• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.251-254
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• 2007

Veneer plate was painted by the treatment with ammonium salts such as ammonium chloride (AMCR), ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP) at room temperature. The flame retardancy of painted veneer plate was investigated. The painted veneer plate shows an increased $CO/CO_2$ over virgin veneer and it was supposed to affect the toxicity to different extents. But when the ammonium salts were used as the retardant for veneer, the flame retardancy was improved due to the painted ammonium salts in the veneers. Also, the veneer plates with ammonium sulfate and ammonium chloride showed both the lower total smoke release (TSR) and lower total smoke production (TSP) than that of virgin veneer.

• Advances in environmental research
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• v.6 no.3
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• pp.189-202
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• 2017

This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.469-474
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• 2010

Wood has an essential drawback such as high combustion ability. The purpose of this paper is to examine the combustion properties of the quercus variabilis and zelkova serrata dried at room temperature. The cone calorimeter (ISO 5660-1) was used to determine the heat release rate (HRR) and fire smoke index, as well as CO/$CO_2$ production and smoke obscuration. The total heat release (THR), $140.2\;MJ/m^2$ of the quercus variabilis under an external $50\;kW/m^2$ was high in comparison with THR $85.7\;MJ/m^2$ for the zelkova serrata. Furthermore, the quercus variabilis has high total smoke production (TSP), $3.50\;m^2$ compared with TSP $0.65\;m^2$ of zelkova serrata. Thease results depend on the bulk density of tested wood species. In addition, the CO/$CO_2$ production ratio of zelkova serrata and quercus variabilis was measured as 0.053, 0.043, respectively. Also, zelkova serrata showed an increase of fire-resistance attributed to char formation compared with that of quercus variabilis.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.303-307
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• 2008

In this study, we have carried out the cone calorimeter test to examine the thermal characteristics, such as total smoke production(TSP), smoke temperature and oxygen consumption, of significant parts of above trees which are representative species of Young Dong Province of Korea. The smoke production of dead leaves and living leaves of pinus densiflora was increased rapidly at the early period of combustion. So the total smoke production of this parts was 8.3 times higher than other parts. The TSP of branches and barks of quercus dentata was 14.4 and 7.2 times higher than of pinus densiflora respectively. And also the maximum smoke temperature was about $338.35{\sim}353.25\;K$. The significant difference of oxygen consumption was not detected for dead leaves, branches and barks. However, the oxygen consumption of living leaves which have high percentage of moisture content is the lowest.

• Journal of the Korean Wood Science and Technology
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• v.43 no.2
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• pp.258-264
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• 2015

To evaluate the influence of 3A zeolite on the flame retardant properties of poplar plywood. Ammonium polyphosphate (APP) and 3A zeolite were used as flame retardants to prepare plywood samples. The combustion properties, such as heat release rate (HRR), total heat release (THR), mean CO and $CO_2$ yield, smoke production rate (SPR), and total smoke production (TSP), were characterized by a cone calorimeter. A synergistic effect was observed between 3A zeolite and APP on reducing the HRR and mean CO yield. The probable flame retardation mechanism was proposed.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.627-631
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• 2010

This study was performed to test the combustion-retardation properties of Pinus rigida-based materials by the treatment of ammonium salts. Pinus rigida plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for Pinus rigida, the flame retardancy improved due to the treated ammonium salts in the virgin Pinus rigida. However the specimen shows increasing CO over virgin Pinus rigida and It is supposed that toxicities depend on extents. Also, the specimen with ammonium sulfate showed both the lower total smoke release (TSR) and lower total smoke production (TSP) than those of virgin plate. Among the specimens, the sample treated with diammonium phosphate showed a strong inhibitory effect of combustion.

• Advances in nano research
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• v.16 no.2
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• pp.127-140
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• 2024

Upon direct/indirect exposure to flame or heat, composite structures may burn or thermally buckle. This issue becomes more important in the natural fiber-based composite structures with higher flammability and lower mechanical properties. The main goal of the present study was to obtain an optimal eco-friendly composite system with low flammability and high thermal buckling resistance. The studied composite consisted of polypropylene (PP) and short abaca fiber (AF) with eggshell powder (ESP) and halloysite clay nanotubes (HNTs) additives. An optimal base composite, consisting of 30 wt.% AF and 70 wt.% PP, abbreviated as OAP, was initially introduced based on burning rate (BR) and the Young's modulus determined by horizontal burning test (HBT) and tensile test, respectively. The effects of adding ESP to the base composite were then investigated with the same experimental tests. The results indicated that though the BR significantly decreased with the increase of ESP content up to 6 wt.%, it had a very destructive influence on the stiffness of the composite. To compensate for the damaging effect of ESP, small amount of HNT was used. The performance of OAP composite with 6 wt.% ESP and 3 wt.% HNT (OAPEH) was explored by conducting HBT, cone calorimeter test (CCT) and tensile test. The experimental results indicated a 9~23 % reduction in almost all flammability parameters such as heat release rate (HRR), total heat released (THR), maximum average rate of heat emission (MARHE), total smoke released (TSR), total smoke production (TSP), and mass loss (ML) during combustion. Furthermore, the combination of 6 wt.% ESP and 3 wt.% HNT reduced the stiffness of OAP to an insignificant amount by maximum 3%. Moreover, the char residue analysis revealed the distinct differences in the formation of char between AF/PP and AF/PP/ESP/HNT composites. Afterward, dilatometry test was carried out to examine the coefficient of thermal expansion (CTE) of OAP and OAPEH samples. The obtained results showed that the CTE of OAPEH composite was about 18% less than that of OAP. Finally, a theoretical model was used based on first-order shear deformation theory (FSDT) to predict the critical bucking temperatures of the OAP and OAPEH composite plates. It was shown that in the absence of mechanical load, the critical buckling temperatures of OAPEH composite plates were higher than those of OAP composites, such that the difference between the buckling temperatures increased with the increase of thickness. On the contrary, the positive effect of CTE reduction on the buckling temperature decreased by raising the axial compressive mechanical load on the composite plates which can be assigned to the reduction of stiffness after the incorporation of ESP. The results of present study generally stated that a suitable combination of AF, PP, ESP, and HNT can result in a relatively optimal and environmentally friendly composite with proper flame and thermal buckling resistance with no significant decline in the stiffness.