Effects of Input Gases on the Growth Characteristics of Vertically Aligned Carbon Nanotubes in Plasma Enhanced Hot Filament Chemical Vapor Deposition

  • Han, Jae-Hee (School of Metallurgy and Materials Engineering Sungkyunkwan University) ;
  • Yang, Ji-Hun (Department of Physics, Sungkyunkwan University) ;
  • Yang, Won-Suk (School of Metallurgy and Materials Engineering Sungkyunkwan University) ;
  • Yang, Cheol-Woong (School of Metallurgy and Materials Engineering Sungkyunkwan University) ;
  • Yoo, Ji-Beom (School of Metallurgy and Materials Engineering Sungkyunkwan University) ;
  • Park, Chong-Yun (Department of Physics, Sungkyunkwan University)
  • Published : 2000.06.01

Abstract

Vertically aligned carbon nanotubes on nickel coated glass substrates were obtained at low temperatures below 600$\^{C}$ by plasma enhanced hot filament chemical vapor deposition where acetylene gas was used as the carbon source and ammonia gas was used as the dilution gas and catalyst. The diameters of the nanotubes decreased from 96 m to 41 m as NH$_3$/C$_2$H$_2$ ratio increased from 2:1 to 5:1. Total flow rate of input gases with constant NH$_3$/C$_2$H$_2$ ratio did not change the diameter of carbon nanotubes. No growth of the carbon nanotubes was observed with only C$_2$H$_2$ nor N$_2$ instead of NH$_2$. G line and D line in Raman spectra were observed, which implies that there were many structural defects in carbon nanotubes.

Keywords