• Title/Summary/Keyword: toxic load

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Electrochemical Reduction Process for Pyroprocessing (파이로프로세싱을 위한 전해환원 공정기술 개발)

  • Choi, Eun-Young;Hong, Sun-Seok;Park, Wooshin;Im, Hun Suk;Oh, Seung-Chul;Won, Chan Yeon;Cha, Ju-Sun;Hur, Jin-Mok
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.279-288
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    • 2014
  • Nuclear energy is expected to meet the growing energy demand while avoiding CO2 emission. However, the problem of accumulating spent fuel from current nuclear power plants which is mainly composed of uranium oxides should be addressed. One of the most practical solutions is to reduce the spent oxide fuel and recycle it. Next-generation fuel cycles demand innovative features such as a reduction of the environmental load, improved safety, efficient recycling of resources, and feasible economics. Pyroprocessing based on molten salt electrolysis is one of the key technologies for reducing the amount of spent nuclear fuel and destroying toxic waste products, such as the long-life fission products. The oxide reduction process based on the electrochemical reduction in a LiCl-$Li_2O$ electrolyte has been developed for the volume reduction of PWR (Pressurized Water Reactor) spent fuels and for providing metal feeds for the electrorefining process. To speed up the electrochemical reduction process, the influences of the feed form for the cathode and the type of anode shroud on the reduction rate were investigated.

Optimal Hydraulic Loading for Ammonia Control in Water Recycling Fish Culture System (순환여과식 양어장의 암모니아 제어를 위한 최적 수리학적 부하)

  • LEE Suk-Mo;KIM Do-Hee;SONG Kyo-Ouk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.3
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    • pp.176-180
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    • 1992
  • Nitrification Is an important facet of water recycling fish culture system, because the toxic cation ammonia is converted to the innocuous anion nitrate. This study was attempted to find the optimal design factor of submerged filter for ammonia removal in water recycling fish culture system. The experimental system was designed submerged filter with corrugated skylight plate, and operated in the fish farm, National Fisheries University of Pusan. When the influent ammonia concentration was about 10mg/l (9.43-13.66mg/l) nitrification rates were tested for the removal of ammonia over a four stage of the hydraulic loadings. The submerged filter removed 76.24, 62.88, 39.09 and $9.20\%$ of the ammonia to hydraulic load of 0.028, 0.037, 0.056 and $0.111m^3/m^2$. day, respectively. We can apply the above data to the material balance on the ammonia concentration in a fish reservoir, and conclude that the maximum allowable ammonia production was 1.52mg/min, and the optimal hydraulic loading was $0.047m^3/m^2$\;\cdot day$, in order to maintain the ammonia concentration below 10mg/l in the fish reservoir.

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Plume Behavior Study of Green FLP-106 ADN Thruster Using DSMC Method (직접모사법을 이용한 친환경 FLP-106 ADN 추력기의 배기가스 거동 연구)

  • Kuk, Jung Won;Lee, Kyun Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.47 no.9
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    • pp.649-657
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    • 2019
  • Hydrazine, which is used as a representative monopropellant, is an extremely poisonous substance and has a disadvantage that it is harmful to the human body and is very difficult to handle. In recent years, research on the development of non-toxic and environmentally friendly propellants has attracted much attention. Ammonium dinitramide(ADN) based propellant developed by Swedish Space Corporation has superior performance to hydrazine and has been commercialized through performance verification in space environment. On the other hand, the exhaust gas from a thruster nozzle collides with a satellite while it is spreading in the vacuum space, thermal load and surface contamination may occur and may reduce the performance and lifetime of the satellite. However, a study on the effect of the exhaust gas of the green propellant thruster on the satellite has not been conducted in earnest yet. Therefore, the exhaust gas behavior in space was analyzed in this study for the ADN based green monopropellant using Navier-Stokes equations and the DSMC method. As a result, it can be expected to be used as design validation data in the development of satellite when using the ADN based green monopropellant.

Estimation of Pollutant EMCs and Loadings in Highway Runoff (국내 고속도로 강우 유출수의 EMCs 및 유출 부하량 산정)

  • Kim, Lee-Hyung;Ko, Seok-Oh;Lee, Byung-Sik;Kim, Sunggil
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.2B
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    • pp.225-231
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    • 2006
  • The nonpoint source control is based on TPLMS (Total Pollution Load Management System) program. Recently, the Ministry of Environment in Korea has programed TPLMS for 4 major large rivers to improve the water quality in rivers by controling the total pollutant loadings from the watershed area. Usually the urbanization is the main pollutant sources, particularly for nonpoint pollutants, because of high imperviousness and high pollutant mass emissions. The stormwater runoff from urban areas is containing various pollutants such as sediments, metals and toxic chemicals due to human and vehicle activities. Of the various landuses, the highways are highly polluted landuses because of high pollutant accumulation rate by vehicle activities during dry periods. Therefore, this research is achieved to provide pollutant EMCs (Event Mean Concentrations) and mass loadings washed-off from highways during rainfall periods. Five monitoring locations were equipped with an automatic rainfall gage and an flow meter. The results show that the EMC ranges for 95% confidence intervals in highway land use are 45.52-125.76 mg/L for TSS, 52.04-95.48 mg/L for COD, 1.77-4.48 mg/L for TN, 0.29-0.54 mg/L for TP. The ranges of washed- off mass loading are $712.7-2,418.4mg/m^2$ for TSS and $684.1-1,779.6mg/m^2$ for COD.

Effect of intravenous deferoxamine in multiply transfused patients (대량 수혈을 받은 환아들에서 정맥 투여한 deferoxamine의 효과)

  • Oh, Sang Min;Kang, Joon Won;Kim, Sun Young
    • Clinical and Experimental Pediatrics
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    • v.50 no.12
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    • pp.1225-1230
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    • 2007
  • Purpose : Multiple transfusions in patients with chronic anemia can result in excessive iron deposition in tissues and organs. Effective iron chelation therapy in chronically transfused patients can only be achieved when iron chelators remove sufficient amounts of iron equivalent to those accumulated in the body from transfusions, thus leading to maintain body iron load at a non-toxic level. This study was retrospectively carried out to investigate the effect of intravenous iron chelation therapy with deferoxamine in patients who have received multiple transfusions. Methods : From March 2005 to January 2007, 15 patients who have received multiple transfusions were included in this study. Transfusion dependent patients were defined as those receiving >1 packed red blood cell (RBC) units/month for at least 6 months. They received intravenous deferoxamine for 7 days (10-30 mg/kg/day, 24 hour continuous infusions). Before and after deferoxamine infusions and 3 months later, we compared serum iron, TIBC, and ferritin in transfusion dependent patients and transfusion independent patients. Results : There were 6 males and 9 females and their age range was 5.6-21.3 (median 8.3) years. Transfusion dependent patients were 7 and 8 were transfusion independent states after stem cell transplantation or chemotherapy. There was no significant change in ferritin level after deferoxamine treatment for the transfusion dependent patients but significant falling of ferritin level was observed for the transfusion independent patients 3 months later compared with baseline ferritin level (P=0.046). Some adverse events were observed but symptoms were mild and tolerable. Conclusion : Seven days of intravenous deferoxamine was safe and effective in transfusion independent patients. In transfusion dependent patients, chelation therapy should be maintained, in order to minimize or prevent iron accumulation and storage in the tissues.