (산소 에틸렌 토치로 동파이프 절단작업 후 발생한 이산화질소 중독에 의한 비심인성 폐부종 1례)

  • JeGal, Yang-Jin;Ahn, Jong-Joon;Seo, Kwang-Won;Cha, Hee-Jeong;Kwon, Woon-Jung;Kim, Yang-Ho
    • Journal of The Korean Society of Clinical Toxicology
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    • v.4 no.2
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    • pp.175-179
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    • 2006
  • Welders are exposed to a number of hazards including metal fumes, toxic gases, electricity, heat, noise, and radiation such as ultraviolet and infrared light. We encountered a patient who developed non-cardiogenic pulmonary edema within a day after cutting copper pipe with an oxyethylene torch. The patient was a 26-year-old welder. He complained of dyspnea, generalized myalgia, and febrile sensation the following morning. The patient's chest X-ray and chest CT scan showed extensively distributed and ill-defined centrilobular nodules. Both his symptoms and chest X-ray abnormalities improved spontaneously. We attributed the patient's symptoms to non-cardiogenic pulmonary edema due to nitrogen dioxide, reasoning that: 1) the pipe consisted only of copper, according to material safety data sheet (MSDS); 2) a previous report in the literature demonstrated increased nitrogen dioxide levels under similar conditions; 3) the patient's clinical course and radiologic findings were very reminiscent of non-cardiogenic pulmonary edema following accidental exposure to nitrogen dioxide.

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Effect of Chlorination on Removal of Cyanobacterial Microcystins

  • Jung, Jong-Mun;Park, Hong-Ki;Lee, You-Jung;Jung, Eun-Young;Kwon, Ki-Won;Shin, Pan-Se;Joo, Gea-Jae
    • Journal of Environmental Science International
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    • v.11 no.11
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    • pp.1157-1163
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    • 2002
  • The effective removal of microcystins by chlorination was investigated on a laboratory scale. With an initial chl.a concentration of more than 1,000 $\mu\textrm{g}$/ℓ, the required chlorine dose for the effective removal of microcystins from the raw water was more than 8.0 mg/ℓ. Whereas, a chlorine dose of 3.0 mg/ℓcould effectively remove microcystins from raw water containing a chl.a concentration of less than 1,000 $\mu\textrm{g}$/ℓ. The microcystin removal was more effective below pH 8.0, plus the optimum pH range was unrelated to the concentration of toxic algal material. Although chlorination is one of the most effective methods for reducing the toxin from blue-green algae, it causes cell lysis and toxin release. However, it was demonstrated that the released cell lysates and toxins could be effectively removed by a higher dose of the oxidant. The highest removal efficiency of dissolved microcystins(initial concentration: 280 $\mu\textrm{g}$ L$\^$-1/) was with a chlorine dose of 5.0 mg/ℓ.

Factors associated with Respiratory Usage of Manufacturing Workers Based on the Reasoned Action Theory (이성적 행동이론에 의한 제조업 근로자들의 호흡보호구착용에 영향을 주는 요인분석)

  • Koh, Sang Baek;Chang, Sei Jin;Cho, Young Bong;Choi, Hong Ryul;An, Jae Soon;Heo, Jeong Cheol;Wang, Seung Ho;Park, Ki Woo;Lee, Wang Ro;Cha, Bong Suk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.10 no.2
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    • pp.27-39
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    • 2000
  • Objectives : The purpose of this study is to analyze the factors associated with respirator usage on the basis of reasoned action theory. Methods : The data were collected from August 1 to September 30 1999, and study subjects consisted of 303 workers who were employed in the manufacturing industries. A self-administered questionnaire was used to measure the attitude, subjective norm and related factors. Results : In bivariate analysis, the variables related to protector usage were prevention of occupational disease, protection of toxic material, disturbance during working, troublesome of usage, proper exchange of protector. Multivariate logit analysis was used to estimate factors associated with respirator usage. Significant predictors that are related to respirator usage were attitude toward the behavior, size of industry and proper exchange of protector. Conclusions : The results suggest that it is strongly required to focus on attitude toward the behavior in order to improve workers' usage of respirator.

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Single Oral Dose Toxicity Studies of Polycan, β-Glucan Originated from Aureobasidium in Mice

  • Lee, Hyeung-Sik;Yang, Kun-Ju;Shin, Hyun-Dong;Park, Bok-Ryeon;Son, Chang-Woo;Jang, Hee-Jeong;Park, Dong-Chan;Jung, Young-Mi;Ku, Sae-Kwang
    • Toxicological Research
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    • v.21 no.4
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    • pp.361-365
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    • 2005
  • This study was conducted to obtain the acute information of the oral dose toxicity of Polycan - originated from Aureobasidium pullulans SM-2001 (half of the dry material is -1,3/1,6-glucans), a UV induced mutant of A. pullulans, having various pharmacological effects, in male and female mice. In order to calculate $50\%$ lethal dose $(LD_{50})$, approximate LD and target organs, test article was administered twice by oral gavage to male and female ICR mice at total 1000, 500 and 250mg/kg. The mortality and changes on body weight, clinical signs and gross observation were monitored during 14 days after dosing. As the results, we could not find any mortalities, clinical signs, changes in the body weight and gross findings. The results obtained in this study suggest that the Polycan is non-toxic in mice and is therefore likely to be safe for clinical use. The L050 and approximate $(LD_{50})$ in mice after single oral dose of Polycan were considered over 1000 mg/kg, respectively.

Optimization of CdS buffer layers for $Cu_2ZnSnSe_4$ thin-film applications ($Cu_2ZnSnSe_4$ 태양전지의 적용을 위한 최적화 된 CdS 버퍼층 연구)

  • Kim, Gee-Yeong;Jeong, Ah-Reum;Jo, William
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.400-403
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    • 2012
  • $Cu_2ZnSnSe_4$(CZTSe) is emerged as a promising material for thin-film solar cells because of non-toxic, inexpensive and earth abundant more than $Cu(In,Ga)Se_2$ materials. For fabricating compound semiconductor thin-film solar cells, CdS is widely used for a buffer layer which fabricated by a chemical bath deposition method (CBD). Through the experiment, we controlled deposition temperature and mol ratio of solution conditions to find the proper grain 크기 and exact composition. The optimum CdS layers were characterized in terms of surface morphology by using a scanning electron microscope (SEM) and atomic force microscope (AFM). The optimized CdS layer process was applied on CZTSe thin-films. The thickness of buffer layer related with device performance of solar cells which controlled by deposition time. Local surface potential of CdS/CZTSe thin-films was investigated by Kelvin probe force microscopy (KPFM). From these results, we can deduce local electric properties with different thickness of buffer layer on CZTSe thin-films. Therefore, we investigated the effect of CdS buffer layer thickness on the CZTSe thin-films for decreasing device losses. From this study, we can suggest buffer layer thickness which contributes to efficiencies and device performance of CZTSe thin-film solar cells.

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