• 한국세라믹학회지
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• 제33권7호
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• pp.761-770
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• 1996

Silicon carbide (SiC) films were deposited by low pressure chemical vapor deposition (LPCVD) using MTS (CH3SICl3) in a hydrogen atmosphere onto graphite substrates. Depletion effects of reactants which usually occur in the hot wall horizaontal reactor were increased with deposition temperature and pressure. Below 50 torr of total pressure (111) plane was preferenctially grown irrespectrive of deposition temperature and deposition site. Over 50 torr of total pressure however (220) plane was preferentially deposited under 130$0^{\circ}C$ and at inlet site. The surface morphologies of SiC films were uniform at all deposition sites under low pressure but greatly changed with pressure. It shows that a facet structure which was formed above 125$0^{\circ}C$ played an important role in the changed of preferred orientation and surface roughness.

• Environmental Engineering Research
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• 제10권6호
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• pp.306-315
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• 2005

Total gas phase mercury (TGM) concentrations and event wet-only precipitation for Hg were collected for nine months (from April, 2002 to Dec., 2002) at Sterling, NY on the shoreline of Lake Ontario. TGM concentrations measured in this study ($3.02{\pm}2.14\;ng/m^3$) were in somewhat high range compared to other background sites. Using simplified quantitative transport bias analysis (SQTBA) possible sources affecting high Hg concentration in Sterling was identified, and they are coal-fired power plants located in southern NY and Pennsylvania. Wet deposition measured at Mercury Deposition Network (MDN) sites including Pt. Petre and Egbert, ON were compared with data obtained at the Sterling to estimate the total mercury wet deposition flux to Lake Ontario. The wet deposition flux was calculated to be the highest at the Sterling site ($7.94\;{\mu}g/m^2$ from April, 2002 to Dec. 2002) and the lowest at the Egbert ($3.92\;{\mu}g/m^2$), due to the both the difference in precipitation depth and Hg concentration in the precipitation. The deposition measured at the Sterling site is similar to Lake Michigan deposition of $6-14\;{\mu}g/m^2$ (converted for ninth months) measured for Lake Michigan Mass Balance Study (LMMBS).

• 한국대기환경학회지
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• 제17권1호
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• pp.19-29
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• 2001

Atmospheric concentrations of acidic pollutant were measured by the 4 stage filter pak method at Chunchon and by the 3 stage filter pack method at Seoul and Anmyon-do from January to December 1998. The sample was collected for 24 hours on every Wednesday. Concentrations of particulate matters were highest at Anmyon-do. The particulate concentration was much higher during the warm season than other seasons. While the particulate concentration was higher during the warm season, the concentration of gaseous matter was higher in winter. Dry deposition flux was calculated by using reported deposition velocities and concentration of pollutants measured in this study. The dry deposition velocities used in this study for SO$_2$, SO$_{4}^{2}$, HNO$_3$,NO$_{3}^{-}$ and NH$_3$ were 0.29, 0.15, 2.08( 2.13 only for Anmyon-do), 0.20 and 1.00cm/sec, respectively. At Chunchon, annual sulfur flux originated from dry deposition was 384 kg/$textrm{km}^2$, and the flux from wet deposition was 782kg/$textrm{km}^2$. Dry deposition of sulfur was 33% of total sulfur deposition. The annual nitrogen flux originated from dry deposition was 1,892kg/$textrm{km}^2$. And the flux from wet deposition was 1,066kg/$textrm{km}^2$. Dry deposition of nitrogen was 64% of total nitrogen deposition. Dry deposition as well as wet deposition have to be considerd in the study on acidification of environment such as soil or watershed.

• 한국환경보건학회지
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• 제32권4호
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• pp.359-372
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• 2006

In order to investigate the daily deposition characteristics of water-soluble inorganic components in airborne deposit on the Iksan, deposition samples were collected using a deposition gauge from October 16 to November 1, 2004. Deposition samples were collected using two different sampling gauges, a dry gauge and a wet gauge, respectively. To get wet the bottom of wet gauge during the sampling period, the volume of $30{\sim}50ml$ distilled ionized water was added in a wet gauge before the beginning of each deposition sampling. Deposition samples were collected twice a day and analyzed for inorganic water-soluble anions ($Cl^-,\;{NO_3}^-,\;{SO_4}^{2-}$) and cations (${NH_4}^+,\;Na^+,\;K^+,\;Mg^{2+},\;Ca^{2+}$) using ion chromatography. Qualify control and quality assurance of analytical data were checked by the data obtained from reinjection of standard solution, Dionex cross check standard solutions, and random several deposition samples, and measured data was estimated to be reliable. Considering the deposition sample volume, the sampling time, the surface area of sampling container, and the ion concentration measured, the daily deposition amounts for measured ions were calculated in $mg/m^2$. The total daily deposition amounts of all measured ions for dry and wet gauge were $7.5{\pm}2.8$ and $17.7{\pm}4.2mg/m^2$, respectively. A significant increase in deposition amount during rainfall days was observed for both wet gauge and dry gauge, having no difference of deposition amount between in wet gauge and in dry gauge. The mean deposition of all ions measured in this study were higher in wet gauge than in dry gauge because of the surface difference of the sampling container, especially for ${NH_4}^+\;and\;{SO_4}^{2-}$. The mean deposition amounts of ${NH_4}^+\;and\;{SO_4}^{2-}$ in wet gauge were found to be about 10 times and 3 times higher than those in dry gauge, while the rest of the chemical species were equal or a little higher in wet gauge than in dry gauge. Dominant species in dry gauge were ${NO_3}^-\;and\;Ca^{2+}$, accounting for 21% and 28% of the total ion deposition, whereas those in wet gauge were ${SO_4}^{2-}\;and\;{NH_4}^+$, accounting for 19% and 41% of the total ion deposition, respectively.

• 한국환경보건학회지
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• 제22권2호
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• pp.124-129
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• 1996

In order to investigate the deposition chara.cteristics of water-soluble ionic components in dustfall in Kwangju city, dustfall samples were collected by deposit jar for one year from December 1992 to November 1993. The depositjon amount of dustfall and water-soluble ionic components ($SO_4^{2-}, NO_3^-, Cl^-, NH_4^+, Na^+, Ca^{2+}, Mg^{2+}, K^+$) were measured. The total deposition amount of dustfall was 10.0 ton/$km^2$/month and showed seasonal trend of Summer and Spring > Fall and Winter. The total deposition amounts of water-soluble components showed 2.41 ton/$km^2$/month and seasonal trend of Summer > Fall > Spring > Winter. Deposition amount of $SO_4^{2-}$ was 0.99 ton/$km^2$/month which makes up 41% of water-soluble components. The deposition amounts of dustfall and watersoluble components according to the sampling points were approximately similar to each other. From this result, it can be estimated that the deposition amounts of dustfall and water-soluble components in dustfall were more influenced by the seasonal variation than the regional emission characteristics of pollution source. The content of each ionic component to the deposition amount of water-soluble components showed in order of $SO_4^{2-} > Cl^- > NH_4^+ > Na^+ > Ca^{2+} = K^+ > NO_3^- > Mg^{2+}$ respectively.

• 한국대기환경학회지
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• 제12권1호
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• pp.101-112
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• 1996

Dry and wet deposition is an impertant removal mechanism of the amobient aerosol in the atmospheric environment. Since the deposition flut provides adverse impacts on various encironmental media including aquatic and ecological system as well as human health, it is essential to quantitatively estimate the removal fluxes of many air pollutants. Thus, the purposes of this experimental study are to investigate seasonal deposition flux variations of the total dustfall and various inorganic elements in the local ambient air and then to finally estimate their dry deposition velocities. To perform the study, the total of 90 dustfall samples were collected from January, 1994 thru February, 1995 in 5 different cities of Korea including Seoul, Suwon, Daejon, Kwangju, and Kangrung. Each sample was analyzed by an AAS and an ICP to determine the quantities of the 11 inorganic elements, such as Zn, Cd, Cr, K, Na, Pb, Ca, Fe, Mn, Mi, and Cu. As results, deposition fluxes, soluble/insoluble fractions, and deposition velocities for each element were extensively investigated. The resulting dry deposition velocities of some elements in Suwon were estimated by ranges of 0.57 .sim. 0.87 cm/sec for Zn, 0.35 .sim. 0.45 cm/sec for Pb, 1.25 .sim. 3.52 cm/sec for Ca, 0.21 .sim. 0.48 cm/sec for Fe, 0.95 .sim. 9.31 cm/sec for Mn, and 2.08 cm/sec for Cu.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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• pp.42-45
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• 1992

The poly silicon thin films were prepared by solid phase crystallization at 600$^{\circ}C$ of amorphous silicon films deposited on Corning 7059 glass and (100) silicon wafer with thermally grown SiO$_2$substrate by plasma enhanced chemical vapor deposition with varying rf power, deposition temperature, total flow rate. Crystallization time, microstructure, absorption coefficients were investigated by RAMAN, XRD analysis and UV transmittance measurement. Crystallization time of amorphous silicon films was increased with increasing rf power, decreasing deposition temperature and decreasing total flow rate.

• Nuclear Engineering and Technology
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• 제26권4호
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• pp.570-577
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• 1994

The loss of water in the carbon steel balls and water region of the end shield for CANDU 6 reactor could lead to significant temperature gradient through the end shield structure which amy result in the excessive deformation. With an assumed end shield drained scenario, the heat deposition rates were calculated through the end shield associated with the central fuel channel during full power operation as an initial step to thermal stress analysis. The drained case was compared with that of water present normal case in therms of heat deposition rater and the total heating throughout the end shield regions. The compared results show that the heat deposition and the total heating remain almost the same between the two cases. It was found that the change of volume integrated flux in the end shield regions due to the loss of water contribute a negligible effect on the heat deposition in this region.

• Fisheries and Aquatic Sciences
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• 제8권3호
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• pp.167-176
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• 2005

Atmospheric deposition and riverine waters were sampled throughout a year, to estimate the loading fluxes of polycyclic aromatic hydrocarbons (PAHs) into the Masan Bay and its vicinity, Korea. Atmospheric deposition fluxes of total PAHs in the surveyed area varied from 62.2 to 464 ${\mu}g/m^2/year$. Concentration of total PAHs in water samples from six rivers ranged from 34.6 to 239 ng/L. Contribution of the carcinogenic PAHs to the total PAHs occupied $38\%$ and $50\%$ for atmospheric deposition and river waters, respectively. Atmospheric deposition fluxes and water concentrations of PAHs were slightly low or moderate to those in locations from some countries. Correspondence analysis was used to investigate the loading characteristics of PAHs according to transport routes. Atmospheric deposition samples were corresponded to higher molecular aromatics of PAHs, while riverine water samples were associated with lower molecular weight of PAHs. The results indicate that the higher-molecular-weight PAHs can be primarily transported by atmosphere deposition and the lower-molecular-weight PAHs can be mainly contaminated by riverine discharge into the Masan Bay and its vicinity. Loadings fluxes of PAHs into the Masan Bay and its vicinity were 39.2 g/day via atmosphere and 10.3 g/day via rivers, showing that atmospheric input was about 4 times higher than riverine one. Therefore, in order to minimize the contamination burden of PAHs from terrestrial sources to the Masan Bay and its vicinity, the control and management of PAHs deriving from atmosphere will be necessary.

• 산업기술연구
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• 제2권
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• pp.13-19
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• 1982

Polycrystalline silicon layers have been deposited by a chemical vapor deposition technique using $SiCl_4$, $H_2$ gas mixture on single crystal silicon substrates. In this work, the effects of depostion temperature and total flow rate on the deposition rate of polycrystalline silicon are investigated. From the experimental results it was found that the formation reaction of polycrystalline silicon was limited by surface reaction and mass transfer controlled as the deposition temperature was increased. The morphology of polycrystalline silicon layer changed from a fine structure to a coarse one as the deposition temperature was increased.