• Journal of Electrochemical Science and Technology
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• 제5권4호
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• pp.115-127
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• 2014

Cd-Pb thin films were electrodeposited from a diluted chloride solution using stainless steel rotating disc electrode. The linear sweep voltammograms of the single metallic ions show that electrodeposition of these ions was mass transfer control due to the plateau observed for different rotations at concentration (50 and 200 ppm). The voltammograms of binary system elucidate that electrodeposition process always start at cathodic potential located between the potential of individual metals. Currents transients measurements, anodic linear sweep voltammetry (ALSV) and atomic force microscopy (AFM) were used to characterize the electrocryatalization process and morphology of thin films. ALSV profiles show a differentiation for the dissolution process of individual metals and binary system. Two peaks of dissolution Cd-Pb film were observed for the binary system with different metal ion concentration ratios. The model of Scharifker and Hills was used to analyze the current transients and it revealed that Cd-Pb electrocrystalization processes at low concentration is governed by three-dimensional progressive nucleation controlled by diffusion, while at higher concentration starts as a progressive nucleation then switch to instantaneous nucleation process. AFM images reveal that Cd-Pb film electrodeposited at low concentration is more roughness than Cd-Pb film electrodeposited at high concentrated solution.

• BMB Reports
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• 제28권1호
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• pp.51-56
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• 1995

Thioredoxin is a small redox protein with an active-site disulfide/dithiol, and is ubiquitous in bacteria, plants, and animals. To investigate the structure-function relationship of thioredoxin, the genes encoding Escherichia coli thioredoxin and Corynebacterium nephridii thioredoxin C3 were fused via a common restriction site in the nucleotide sequence coding for the active site of the proteins to generate two chimeric thioredoxins, designated E-C3(N to C-terminal) and C3-E. The hybrid thioredoxin genes were put under the T7 promoter and their productions were confirmed. The two hybrid thioredoxins complemented phenotypes of a thioredoxin-deficient E. coli strain. A strain containing the C3-E hybrid thioredoxin supported growth of the T7 phage, whereas a strain expressing the E-C3 hybrid thioredoxin did not. However, both hybrids supported growth of M13 phages. The two hybrid thioredoxins were also characterized in other aspects. Differences in activity between the hybrid thioredoxins were attributed to altered interactions of the N- and C-terminal domains of the molecule, which produced changes in the three-dimensional structure of the active site region.

• 대한기계학회논문집A
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• 제26권1호
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• pp.105-112
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• 2002

In recent years, the integrity of reactor Pressure Vessel(RPV) under pressurized thermal shock (PTS) accident has been treated as one of the most critical issues. Under PTS condition, the combination of thermal and mechanical stress by steep temperature gradient and internal pressure causes considerably high tensile stress at the inside of RPV wall. As a result, cracks on inner surface of RPV may experience elastic-plastic behavior which can be characterized by J-integral. In such a case, however, J-integral may possibly lose its vapidity due to the constraint effect. The degree of constraint effect is influenced by the loading mode, crack geometry and material properties. In this paper, in order to investigate the effect of clad thickness and crack geometry on constraint effect, three dimensional finite element analyses were performed for various surface cracks. Total of 27 crack geometries were analyzed and results were presented by a two-parameter characterization based on the J-integral and the f-stress.

• Structural Engineering and Mechanics
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• 제58권5호
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• pp.887-903
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• 2016

This study analyses the seismic response of a three-dimensional (3-D) rigid massless square foundation resting or embedded in a viscoelastic soil limited by rigid bedrock. The foundation is subjected to harmonic oblique seismic waves P, SV, SH and R. The key step is the characterization of the soil-foundation interaction by computing the impedance matrix and the input motion matrix. A 3-D frequency boundary element method (BEM) in conjunction with the thin layer method (TLM) is adapted for the seismic analysis of the foundation. The dynamic response of the rigid foundation is solved from the wave equations by taking into account the soil-foundation interaction. The solution is formulated using the frequency BEM with the Green's function obtained from the TLM. This approach has been applied to analyze the effect of soilstructure interaction on the seismic response of the foundation as a function of the kind of incident waves, the angles of incident waves, the wave's frequencies and the embedding of foundation. The parametric results show that the non-vertical incident waves, the embedment of foundation, and the wave's frequencies have important impact on the dynamic response of rigid foundations.

• 한국재료학회지
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• 제28권2호
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• pp.95-100
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• 2018

In this study, $ZrO_2$ ceramic ink was formulated for additive manufacturing three dimensional structure using dispenser printing technique. Ceramic ink with various $ZrO_2$ loading (30, 40, 50vol%) was prepared to evaluate their rheological properties and printability. High $ZrO_2$ loading $ZrO_2$ ceramic ink showed higher elastic modulus and improved shape retention, when the ceramic ink was printed and sintered at $1450^{\circ}C$ for 1h. Microstructural analysis of printed $ZrO_2$ objective indicated that high $ZrO_2$ loading objective showed lower porosity and smaller pore size.

• 한국자기공명학회논문지
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• 제19권1호
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• pp.49-53
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• 2015

MRA1997 is a 76-residue conserved hypothetical protein of Mycobacterium tuberculosis H37Ra, one of the most pathogenic bacterial species and the causative agent of tuberculosis. In this study, the sequence-specific backbone resonance assignment of MRA1997 was performed using NMR spectroscopy. Approximately 88.3% of the total resonances could be unambiguously assigned. By analyzing deviations of the $C{\alpha}$ and $C{\beta}$ chemical shift values, the secondary structure of MRA1997 was calculated. The result revealed that secondary structure of MRA 1997 consists of one ${\alpha}$-helix and five ${\beta}$-sheets. Our structural study will be a footstone towards the characterization of the three-dimensional structure of MRA1997.

• Smart Structures and Systems
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• 제5권6호
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• pp.663-679
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• 2009

The use of Micro-Electro-Mechanical Systems (MEMS) accelerometers in geotechnical instrumentation is relatively new but on the rise. This paper describes a new MEMS-based system for in situ deformation and vibration monitoring. The system has been developed in an effort to combine recent advances in the miniaturization of sensors and electronics with an established wireless infrastructure for on-line geotechnical monitoring. The concept is based on triaxial MEMS accelerometer measurements of static acceleration (angles relative to gravity) and dynamic accelerations. The dynamic acceleration sensitivity range provides signals proportional to vibration during earthquakes or construction activities. This MEMS-based in-place inclinometer system utilizes the measurements to obtain three-dimensional (3D) ground acceleration and permanent deformation profiles up to a depth of one hundred meters. Each sensor array or group of arrays can be connected to a wireless earth station to enable real-time monitoring as well as remote sensor configuration. This paper provides a technical assessment of MEMS-based in-place inclinometer systems for geotechnical instrumentation applications by reviewing the sensor characteristics and providing small- and full-scale laboratory calibration tests. A description and validation of recorded field data from an instrumented unstable slope in California is also presented.

• Advances in aircraft and spacecraft science
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• 제6권2호
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• pp.105-116
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• 2019

An alternative to the multilayered preforming is to use structures reinforced through-the-thickness in order to manufacture thicker and more complex pieces. Stitching technology is developed to bind dry reinforcements together or to strengthen composites in thickness performance by inserting structural yarns. Tufting process represents the simplest one-sided sewing technology and it is specifically designed for dry preform/liquid composite molding process route. Currently, the tufting technology is getting more and more interest due to its simplest and efficient process where it involves the insertion of binder threads via a single needle through the fabric. This technique of reinforcement through-the-thickness requires only one access to the preform which makes it suitable for three-dimensional structures and complex shaped textile composites. This paper aims to improve the understanding of the mechanical performance of tufted structures. An experimental study was developed, which included tensile and bending behaviours of tufted and un-tufted preforms, in order to evaluate the effect of tufting on the mechanical performance of dry preforms. The influence of the process parameters (tufting density, loop length, tufting yarns${\ldots}$) on the mechanical performance ofthe final structure is also highlighted.

• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.359-365
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• 2022

The development of efficient electron donor (or hole-transporting) molecules that can be used in various optoelectronic device fields is highly demanded. In this work, a novel class of triptycene-based three-dimensional (3D) triphenylamine (TI-TPA) derivatives with different end substituents was designed and prepared for transparent electron donor materials. Owing to the rigid 3D triptycene framework, the obtained TI-TPA derivatives had an amorphous morphology with high thermal decomposition temperature. The oxidation potential of these TI-TPA derivatives decreased as the electron donating strength of the end substituent increased. Among TI-TPA derivatives, TI-TPA-OMe exhibited the highest HOMO level (-5.31 eV) which is similar to that of Spiro-OMeTAD (-5.22 eV). In addition, TI-TPA-OMe was found to form a strong charge transfer complex with the triptycene-based acceptor TI-BQ, leading to a new absorption band at around 640 nm. These results can be applied for developing efficient electron donor materials that can mimic the advantages of the spiro-linked structure and TPA units of Spiro-OMeTAD.

• Applied Microscopy
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• 제50권
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• pp.17.1-17.9
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• 2020

Recent advances in fabrication have enabled radial-junction architectures for cost-effective and high-performance optoelectronic devices. Unlike a planar PN junction, a radial-junction geometry maximizes the optical interaction in the three-dimensional (3D) structures, while effectively extracting the generated carriers via the conformal PN junction. In this paper, we report characterizations of radial PN junctions that consist of p-type Si micropillars created by deep reactive-ion etching (DRIE) and an n-type layer formed by phosphorus gas diffusion. We use electron-beam induced current (EBIC) microscopy to access the 3D junction profile from the sidewall of the pillars. Our EBIC images reveal uniform PN junctions conformally constructed on the 3D pillar array. Based on Monte-Carlo simulations and EBIC modeling, we estimate local carrier separation/collection efficiency that reflects the quality of the PN junction. We find the EBIC efficiency of the pillar array increases with the incident electron beam energy, consistent with the EBIC behaviors observed in a high-quality planar PN junction. The magnitude of the EBIC efficiency of our pillar array is about 70% at 10 kV, slightly lower than that of the planar device (≈ 81%). We suggest that this reduction could be attributed to the unpassivated pillar surface and the unintended recombination centers in the pillar cores introduced during the DRIE processes. Our results support that the depth-dependent EBIC approach is ideally suitable for evaluating PN junctions formed on micro/nanostructured semiconductors with various geometry.