• Title/Summary/Keyword: thermoelectric.

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Thermoelectric Properties of PbTe Sintered Body Fabricated by Mechanical Alloying Process (기계적합금화 공정에 의해 제조된 PbTe 소결체의 열전특성)

  • 이길근;정해용;이병우
    • Journal of Powder Materials
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    • v.8 no.2
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    • pp.110-116
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    • 2001
  • Abstract To investigate the effect of mechanical alloying process to thermoelectric properties of PbTe sintered body, Pb-Te mixed powder with Pb : Te : 1 : 1 composition was mechanically alloyed using tumbler-ball mill. Thermoelectric properties of the sintered body were evaluated by measuring of the Seebeck coefficient and specific electric resistivity from the room temperature to 50$0^{\circ}C$. Sintered body of only mechanically alloyed PbTe powder showed p-type behavior at the room temperature, and occurred type transition from p-type to n-type at about 30$0^{\circ}C$. PbTe sintered body which was fabricated using heat treated powder in $H_2$ atmosphere after mechanical alloying showed stable n-type behavior under 50$0^{\circ}C$. N-type PbTe sintered body fabricated by mechanical alloying process had 4 times higher power factor than that fabricated by the melt-crushing process. Application of a mechanical alloying process to fabricate of n-type PbTe thermoelectric material seemed to be useful to increase the power factor of PbTe sintered body.

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Direct Solid State Synthesis of Zn4Sb3 by Hot Pressing and Thermoelectric Properties (열간 압축 공정에 의한 Zn4Sb3의 직접 고상 반응 합성 및 열전특성)

  • Ur Soon-Chul
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.255-260
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    • 2005
  • Direct solid state synthesis by hot pressing has been applied in order to produce high efficiency $Zn_4Sb_3$ bulk specimens. Single phase $Zn_4Sb_3$ with 98.5% of theoretical density was successfully produced by direct hot pressing of elemental powders containing 1.2 at.% excess Zn. Thermoelectric properties as a function of temperature were investigated from room temperature to 600 K and compared with results of other studies. Transport properties at room temperature were also evaluated. Thermoelectric properties of single phase $Zn_4Sb_3$ materials produced by direct synthesis were measured and are comparable to the published data. Direct solid state synthesis by hot pressing provides a promising processing route in this material.

Development of Perovskite-type Cobaltates and Manganates for Thermoelectric Oxide Modules

  • Weidenkaff, A.;Aguirre, M.H.;Bocher, L.;Trottmann, M.;Tomes, P.;Robert, R.
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.47-53
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    • 2010
  • Ceramics with perovskite-type structure are interesting functional materials for several energy conversion processes due to their flexible structure and a variety of properties. Prominent examples are electrode materials in fuel cells and batteries, thermoelectric converters, piezoelectrics, and photocatalysts. The very attractive physical-chemical properties of perovskite-type phases can be modified in a controlled way by changing the composition and crystallographic structure in tailor-made soft chemistry synthesis processes. Improved thermoelectric materials such as cobaltates with p-type conductivity and n-type manganates are developed by following theoretical predictions and tested to be applied in oxidic thermoelectric converters.

Properties of Thermoelectric Power in PbS Thin Films by Chemical Bath Deposition (화학 반응에 의한 PbS 박막의 열기전력 특성)

  • Cho, Jong-Rae;Cho, Jung-Ho;Kim, Kang-Eun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.21-24
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    • 2000
  • Properties of thermoelectric power in PbS thin films by chemical bath deposition were investigated The qualified PbS thin film was gained with the amounts of Thiourea($4-8ml/{\ell}$ ), Triethanolamine (1-2ml) and NaOH(l0ml). The molecular ratio of Pb and S was 3 : 7. Satisfied crystallization rate and deposition rate of PbS were greater at $50^{\circ}C$ than at $30^{\circ}C$. The constant of thermoelectric power in PbS was nearly $ 500uv/^{\circ}k$. The PbS thin film was changed from p-type to n-type semiconductor at around $200^{\circ}C$. In case of heat treatment at $300^{\circ}C$, the sample kept the characteristic of p-type semiconductors up to $250^{\circ}C$.

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Design and Fabrication of Laser Diode Integrated with Peltier Cooler (열전 냉각기가 집적된 레이저 다이오드)

  • 이상일;박정호
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.1
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    • pp.159-165
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    • 1995
  • A double-heterostructure mesa-stripe-geometry laser diode integrated with thermoelectric Peltier cooler has been designed and fabricated. Epi-layers have been grown by metal organic chemical vapor deposition(MOCVD) method. Peltier cooling effect has been measured for devices with a mesa width of 14$\mu$m and a cavity length of 380$\mu$m. The effects of thermoelectric cooling could be shown by measuring the optical output of the laser with the increase of the current in the thermoelectric cooler. While the input courrent of the laser was maintained at 250mA, the optical output was decreased from 4.8mW to 3.8mW due to heating, but with the thermoelectric cooler on the optical output power was recovered by more than 40%. The results show that the complicated cooling device is not needed since the cooling can be achevied by the developement of the fabrication processing.

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Study on Characteristics of Heat Exchangers Using Thermoelectric Modules (열전소자를 이용한 열교환기 특성 고찰)

  • 박용군;권동호;김성도;전재수;오범규;김상민
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.832-835
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    • 2003
  • This paper presents the investigation and development of heat exchangers incorporated with thermoelectric modules. Firstly, the characteristics of the modules themselves are evaluated with respect to the applied DC power. Then, the modules-based heat exchangers with an amplification apparatus to enhance cooling effects are designed and developed. The cooling performance of the proposed heat exchangers is experimentally investigated with respect to the magnitude and pattern of input DC power, along with cooling liquids. The results denote that the heat exchangers using thermoelectric modules can be effectively used in the field of the various cooling system.

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Hot and Cool Temperature Control of the Car-Seat Utilizing the Thermoelectric Device (열전소자를 이용한 카시트의 냉ㆍ난방 제어)

  • Choi, Hyeung-Sik;Kim, You-Shin;Jeon, hang-Hoon;Yun, Sang-Kook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.5
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    • pp.518-525
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    • 2004
  • The thermoelectric device was applied to a car seat to control the hot temperature in the summer and cold temperature in the winter. The characteristics of the device used to a car seat were analyzed. The air conditioning structure was designed to regulate the hot side of the thermoelectric device. To control the temperature of the car seat, a robust control algorithm based on the sliding mode control was applied, and a controller using one-chip microprocessor was developed. The performance of the proposed controller through experiments was shown.

Design and implementation of thermoelectric dehumidifier using pottier module (Pottier소자를 이용한 열전 제습기 설계 및 구현)

  • 장재철;양규식
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.3
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    • pp.671-679
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    • 1999
  • In this paper, humidity measurement is accomplished using humidity sensor, dehumidify is implemented using general-purpose $\mu$-processorPIC16C54 and thermoelectric module for control measured humidity and input target humidity value proportionally Pottier module product is variety kind of size and characteristic, very important drawing factor is selection necessary heat sink, which is maintain proper thermal resistance from variety kind of module also. From electronic dehumidifier is manufacture by using thermoelectric module, no sound, no vibration, low power consumption of partial space efficient dehumidify proves the validity of this system.

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Thermoelectric Properties of CoSb3-yTey Prepared by Encapsulated Induction Melting (밀폐유도용해로 제조한 CoSb3-yTey의 열전특성)

  • Kim, Mi-Jung;Shim, Woo-Seop;Ur, Soon-Chul;Kim, Il-Ho
    • Korean Journal of Materials Research
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    • v.16 no.7
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    • pp.412-415
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    • 2006
  • Te-doped $CoSb_3$ was prepared by the encapsulated induction melting, and its doping effects on the thermoelectric properties were investigated. Single phase ${\delta}-CoSb_3$ was successfully obtained by the subsequent annealing at 773 K for 24 hrs. Tellurium atoms acted as electron donors by substituting antimony atoms. Thermoelectric properties were remarkably improved by the appropriate doping. Dimensionless figure of merit was obtained to be 0.83 at 700K for the $CoSb_{2.8}Te_{0.2}$ specimen.

Thermoelectric Properties of Vacuum Hot-pressed $Ba_8Al_{16}Si_{30}$ Clathlate

  • Lee, Joo-Ho;Lee, Jung-Il;Kim, Young-Ho;Kim, Il-Ho;Jang, Kyung-Wook;Ur, Soon-Chul
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1198-1199
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    • 2006
  • Type I clathrate $Ba_8Al_{16}Si_{30}$ was produced by arc melting and hot pressing and thermoelectric properties were investigated. Negative Seebeck coefficient at all temperatures measured, which means that the majority carriers are electrons. Electrical conductivity decreased by increasing temperature and thermal conductivity was 0.012 W/cmK at room temperature and dimensionless thermoelectric figure of merit (ZT) was 0.01 at 873K.

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