• Title/Summary/Keyword: total deposition

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Growth and Characteristics of Near-UV LED Structures on Wet-etched Patterned Sapphire Substrate

  • Cheong, Hung-Seob;Hong, Chang-Hee
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.199-205
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    • 2006
  • Patterned sapphire substrates (PSS) were fabricated by a simple wet etching process with $SiO_2$ stripe masks and a mixed solution of $H_2SO_4$ and $H_3PO_4$. GaN layers were epitaxially grown on the PSS under the optimized 2-step growth condition of metalorganic vapor deposition. During the 1st growth step, GaN layers with triangular cross sections were grown on the selected area of the surface of the PSS, and in the 2nd growth step, the GaN layers were laterally grown and coalesced with neighboring GaN layers. The density of threading dislocations on the surface of the coalesced GaN layer was $2{\sim}4\;{\times}\;10^7\;cm^{-2}$ over the entire region. The epitaxial structure of near-UV light emitting diode (LED) was grown over the GaN layers on the PSS. The internal quantum efficiency and the extraction efficiency of the LED structure grown on the PSS were remarkably increased when compared to the conventional LED structure grown on the flat sapphire substrate. The reduction in TD density and the decrease in the number of times of total internal reflections of the light flux are mainly attributed due to high level of scattering on the PSS.

Geochemistry and isotope compositions of the Han River, Korea

  • 류종식;이광식;장호완;김용제
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.435-437
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    • 2003
  • In order to investigate processes and factors controlling the chemical and isotopic compositions of the Han River, seasonal studies were carried out. The North Han River was much lower in the concentrations of total dissolved solids (TDS), dissolved inorganic carbon (DIC) and major ions than the South Han River, but higher in $SiO_2$ concentration, $\delta$$^{34}$ $S_{so4}$ value and $^{87}$ Sr/$^{86}$ Sr ratio. This indicates that the chemical and isotopic compositions of the Han River were strongly controlled by the geology of their drainage basins: silicate rocks in the North Han River and carbonate rocks in the South Han River. The $\delta$$^{34}$ $S_{so4}$ values were relatively higher in the North Han River (5.90$\pm$1.46$\textperthousand$)) than in the South Han River (3.48$\pm$0.73$\textperthousand$). This implies that dissolved S $O_{4}$$^{2-}$ in the North Han River might be mostly derived from deposition of atmospheric sulfates, whereas in the South Han River from oxidation of sulfide minerals in the abandoned poly-metallic deposits and the coal-bearing sedimentary rocks distributed over the upstream as well as deposition of atmospheric sulfates. The $^{87}$ S $r^{86}$ Sr ratios in the North Han River were distinctly higher than those in the South Han River, reflecting water-rock interaction with different rock types.pes.

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Chemical Vapor Deposition of $\beta$-SiC by Pyrolysis of MTS and Effect of Excess C Sources (MTS의 열분해를 이용한 $\beta$-SiC의 화학증착 및 Excess C 공급원의 영향)

  • 최병진;박병옥;김대룡
    • Journal of the Korean Ceramic Society
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    • v.30 no.1
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    • pp.46-54
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    • 1993
  • $\beta$-SiC was chemically vapor deposited by pyrolysis of MTS+H2 gas mixture. The experiments were conducted in the temperature range of 1100~150$0^{\circ}C$ with a r.f. induction furnace under atmospheric pressure. The IR, XRD, EDS and AES analysis revealed that the free Si was always codeposited with SiC below 140$0^{\circ}C$, regardless of the total flow rate and MTS concentration, whereas $\beta$-SiC single phase was deposited at 150$0^{\circ}C$. C3H8 or CH2Cl2 as an excess C sources, was supplied with MTS in order to obtain stoichiometric SiC at low temperature. With the addition of C3H8 or CH2Cl2, the deposition rate was increased and $\beta$-SiC single phase could be deposited even at temperature as low as 110$0^{\circ}C$. In the absence of C3H8 or CH2Cl2, the microhardness of the layer was quite low (

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ISO/TC107 - Metallic and other inorganic coatings: Involvement, Activities and Standardization

  • Gyawali, Gobinda
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.85-85
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    • 2017
  • ISO (International Organization for Standardization) is an independent, non-governmental international organization with a membership of 163 national standards bodies (NSB). The ISO standards are developed and processed within the technical committees (TC) or their subcommittees (SC) dealing with the different subject matters. The first technical committee, ISO/TC1, deals with screw threads and was created back in 1947. While, more recently, TC 309 was created to standardize organizational governance. The ISO technical committee in the field of metallic coatings was created in 1962 with the title ISO/TC107- Metallic and other inorganic coatings. This ISO/TC107 technical committee is dealing with the standardization of the characteristics of protective and decorative metallic coatings applied by electrolysis, fusion, vacuum or chemical means, mechanical deposition and ion plating. similarly, it also covers the standardization of the characteristics of protective and decorative non-metallic coatings (excluding paints and other organic coatings) on metal surface applied by electrolysis, fusion, vacuum or chemical means. Scope is further extended to the Standardization of the preparation of the substrates prior to the deposition of metallic and inorganic coatings. There are a total of 144 existing ISO standards published by this technical committee and has 19 participating countries (P-members) and 24 observing countries (O-members). Korean Agency for Technology and Standards (KATS), being the secretariat of ISO/TC107, is constantly supporting this technical committee for the development of standards and related activities.

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Effects of Input Gases on the Growth Characteristics of Vertically Aligned Carbon Nanotubes in Plasma Enhanced Hot Filament Chemical Vapor Deposition

  • Han, Jae-Hee;Yang, Ji-Hun;Yang, Won-Suk;Yang, Cheol-Woong;Yoo, Ji-Beom;Park, Chong-Yun
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.2
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    • pp.55-60
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    • 2000
  • Vertically aligned carbon nanotubes on nickel coated glass substrates were obtained at low temperatures below 600$\^{C}$ by plasma enhanced hot filament chemical vapor deposition where acetylene gas was used as the carbon source and ammonia gas was used as the dilution gas and catalyst. The diameters of the nanotubes decreased from 96 m to 41 m as NH$_3$/C$_2$H$_2$ ratio increased from 2:1 to 5:1. Total flow rate of input gases with constant NH$_3$/C$_2$H$_2$ ratio did not change the diameter of carbon nanotubes. No growth of the carbon nanotubes was observed with only C$_2$H$_2$ nor N$_2$ instead of NH$_2$. G line and D line in Raman spectra were observed, which implies that there were many structural defects in carbon nanotubes.

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Effect of Ventilation Type on the Trajectory of Coughed Particles in a Hospital Ward (실내환기 방식이 재채기 토출입자의 거동특성에 미치는 영향)

  • Kwon, Soon-Bark;Song, Ji-Han;Cho, Young-Min;Jeong, Woo-Tae;Park, Duck-Shin
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.59-67
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    • 2013
  • One of purposes in this study was to confirm the behavior of coughed particles under different ventilation conditions. Three types of ventilation systems were applied for this experiment and the properties of coughed particles were measured using computational fluid dynamics (CFD) in an intensive care unit. The changes of total airborne particles for each case showed different trends according to the ventilation type and time, but the deposited particles were similar in all conditions. Although the time taken for 50% of the particles to be deposited was the fastest in case 2, the portion of deposited particles after 300 seconds was only 5% in all conditions. In case 1, a relatively small number of particles were deposited on the wall, but the particle exhaust and deposition on the occupants were the highest. In case 3, the downward ventilation was applied as that recommended by the US Center for Disease Control and Prevention (CDC) and showed different exhaust efficiencies according to the particle size.

Neural Network Modeling of Ion Energy Impact on Surface Roughness of SiN Thin Films (신경망을 이용한 SiN 박막 표면거칠기에의 이온에너지 영향 모델링)

  • Kim, Byung-Whan;Lee, Joo-Kong
    • Journal of Surface Science and Engineering
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    • v.43 no.3
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    • pp.159-164
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    • 2010
  • Surface roughness of deposited or etched film strongly depends on ion bombardment. Relationships between ion bombardment variables and surface roughness are too complicated to model analytically. To overcome this, an empirical neural network model was constructed and applied to a deposition process of silicon nitride (SiN) films. The films were deposited by using a pulsed plasma enhanced chemical vapor deposition system in $SiH_4$-$NH_4$ plasma. Radio frequency source power and duty ratio were varied in the range of 200-800 W and 40-100%. A total of 20 experiments were conducted. A non-invasive ion energy analyzer was used to collect ion energy distribution. The diagnostic variables examined include high (or) low ion energy and high (or low) ion energy flux. Mean surface roughness was measured by using atomic force microscopy. A neural network model relating the diagnostic variables to the surface roughness was constructed and its prediction performance was optimized by using a genetic algorithm. The optimized model yielded an improved performance of about 58% over statistical regression model. The model revealed very interesting features useful for optimization of surface roughness. This includes a reduction in surface roughness either by an increase in ion energy flux at lower ion energy or by an increase in higher ion energy at lower ion energy flux.

Geochemistry of Total Gaseous Mercury in Nan-Ji-Do, Seoul, Korea (난지도 지역의 대기수은 지화학)

  • Kim, Min-Young;Lee, Gang-Woong;Shin, Jae-Young;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.21 no.5
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    • pp.611-622
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    • 2000
  • To investigate the exchange rates of mercury(Hg) across soil-air boundary, we undertook the measurements of Hg flux using gradient technique from a major waste reclamation site, Nan-Ji-Do. Based on these measurement data, we attempted to provide insights into various aspects of Hg exchange in a strongly polluted soil environment. According to our analysis, the study site turned out to be not only a major emission source area but also a major sink area. When these data were compared on hourly basis over a full day scale, large fluxes of emission and deposition centered on daytime periods relative to nighttime periods. However, when comparison of frequency with which emission or deposition occurs was made, there emerged a very contrasting pattern. While emission was dominant during nighttime periods, deposition was most favored during daytime periods. When similar comparison was made as a function of wind direction, it was noticed that there may be a major Hg source at easterly direction to bring out significant deposition of Hg in the study area. To account for the environmental conditions controlling the vertical direction of Hg exchange, we compared environmental conditions for both the whole data group and those observed from the wind direction of strong deposition events. Results of this analysis indicated that the concentrations of pollutant species varied sensitively enough to reflect the environmental conditions for each direction of exchange. When correlation analysis was applied to our data, results indicated that windspeed and ozone concentrations best reflected changes in the magnitudes of emission/deposition fluxes. The results of factor analysis also indicated the possibility that Hg emission of study area is temperature-driven process, while that of deposition is affected by a mixed effects of various factors including temperature, ozone, and non-methane HCs. If the computed emission rate is extrapolated to the whole study area we estimate that annual emission of Hg from the study area can amount to approximately 6kg.

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Environmental Mobilization Characteristics of Total Gaseous Mercury in the Western Coast of Korea During the Yellow Sand Period, 2001 (2001년 봄철 황사기간 중 서해안지역에서 관측한 대기 중 수은의 환경유동특성 연구)

  • Kim, Min-Young;Shin, Jae-Young;Cho, Suk-Choo;Kim, Joon;Lee, Gang-Woong;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.480-490
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    • 2001
  • The soil-air exchange processes of Hg were investigated from the Hari area of Kang Hwa Island during the late March 2001. In the course of our study, we determined the concentration gradients of Hg and combined these gradient data with micrometeorological components to derive its fluxes. Results of our study indicate that the concentration levels of Hg in the study area are notably lower than those typically found in urbanized areas of Korea. However, the computed fluxes were seen to be significantly larger for relatively remote areas, reaching over 200 ng/m$^2$/hr. Comparison of environmental conditions shows that the concentrations of most pollutant species including NO$_X$ and PM were significantly higher during emission, while meteorological conditions were characterized by high temperature and low humidity. Results of correlation analysis also indicate that such pollutants as hydrocarbons, nitrogen oxides, and PM generally exhibit strong positive correlations with Hg-related parameters during emission events, while such relationships were reversed during dry deposition events. The results of our present study suggest the possibility that the concentrations and fluxes of total gaseous Hg observed during deposition events can be influenced by the processes that are also important for the fine, rather than coarse, size fraction of particles.

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Seasonal Variation of $^7Be$ and $^{137}Cs$ Concentrations in Airborne Dust, Dry Fallout and Precipitation in Daejeon (대전지역 대기부유진, 낙진 및 강수 중 $^7Be$$^{137}Cs$ 방사능 농도의 계절별 변화)

  • Kim, Chang-Kyu;Lee, Seung-Chan;Lee, Dong-Myung;Rho, Byung-Hwan
    • Journal of Radiation Protection and Research
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    • v.27 no.1
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    • pp.11-19
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    • 2002
  • The seasonal variation of $^7Be$ and $^{137}Cs$ concentrations in airborne dust, precipitation and dry fallout collected at Daejeon during the period of 1998 - 1999 has been studied. The annual mean values of 7Be concentrations in airborne dust, precipitation and dry fallout were in the range of $3.80{\sim}4.29\;mBq\;m^{-3},\;1.25{\sim}1.67\;Bq\;l^{-1},\;19.7{\sim}22.3 MBq\;km^{-2}$, respectively. The annual mean values of $^{137}Cs$ concentrations in airborne dust, precipitation and dry fallout ranged $1.08{\sim}1.28{\mu}Bq\;m^{-3},\;0.44{\sim}2.66 mBq\;l^{-1}\;\;0.036{\sim}0.0455\;MBq\;km^{-2}$, respectively. While the concentrations of $^7Be$ and $^{137}Cs$ in airborne dust and dry fallout were relatively higher in the spring and autumn when the amount of dry fallout increased than in other season, their concentrations in precipitation were relatively lower in the summer when the rainfall increased. The total depositions of $^7Be$ and $^{137}Cs$ due to dry fallout and precipitation were in the range of $80.7{\sim}137MBq\;km^{-2}$ and $0.059{\sim}0.060MBq\;km^{-2}$, respectively. More than 80% of $^7Be$ deposition resulted from precipitation, whereas about 60% of $^{137}Cs$ deposition was due to dry fallout.