• Title/Summary/Keyword: time-varying

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Effects of Sulfuric Acid on the Synthesis of Highly Pure Calcium Borate in the Boron-Containing Brine and Bittern (붕소함유 염수와 간수로부터 고순도 calcium borate를 합성하는 반응에 황산이 미치는 영향)

  • Seo, Hyo-Jin;Kim, Myoung-Jin
    • Journal of Navigation and Port Research
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    • v.39 no.6
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    • pp.523-528
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    • 2015
  • In this study, we investigated the effects of sulfuric acid on the synthesis of calcium borate in the artificial boron-containing brine (bittern) saturated with calcium hydroxide. For the study, we attempted to synthesize calcium borate under various conditions such as reaction temperature, reaction time, and cooling temperature after heating, and then to examine the recovery and purity of the calcium borate according to the presence or absence of sulfuric acid at each condition. The XRD analysis confirmed that, regardless of the presence of sulfuric acid, the calcium borate ($Ca_2B_2O_5{\cdot}H_2O$) was synthesized, while, in the presence of sulfuric acid, the calcium sulfate ($CaSO_4{\cdot}0.5H_2O$) was produced as a by-product. In all the experiments performed by varying the reaction temperature and time, the recovery and purity of the calcium borate without sulfuric acid were observed higher than those with it. The results indicated that the addition of sulfuric acid increased the solubility of the calcium hydroxide, but the calcium sulfate produced as a by-product could decrease the recovery and purity of the calcium borate by preventing the synthesis. In this study, the artificial boron-containing brine (bittern) (500 mg-B/L) was saturated with calcium hydroxide in the absence of sulfuric acid, and then the solution was heated at $80-105^{\circ}C$ for less than 10 minutes to synthesize the calcium borate. The recovery and purity of calcium borate were measured as high as 80 % and 96 %, respectively.

A Study on the Optimal Water Supply using Virtual Drought Exercise with Hydrological Drought Index (수문학적 가뭄지수와 가상가뭄훈련에 의한 저수지의 최적 물 공급 방안 연구)

  • Seo, Hyeong-Deok;Jeong, Sang-Man;Kim, Seong-Joon;Lee, Joo-Heon
    • Journal of Korea Water Resources Association
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    • v.41 no.10
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    • pp.1045-1058
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    • 2008
  • Drought is a natural phenomena caused by long time lack of precipitation causing varying damages in several regions which increases yearly. Specifically, in 1994$\sim$1995 and 2001 severe drought occurred in almost every region of Korea. Small and medium sized water supply reservoirs exposed their bottoms and also raised considerable economic losses. In spite of this fact, damages and impacts from the drought can still be minimized by well defined drought management plans with optimal management of water supply facilities. Throughout this research, integrated drought information system is proposed to used in monitoring the drought of Korea in real time. And the expert system for the management of water supply facilities has developed using Shared Vision Model (SVM) to enable the Virtual Drought Exercise (VDE). To find a better way to manage water during drought and to develop the enhanced abilities to respond to drought, virtual drought exercise is the most effective approach and process. The proposed process of virtual drought exercise using integrated drought information system can be used as an effective tool to prepare the optimal water supply plans during the drought.

Formation of Si Nanodot by Using SiNx Thin Films (SiNx 박막을 이용한 Si Nanodot의 형성)

  • Lee, Jang Woo;Park, Ik Hyun;Shin, Byul;Chung, Chee Won
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.768-771
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    • 2005
  • The deposition of silicon nitride ($SiN_x$) thin films was carried out on $SiO_2/Si$ substrate at room temperature by reactive dc magnetron sputtering. The analysis of deposited $SiN_x$ films using x-ray photoelectron spectroscopy indicated that the composition of $SiN_x$ films was Si-rich. The deposited $SiN_x$ thin films were annealed by varying annealing temperature and time. X-ray diffraction (XRD) analysis was performed in order to examine the crystallization of Si in $SiN_x$ thin films. The optical and electrical properties of $SiN_x$ thin films were measured for the observation of Si nanodot. As a result, we observed the XRD peaks that might be the Si crystals. As the annealing time and annealing temperature increased, the photoluminescence intensity of $SiN_x$ films gradually increased. The capacitance-voltage characteristics of $SiN_x$ film measured before and after annealing indicated that the trap effect of electrons or holes occurred due to the existence Si nanodots in the $SiN_x$ thin films.

A Time Slot Assignment Scheme for Sensor Data Compression (센서 데이터의 압축을 위한 시간 슬롯 할당 기법)

  • Yeo, Myung-Ho;Kim, Hak-Sin;Park, Hyoung-Soon;Yoo, Jae-Soo
    • Journal of KIISE:Computing Practices and Letters
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    • v.15 no.11
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    • pp.846-850
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    • 2009
  • Recently, wireless sensor networks have found their way into a wide variety of applications and systems with vastly varying requirements and characteristics such as environmental monitoring, smart spaces, medical applications, and precision agriculture. The sensor nodes are battery powered. Therefore, the energy is the most precious resource of a wireless sensor network since periodically replacing the battery of the nodes in large scale deployments is infeasible. Energy efficient mechanisms for gathering sensor readings are indispensable to prolong the lifetime of a sensor network as long as possible. There are two energy-efficient approaches to prolong the network lifetime in sensor networks. One is the compression scheme to reduce the size of sensor readings. When the communication conflict is occurred between two sensor nodes, the sender must try to retransmit its reading. The other is the MAC protocol to prevent the communication conflict. In this paper, we propose a novel approaches to reduce the size of the sensor readings in the MAC layer. The proposed scheme compresses sensor readings by allocating the time slots of the TDMA schedule to them dynamically. We also present a mathematical model to predict latency from collecting the sensor readings as the compression ratio is changed. In the simulation result, our proposed scheme reduces the communication cost by about 52% over the existing scheme.

Pyrometallurgy Process for a Low Graded Gold Alloy with PbO and CaO (저품위 금합금의 PbO와 CaO를 이용한 건식 정련 공정)

  • Song, Jeongho;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.608-613
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    • 2017
  • We proposed a pyrometallurgical process to achieve gold alloy with an Au content of more than 80wt% from low grade (<35wt%) gold alloys. We performed the heat treatment at a temperature of $1200^{\circ}C$ for 5 hrs using Au35wt%-Ag5wt%-Cu60wt% gold alloys mixed with 1/2 weighed PbO and CaO flux by varying the ratio of PbO/(PbO+CaO) from 0 to 1. We investigated the change in content of the samples with energy dispersive X-ray spectroscopy (EDS) and time of flight secondary ion mass spectrometry (ToF-SIMS). The EDS results showed that the Au content increased from 35.0wt% in the PbO-only sample to 86.7wt% (in the PbO/(PbO+CaO) 1:1 sample), while the other samples achieved more that 84wt%. In addition, the 2/3 flux ratio sample showed the lowest Ag loss into the flux. In the ToF-SIMS results, the PbO only and CaO only fluxes had Au+ peak intensities of 349 and 37, respectively. Although the CaO-only flux might be more favorable considering the loss of Au into the flux, we concluded that the amount of Au lost into the flux could be ignored. Our results imply that that the pyrometallurgical process using a mixed flux is an effective hydrometallurgical process.

Development of a Coupled Eulerian-Lagrangian Finite Element Model for Dissimilar Friction Stir Welding (Coupled Eulerian-Lagrangian기법을 이용한 이종 마찰교반용접 해석모델 개발)

  • Lim, Jae-Yong;Lee, Jinho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.7-13
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    • 2019
  • This study aims to develop a FE Model to simulate dissimilar friction stir welding and to address its potential for fundamental analysis and practical applications. The FE model is based on Coupled Eulerian-Lagrangian approach. Multiphysics systems are calculated using explicit time integration algorithm, and heat generations by friction and inelastic heat conversion as well as heat transfer through the bottom surface are included. Using the developed model, friction stir welding between an Al6061T6 plate and an AZ61 plate were simulated. Three simulations are carried out varying the welding parameters. The model is capable of predicting the temperature and plastic strain fields and the distribution of void. The simulation results showed that temperature was generally greater in Mg plates and that, as a rotation speed increase, not the maximum temperature of Mg plate increased, but did the temperature of Al plate. In addition, the model could predict flash defects, however, the prediction of void near the welding tool was not satisfactory. Since the model includes the complex physics closely occurring during FSW, the model possibly analyze a lot of phenomena hard to discovered by experiments. However, practical applications may be limited due to huge simulation time.

A Model for the Optimal Mission Allocation of Naval Warship Based on Absorbing Markov Chain Simulation (흡수 마코프 체인 시뮬레이션 기반 최적 함정 임무 할당 모형)

  • Kim, Seong-Woo;Choi, Kyung-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.6
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    • pp.558-565
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    • 2021
  • The Republic of Korea Navy has deployed naval fleets in the East, West, and South seas to effectively respond to threats from North Korea and its neighbors. However, it is difficult to allocate proper missions due to high uncertainties, such as the year of introduction for the ship, the number of mission days completed, arms capabilities, crew shift times, and the failure rate of the ship. For this reason, there is an increasing proportion of expenses, or mission alerts with high fatigue in the number of workers and traps. In this paper, we present a simulation model that can optimize the assignment of naval vessels' missions by using a continuous time absorbing Markov chain that is easy to model and that can analyze complex phenomena with varying event rates over time. A numerical analysis model allows us to determine the optimal mission durations and warship quantities to maintain the target operating rates, and we find that allocating optimal warships for each mission reduces unnecessary alerts and reduces crew fatigue and failures. This model is significant in that it can be expanded to various fields, not only for assignment of duties but also for calculation of appropriate requirements and for inventory analysis.

Effects of Initial Responses in Steps for the Release Accidents of Hydrofluoric Acid (불산수용액 누출사고에 대한 초기대응 단계별 영향)

  • Choi, Jae Sik;Choi, Jae U;Shim, Ju Yong;Lee, Mu Chul
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.68-76
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    • 2021
  • As hazardous chemicals are releasing in process industries such as chemical & petro-chemical plants, the importance of initial responses has been always emphasized. However, little attention of quantitative analysis of the consequence by different initial responses during releasing of the chemicals has been done. The main objective of current paper is to investigate the effects of initial responses for the release accidents of hydrofluoric acid. For this, a simplified equation that can easily calculate the effect distance by varying concentrations of hydrofluoric acid was firstly deduced. In addition, a causal loops for the initial response steps using the system dynamics technique was constructed during release of 50% hydrofluoric acid. The effect distances according to different scenarios of the initial actions were also quantitatively analyzed by applying the simplified equation to the causal map. As a result, the highest reduction rate on the maximum effect distance was obtained with 'start time of action after leak detection' being about 87% while the lowest was 'arrival time of professional response team' being about 50%, as expected. It is expected that the results gained from the current study can be helpful as of basics of the initial response to the workplace, dealing with the hydrofluoric acid.

Cluster-based Delay-adaptive Sensor Scheduling for Energy-saving in Wireless Sensor Networks (센서네트워크에서 클러스터기반의 에너지 효율형 센서 스케쥴링 연구)

  • Choi, Wook;Lee, Yong;Chung, Yoo-Jin
    • Journal of the Korea Society for Simulation
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    • v.18 no.3
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    • pp.47-59
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    • 2009
  • Due to the application-specific nature of wireless sensor networks, the sensitivity to such a requirement as data reporting latency may vary depending on the type of applications, thus requiring application-specific algorithm and protocol design paradigms which help us to maximize energy conservation and thus the network lifetime. In this paper, we propose a novel delay-adaptive sensor scheduling scheme for energy-saving data gathering which is based on a two phase clustering (TPC). The ultimate goal is to extend the network lifetime by providing sensors with high adaptability to the application-dependent and time-varying delay requirements. The TPC requests sensors to construct two types of links: direct and relay links. The direct links are used for control and forwarding time critical sensed data. On the other hand, the relay links are used only for data forwarding based on the user delay constraints, thus allowing the sensors to opportunistically use the most energy-saving links and forming a multi-hop path. Simulation results demonstrate that cluster-based delay-adaptive data gathering strategy (CD-DGS) saves a significant amount of energy for dense sensor networks by adapting to the user delay constraints.

Learning Data Model Definition and Machine Learning Analysis for Data-Based Li-Ion Battery Performance Prediction (데이터 기반 리튬 이온 배터리 성능 예측을 위한 학습 데이터 모델 정의 및 기계학습 분석 )

  • Byoungwook Kim;Ji Su Park;Hong-Jun Jang
    • KIPS Transactions on Software and Data Engineering
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    • v.12 no.3
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    • pp.133-140
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    • 2023
  • The performance of lithium ion batteries depends on the usage environment and the combination ratio of cathode materials. In order to develop a high-performance lithium-ion battery, it is necessary to manufacture the battery and measure its performance while varying the cathode material ratio. However, it takes a lot of time and money to directly develop batteries and measure their performance for all combinations of variables. Therefore, research to predict the performance of a battery using an artificial intelligence model has been actively conducted. However, since measurement experiments were conducted with the same battery in the existing published battery data, the cathode material combination ratio was fixed and was not included as a data attribute. In this paper, we define a training data model required to develop an artificial intelligence model that can predict battery performance according to the combination ratio of cathode materials. We analyzed the factors that can affect the performance of lithium-ion batteries and defined the mass of each cathode material and battery usage environment (cycle, current, temperature, time) as input data and the battery power and capacity as target data. In the battery data in different experimental environments, each battery data maintained a unique pattern, and the battery classification model showed that each battery was classified with an error of about 2%.