• 한국물환경학회지
• /
• 제21권5호
• /
• pp.516-519
• /
• 2005

An useful protocol coiled load duration curve methodology to estimate contaminant loading to a river on an exceedance probability scale was developed in this research. The technique was further applied to estimate total coliform loading to the Geum River, using the daily mean flow rate and total coliform concentration data during January, 1996 and July, 2004 for the Gongju where an automated monitoring station is located. Drought flow of the Gongju (=50.3 cms) was equivalent to 40% on an exceedance probability scale. Load duration curve for total coliform loading at the Gongju was constructed. Standard duration curve was constructed with the water quality criteria for the class 2 (total coliform concentration = 1000 MPN/100 mL). By plotting load duration curve with standard duration curve, it could be revealed that water quality do not meet the desired water quality for 47% on an exceedance probability scale. If linearity between flow rate and coliform concentration is assumed, it can be interpretated that water quality exceeds desired criteria when average mean flow rate is over 51 cms.

• 한국응용과학기술학회지
• /
• 제41권2호
• /
• pp.520-529
• /
• 2024

Lycium barbarum extract has a high potential to be developed as a health functional food due to the various health-promoting effects of Lycium barbarum. This study analyzed changes in nutritional and functional components depending on the extraction solvent (purified water and a mixture of purified water and alcohol) and the condition of the sample. The nutritional components (carbohydrates, protein, fat, ash), organic acids, amino acids, total phenolic compounds, and total flavonoids of the extract produced during the extraction process were analyzed. The nutritional composition and functional substances of the extracts showed some differences depending on the type of solvent and the condition of the sample. The amounts of crude protein (7.61%), crude fat (1.63%), carbohydrate (90.22%), and ash (0.54%) of dried Lycium barbarum extract using purified water as a solvent were similar to those of the powder sample extract. The highest content of citric acid was 4.31 mg/mL, similar to the case of acetic acid, when the powder sample used a mixture of purified water and alcohol as a solvent. The highest amino acid content was 357.39 mg/mL when the powder sample was mixed with purified water and alcohol as a solvent. The total amount of phenolic compounds was 686.16 g/L when the powder sample was extracted with a mixture of purified water and alcohol as a solvent. The highest total flavonoid content was 111.32 g/L when the powder sample was extracted with a mixture of purified water and alcohol as a solvent.

• 한국환경보건학회지
• /
• 제26권4호
• /
• pp.97-104
• /
• 2000

The purpose of this is made an examination of phosphorus loading model for eutrophication response in the Yongsan lake. For the model, we measured the total amount of nutrients derived from the Yongsan river watershed, inflow rate to the Yongsan lake, water quality, and water budget from January to December in 1999. The total amount of precipitation in the Yongsan river watershed was 4,951.7$\times$10$^{6}$ ㎥/y and inflow amount was 2,569.7$\times$10$^{6}$ ㎥/y, therefore the outflow rate of the Yongsan river watershed was 51.9%. The develop loading of total nitrogen was 86,928.1kg/d and that of total phosphorus was 22,007.6kg/d at the Yongsan river watershed, But, as the inflow loading of total nitrogen was 33,962kg/d and the inflow loading of total phosphorus was 2,218kg/d to the Yongsan lake. so each infolw rate was 39.0% and 10.1%. The hydraulic residence time was 34days, total phosphorus loading [L(P)] on the surface area was 23.398g/㎥/y, the hydraulic load( $Q_{s}$) of inflow water was 74.269m/y, the reserve rate of phosphorus in the lake was 0.359, and the settinh velocity of phosphorus was 0.114m/d at the Yongsan lake. Mathematical model of phosphorus loading to estimate the responses of eutrophication at the Yongsan lake is [ $P_{j}$] = 0.838 [L(P)/Q.(1+√ $T_{w}$)$^{-1}$ ] . ] . .

• 한국물환경학회지
• /
• 제32권6호
• /
• pp.670-699
• /
• 2016

In this study, 16 antibiotics were selected from among the top 30 veterinary antibiotics sold in South Korea in 2014, as well as from among the pharmaceuticals targeted by EPA method 1694, in order to review analytical methods for the detection of trace levels of antibiotics in environmental samples: surface water, soils, animal origin foods, and manures. LC-MS/MS was heavily used. In the chromatography for the detection of the selected antibiotics, the $C_{18}$ column was mostly used at the temperature of $30{\sim}40^{\circ}C$. Water and methanol/acetonitrile were commonly chosen as a nonpolar and a polar mobile phase, respectively. Gradient elution was applied to separate multiclass antibiotics. Volatile additives, such as formic acid, acetic acid, and ammonium acetate were mixed with the mobile phase to improve the ionization efficiency of analytes and the sensitivity in MS detection. Electrospray ionization (ESI) was widely used in the LC-MS/MS and positive ionization was preferred to determine the selected antibiotics. A protonated $[M+H]^+$ molecule was selected as a precursor ion, and its two transitions were analyzed, one for quantitative measurement and the other for confirmation. This study reviewed linearity of the calibration curve, recovery, repeatability, method detection limits (MDLs), and method quantification limits (MQLs) for each target compound used to validate the developed analytical methods.

• 한국물환경학회지
• /
• 제32권6호
• /
• pp.600-627
• /
• 2016

Korea is one of the countries with a large veterinary antibiotics market, although antimicrobial resistance in bacteria is becoming a serious issue in many countries. The Korean government started to take interest in estimating the effects of livestock manure on rivers and agricultural soils and in monitoring of heavy metals, organic pollutants and antibiotics in the ambient water and soil. In this paper, pre-treatment methods to separate the selected antibiotics from solid samples were reviewed. It is essential to select an efficient and appropriate procedure for pre-treatment due to the high proportion of proteins and organics in biosolid samples. Pre-treatment consists of extraction followed by clean-up. Initially, homogenized samples were extracted by sonication, mechanical agitation or pressurized liquid extraction with methanol/acetonitrile/water mixture under acidic/basic conditions depending on the compound. However, aminoglycosides and colistin were extracted with 5% trichloroacetic acid and HCl, respectively. Since the ${\beta}-lactams$ are easily decomposed in acidic and basic conditions, they were extracted in neutral pH. Filtration with a membrane (pore size, $0.2{\mu}m$) or solid phase extraction with HLB and methanol, as eluents, was normally applied for the clean-up. At least, three different pre-treatment procedures should be adopted to screen all the selected antibiotics in solid samples.

• 한국물환경학회지
• /
• 제31권6호
• /
• pp.637-643
• /
• 2015

This study has been carried out to provide the basic data obtained from the evaluation of the variation of water quality around the Chudong intake tower in Daechung resevoir, which may be able to help the establishment of a pure water supply policy. Five sites around the Chudong intake tower were selected, and the average data for recent ten years(from year 2004 to year 2013) were analysed. The average water quality around Chudong intake tower are as followed; pH 7.5, DO 8.7 mg/L, BOD 1.0 mg/L, COD 3.0 mg/L, SS 3.0 mg/L, TN 1.495 mg/L, TP 0.017 mg/L, and Chlorophyll-a 6.5 mg/m³ were matched the good class by comparing with the living environment standard of reservoir. COD values of higher than 3.0 mg/L after July were likely due to non-point pollutants and algae outbreak during rainy summer season. Total phosphorus rose sharply in the summer season, and then algae watch was issued consistently for average 40 days. Total nitrogen to total phosphorus ratio was average 90, and it is important to control the inflow phosphrous from small stream for proper management to block an algae growth according to eutrophication. It was recommended to operate the algae removing boats around intake tower from July to October, and was required advanced water treatment processes to remove NBD COD and bad odor and taste due to algae growth.

• 한국환경보건학회지
• /
• 제19권2호
• /
• pp.34-39
• /
• 1993

One hundred and eighty-seven water samples were collected from 23 of spring water, 2 of ground water, 1 of tap water in Pusan area and 3 of natural mineral waters. Total coliform group, fecal coliform, viable cell count and microflora were investigated to evaluate water quality of drinking water. The results were as follows: range and geometric mean value of total coliform and fecal coliform MPN's of spring water were 0~1,500/100 ml, 85/100 ml and 0~460/100 ml, 24/100 ml but coliform group was not detected in the samples of tap water and natural mineral water. Viable cell count of spring water, ground water and tap water were lower as 100 cell than the criteria for drinking water but that of natural mineral water was higher as 6.5X 10$^2$~7.4X 10$^3$ /ml. Predominant speces among the 219 strains isolated from the samples were 19.6% Aeromonas spp., 19.2% Enterobacteriaceae, 16% Acinetobacter spp. Especially, spring water and vessels were contaminated by Hafnia spp. and Providencia Spp, inhabitant of the oral cavity.

• 한국환경복원기술학회지
• /
• 제4권1호
• /
• pp.32-40
• /
• 2001

Quantifications of fish farm influences on stream water quality may provide basic informations on watershed management to reduce environmental impact due to fish farm development and to conserve stream water quality in forested watershed area. In this research stream water qualities around Mt. Paekun area were monitored seasonally and the following results were obtained. Due to the increase of pH in effluent water from the fish farm it was believed that alkalization of stream water can be accelerated by large scale development of fish farms in the forested watershed area. Negative effects on stream water quality were observed by indications of increase in electrical conductivity and temperature of effluent water from the fish farm. Decreases in physicochemical indices such as the amount of dissolved oxygen, percentage of dissolved oxygen, total amount of cation, total amount of anion and total amount of ion in effluent water from the fish farm were also negative aspects in downstream ecology. It is recommended that water purification system as well as eco-friendly fish farm design should be incorporated to large scale fish farm development plan in forested watershed area.

• 한국해양학회지
• /
• 제6권2호
• /
• pp.63-77
• /
• 1971

An year-long survey of chemical water quality for Lake Eui-am in Kang-won Province, Korea, was conducted from June 1970 to May 1971 to study the water quality and seasonal variations of productivities in relation to selected physical and chemical environmental factors. A monthly series of water samples were taken at the deepest basin of 18m depth of the lake. Water quality parameters determined were water temperature, Secchi disc reading(transparency), pH, O$\_$2/, CO$\_$2/, alkalinity, acidity, Cl, hardness, Ca, Mg, total residue, total ignitious residue, COD, BOD$\_$5/, nutrients, total-Fe, soluble Fe, Mn and Cu. On the whole, the results indicate that the chemical water quality of Lake Eui-am is high, and vary with season. The lake water is characterized that higher levels of dissolved oxygen(8.6 ml/L in mean of whole water) or percent saturation of dissolved oxygen(114%), and of nitrate nitrogen (523 $\mu\textrm{g}$/L). On the other hand, CO$\_$2/(9.6ppm), chlorides(3.5ppm), Ca(7.7ppm) Mg(2.2ppm), hardness(28.5ppm), silica(2.4ppm) and BOD$\_$5/(1.08ppm) are quite low. In terms of nutrient levels, the lake water exhibit slight signs of eutrophication. The high values for nitrate nitrogen, soluble iron and Cu of the lake water suggest that there are some imputs such as domestic and industrial discharges to the lake.

• 한국농공학회논문집
• /
• 제46권1호
• /
• pp.99-105
• /
• 2004

The present agricultural water quality standards are set by a policy goal. This is intended for water quality management of public water resources, but not for the use of water resources. These standards were not determined by considering the influence of water quality on the safety of agricultural produce and the growth, yield and quality of agricultural crops. Thus, this study was carried out to investigate the influence of irrigation water quality on the growth, yield, and grain quality of rice and acquire fundamental knowledges to set up irrigation water quality standards. The pot experiment was conducted with 4 treatments using irrigation waters with various total nitrogen concentrations (control, 1, 5, 10, 20mg/L) and replicated four times with randomized block design. The results of this study showed that plant height, number of tiller, plant dry weight, the uptake of N, P, and K, and rice protein contents tended to increase as the T-N concentration in irrigation water was increased. In addition, grain yield at T-N 20 mg/L was significantly higher than in the control, but the percentage of head rice was slightly lower due to the increase of green kernel and white belly/core kernel.