Thermoelectric Properties of PbTe Sintered Body Fabricated by Mechanical Alloying Process

기계적합금화 공정에 의해 제조된 PbTe 소결체의 열전특성

  • 이길근 (부경대학교 공과대학 재료공학부) ;
  • 정해용 (부경대학교 공과대학 재료공학부) ;
  • 이병우 (부경대학교 공과대학 재료공학부)
  • Published : 2001.06.01

Abstract

Abstract To investigate the effect of mechanical alloying process to thermoelectric properties of PbTe sintered body, Pb-Te mixed powder with Pb : Te : 1 : 1 composition was mechanically alloyed using tumbler-ball mill. Thermoelectric properties of the sintered body were evaluated by measuring of the Seebeck coefficient and specific electric resistivity from the room temperature to 50$0^{\circ}C$. Sintered body of only mechanically alloyed PbTe powder showed p-type behavior at the room temperature, and occurred type transition from p-type to n-type at about 30$0^{\circ}C$. PbTe sintered body which was fabricated using heat treated powder in $H_2$ atmosphere after mechanical alloying showed stable n-type behavior under 50$0^{\circ}C$. N-type PbTe sintered body fabricated by mechanical alloying process had 4 times higher power factor than that fabricated by the melt-crushing process. Application of a mechanical alloying process to fabricate of n-type PbTe thermoelectric material seemed to be useful to increase the power factor of PbTe sintered body.

Keywords

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