• Title/Summary/Keyword: thermoplastic materials

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Dynamic Fracture Properties of Nylon Thermoplastic Material Depending on Notch Angle with Charpy Impact Machine and Finite Element Method (유한요소법과 샤피충격시험기에 의한 노치각도에 따른 나일론 열가소성 플라스틱 재료의 파괴특성)

  • Park, Myung-Kyun;Lee, Jung-Won;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.12 no.1
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    • pp.1-6
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    • 2008
  • The notched Charpy impact test is one of the most prevalent techniques used to characterize the effect of high impulse loads on polymeric materials. In this study, a method of analysis in nylon plastic materials is suggested to evaluate the critical strain energy release rate for variation of notch angles from the Charpy impact energy measurement. Instrumented Charpy impact tester was used to extract ancillary information concerning fracture parameters in addition to total fracture properties and maximum critical load. The dynamic stress intensity factor of nylon plastic material was calculated for the ASTM Charpy specimen from the obtained maximum critical load. Also, the finite element model was developed to figure out the stress distributions for Charpy specimen with different notch angles subject to 3 point bending load which is equivalent to the load applied in the experiment.

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Effect of Coupling Agent and Fiber Loading on Mechanical Behavior of Chopped Jute Fiber Reinforced Polypropylene Composites (황마 단섬유 강화 폴리프로필렌 복합재료의 기계적 거동에 미치는 결합제 및 섬유 Loading의 영향)

  • Rasel, S.M.;Nam, G.B.;Byeon, J.M.;Kim, B.S.;Song, J.I.
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.204-210
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    • 2011
  • In this study, Jute fibers reinforced polypropylene (JFRP) composites were manufactured by injection molding technique. In order to improve the affinity and adhesion between fibers and thermoplastic matrices during manufacturing, Maleic anhydride (MA) as a coupling agent have been employed. Untreated and treated surfaces of jute fibers were characterized using SEM and Fourier transform infrared (FTIR). Physical properties like water absorption rate were studied. Tensile and flexural tests were carried out to evaluate the composite mechanical properties. Tensile test and bending test indicated that JFRP composites show higher strength and modulus than pure PP. In addition, strength and modulus were found to be influenced by the variation of MAPP content (1%, 2%, and 3%). Tensile fracture surfaces were examined using scanning electron microscope. It ensures better interfacial adhesion between fibers and matrix by increasing the percentage of MAPP.

Electromagnetic Interference Shielding Effectiveness and Mechanical Properties of MWCNT-reinforced Polypropylene Nanocomposites (다중벽 탄소나노튜브강화 폴리프로필렌 나노복합재료의 전자파 차폐효과 및 기계적 특성)

  • Yim, Yoon-Ji;Seo, Min-Kang;Kim, Hak-Yong;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.494-499
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    • 2012
  • In this work, the effect of multi-walled carbon nanotube (MWCNT) on electromagnetic interference shielding effectiveness (EMI SE) and mechanical properties of MWCNT-reinforced polypropylene (PP) nanocomposites were investigated with varying MWCNT content from 1 to 10 wt%. Electric resistance was tested using a 4-point-probe electric resistivity tester. The EMI SE of the nanocomposites was evaluated by means of the reflection and adsorption methods. The mechanical properties of the nanocomposites were studied through the critical stress intensity factor ($K_{IC}$) measurement. The morphologies were observed by scanning electron microscopy (SEM). From the results, it was found that the EMI SE was enhanced with increasing MWCNT content, which played a key factor to determine the EMI SE. The $K_{IC}$ value was increased with increasing MWCNT content, whereas the value decreased above 5 wt% MWCNT content. This was probably considered that the MWCNT entangled with each other in PP due to an excess of MWCNT.

Study on the Applicability of the Air Cushion Material for Impact Relief through Thermal Bonding of High Strength Fabrics (고강력 직물의 열융착 라미네이팅을 통한 충격 완화용 에어쿠션 소재로의 적용 가능성 검토 연구)

  • Kim, Ji Yeon;Kim, Hun Min;Min, Mun Hong
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.176-183
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    • 2020
  • In order to study wearable air cushion materials capable of responding to massive impact in high-altitude fall situation, high tenacity woven fabrics were bonded by heat only depending on various type of thermoplastic films and then mechanical properties were measured. Tensile strength, elongation, and 100% modulus measurement results for 4 types of films show that TPU-2 has higher impact resistance and easier expansion than PET-1. After thermal bonding, the combination with the highest tensile strength was a material with a TPU-2 film for nylon and a PET-2 film for PET, so there was a difference by type of fabric. The tear strength of the bonded materials were increased compared to the fabric alone, which shows that durability against damage such as tearing can be obtained through film adhesion. All of the peel strengths exceeded the values required by automobile airbags by about 5 times, and the TPU-2 bonded fabric showed the highest value. The air permeability was 0 L/dm2 /min. For both the film and the bonded material, which means tightness between the fabric and the film through thermal bonding. It is expected to be applied as a wearable air cushion material by achieving a level of mechanical properties similar to or superior to that of automobile airbags through the method of bonding film and fabric by thermal bonding.

Study of the Compressive Behavior of Polypropylene-low Glass Fiber Compound and Thermoplastic Olefin under High Strain Rate (고 변형률 속도에서 폴리프로필렌 및 열가소성 올레핀 소재의 압축 거동에 대한 연구)

  • Lee, Se-Min;Kim, Dug-Joong;Han, In-Soo;Kim, Hak-Sung
    • Composites Research
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    • v.35 no.1
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    • pp.38-41
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    • 2022
  • In this study, the strain rate dependent tensile and compressive properties of PP-LGF and TPO was investigated under the high strain rate by using the Split Hopkinson Pressure Bar (SHPB). The SHPB is the most widely used apparatus to characterize dynamic mechanical behavior of materials at high strain rates between 100 s-1 and 10,000 s-1. The SHPB test is based on the wave propagation theory which was developed to give the stress, strain and strain rate in the specimen using the strains measured in the incident and transmission bars. In addition, to verify the strain data obtained from SHPB, the specimen was photographed with a high-speed camera and compared with the strain data obtained through the Digital Image Correlation (DIC).

Thermally Conductive Polymer Composites for Electric Vehicle Battery Housing (전기자동차 배터리 하우징용 열전도성 고분자 복합재료)

  • Yoon, Yeo-Seong;Jang, Min-Hyeok;Moon, Dong-Joon;Jang, Eun-jin;Oh, Mee-Hye;Park, Joo-Il
    • Journal of the Korea Convergence Society
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    • v.13 no.4
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    • pp.331-337
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    • 2022
  • Manufactured thermoplastic composite materials to replace the metal materials used as battery housing materials for electric vehicles with lightweight materials. As the matrix material, nylon 6 which is a polymer material was used. Boron Nitrate(BN), which has high thermal conductivity, was used to provide heat dissipation performance. The heat dissipation characteristics of the thermally conductive polymer composite material according to the BN content and particle size were analyzed. The thermal conductivity value increased as the filler content increased, and composite materials particle size of 60 to 70㎛ and BN content of 50%, the thermal conductivity was 1.4 W/mK. The larger the particle size, the wider the inter-particle interface contact surface, which means that a thermal path was formed. wider the interfacial contact surface between the particles, and the thermal path was formed. A battery housing was manufactured using the manufactured thermally conductive polymer composite material, and the temperature change during charging and discharging of the cell was observed, and the possibility as a substitute material for the battery housing was confirmed.

Usefulness of Non-coplanar Helical Tomotherapy Using Variable Axis Baseplate (Variable Axis Baseplate를 이용한 Non-coplanar 토모테라피의 유용성)

  • Ha, Jin-Sook;Chung, Yoon-Sun;Lee, Ik-Jae;Shin, Dong-Bong;Kim, Jong-Dae;Kim, Sei-Joon;Jeon, Mi-Jin;Cho, Yoon-Jin;Kim, Ki-Kwang;Lee, Seul-Bee
    • The Journal of Korean Society for Radiation Therapy
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    • v.23 no.1
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    • pp.31-39
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    • 2011
  • Purpose: Helical Tomotherapy allows only coplanar beam delivery because it does not allow couch rotation. We investigated a method to introduce non-coplanar beam by tilting a patient's head for Tomotherapy. The aim of this study was to compare intrafractional movement during Tomotherapy between coplanar and non-coplanar patient's setup. Materials and Methods: Helical Tomotherapy was used for treating eight patients with intracranial tumor. The subjects were divided into three groups: one group (coplanar) of 2 patients who lay on S-plate with supine position and wore thermoplastic mask for immobilizing the head, second group (non-coplanar) of 3 patients who lay on S-plate with supine position and whose head was tilted with Variable Axis Baseplate and wore thermoplastic mask, and third group (non-coplanar plus mouthpiece) of 3 patients whose head was tilted and wore a mouthpiece immobilization device and thermoplastic mask. The patients were treated with Tomotherapy after treatment planning with Tomotherapy Planning System. Megavoltage computed tomography (MVCT) was performed before and after treatment, and the intrafractional error was measured with lateral(X), longitudinal(Y), vertical(Z) direction movements and vector ($\sqrt{x^2+y^2+z^2}$) value for assessing overall movement. Results: Intrafractional error was compared among three groups by taking the error of MVCT taken after the treatment. As the correction values (X, Y, Z) between MVCT image taken after treatment and CT-simulation image are close to zero, the patient movement is small. When the mean values of movement of each direction for non-coplanar setup were compared with coplanar setup group, X-axis movement was decreased by 13%, but Y-axis and Z-axis movement were increased by 109% and 88%, respectively. Movements of Y-axis and Z-axis with non-coplanar setup were relatively greater than that of X-axis since a tilted head tended to slip down. The mean of X-axis movement of the group who used a mouthpiece was greater by 9.4% than the group who did not use, but the mean of Y-axis movement was lower by at least 64%, and the mean of Z-axis was lower by at least 67%, and the mean of Z-axis was lower by at least 67%, and the vector was lower by at least 59% with the use of a mouthpiece. Among these 8 patients, one patient whose tumor was located on left frontal lobe and left basal ganglia received reduced radiation dose of 38% in right eye, 23% in left eye, 30% in optic chiasm, 27% in brain stem, and 8% in normal brain with non-coplanar method. Conclusion: Tomotherapy only allows coplanar delivery of IMRT treatment. To complement this shortcoming, Tomotherapy can be used with non-coplanar method by artificially tilting the patient's head and using an oral immobilization instrument to minimize the movement of patient, when intracranial tumor locates near critical organs or has to be treated with high dose radiation.

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Evaluation of Fiber Arrangement Condition of CF/PP Composites Using Electrical Resistance Measurement and Wettability (전기저항 평가법 및 접촉각을 이용한 CF/PP 복합재료 사출성형품 섬유 배열성 평가)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.15-20
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    • 2016
  • Fiber arrangement was important for fiber reinforced thermoplastic composites using injection fabrication. In this work, fiber arrangement in CF/PP was investigated to use electrical resistance (ER) method during injection times. There were 3 types of injection products of CF/PP with different ER change ratio by fiber arrangement. High ER change ratio case of injection CF/PP products had better increased tensile strength. This reason was due to the fiber arrangement of CF/PP by injection. Fractured surface and contact angle of CF/PP products were used to evaluate for injection product quality. Uniform fiber arrangement of CF/PP by injection type exhibited the uniform heat condition of melted CF/PP. Steady thermal transfer effect occurred from melted CF/PP to steel injection mold. Steady thermal transfer effect of CF/PP was transmitted to high ER change ratio of mold. Ultimately, good condition CF/PP product by injection molding method could be predicted by using ER method.

A Study on the Characteristics of Organic Insulating Materials Carbonized by a Leakage Current (누설전류에 의하여 탄화된 유기절연재료의 특성에 대한연구)

  • Park, Sang-Taek;Roh, Young-Su
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.2
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    • pp.161-167
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    • 2009
  • Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

Synthesis and Properties of Novel Flame-Retardant and Thermally Stable Poly(amideimide)s from N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino Acids and Phosphine Oxide Moiety by Two Different Methods

  • Faghihi, Khalil;Hajibeygi, Mohsen;Shabanian, Meisam
    • Macromolecular Research
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    • v.17 no.10
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    • pp.739-745
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    • 2009
  • N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g were synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride 1 with two equimolars of Lalanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e, L-2-aminobutyric acid 2f and L-histidine 2g in an acetic acid solution. Seven new poly(amide-imide)s PAIs 5a-g were synthesized through the direct polycondensation reaction of seven chiral N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g with bis(3-amino phenyl) phenyl phosphine oxide 4 by two different methods: direct polycondensation in a medium consisting of N-methyl-2-pyrrolidone (NMP)/triphenyl phosphite (TPP)/calcium chloride ($CaCl_2$/pyridine (py), and direct polycondensation in a tosyl chloride (TsCl)/pyridine (py)/N,N-dimethylformamide (DMF) system. The polymerization reaction produced a series of flame-retardant and thermally stable poly(amide-imide)s 5a-g with high yield. The resulted polymers were fully characterized by FTIR, $^1H$ NMR spectroscopy, elemental analyses, inherent viscosity, specific rotation and solubility tests. Data obtained by thermal analysis (TGA and DTG) revealed that the good thermal stability of these polymers. These polymers can be potentially utilized in flame retardant thermoplastic materials.