• Title/Summary/Keyword: thermoelectric film

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Design of Thermoelectric Films for Micro Generators (마이크로 발전기의 열전박막 설계)

  • Kim, Hyun-Se;Lee, Yang-Lae;Lee, Kong-Hoon
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1455-1458
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    • 2007
  • In this research, a polycrystalline silicon (poly-Si) film layer for micro thermoelectric generator (TEG) was fabricated. The fabrication process of the thermoelectric poly-Si film layer is explained. The P-type and N-type poly-Si films were fabricated on a tetra ethoxy silane (TEOS) layer with a supporting Si wafer. Seebeck coefficient and electrical conductivity were measured, including the transport properties such as the hall coefficient, hall mobility and carrier concentration. The design parameters for a rapid thermal process (RTP) were decided based on the experimental results. The measured power factors of the P-type and N-type were $21.2\;{\mu}Wm^{-1}K^{-2}$ and $26.7\;{\mu}Wm^{-1}K^{-2}$, respectively.

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Thermoelectric Characteristics of Bi-Te Module with Thermal Conductivity Change (열전도율 변화에 따른 Bi-Te계 열전모듈의 열전특성)

  • Kim, Bong-Seo;Jeong, Hyun-Uk;Park, Su-Dong;Han, Dong-Hee;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2025-2027
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    • 2005
  • Thermal conductive polymer film was adopted to reduce the fracture of module during the fabrication of thermoelectric generator. We investigated the thermoelectric output power of module with the change of thickness of polymer film, direct contact and thermal-conductive grease. It is measured that thermoelectric output power is decreased with the increasing thickness of thermal-conductive polymer film. And

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A Study on the Diffusion Barrier at the p/n Junctions of $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ Thermoelectric Thin Films (열전 박막 $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ 접합에서의 확산 장벽에 관한 연구)

  • Kim, Il-Ho;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.6 no.7
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    • pp.678-683
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    • 1996
  • In the fabrication processes of thin film thermoelectrics, a subsequent annealing treatment is inevitable to reduce the defects and residual stresses introduced during the film growth, and to make the uniform carrier concentration of the film. However, the diffusion-induced atomic redistribution and the broadening of p/n junction region are expected to affect the thermoelectric properties of thin film modules. The present study intends to investigate the diffusion at the p/n junctions of thermoelectric thin films and to relate it to the property changes. The film junctions of p-type(Bi0.5Sb1.5Te3)and n-type(Bi2Te2.4Se0.6)were prepared by the flash evaporation method. Aluminum thin layer was employed as a diffusion barrier between p-and n-type films of the junction. This was found to be an effective barrier by showing a negligible diffusion into both type films. After annealing treatment, the thermoelectric properties of p/n couples with aluminum barrier layer were accordingly retained their properties without any deterioration.

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In-Plane Thermoelectric Properties of InGaAlAs Thin Film with Embedded ErAs Nanoparticles (ErAs 나노입자가 첨가된 InGaAlAs 박막의 평면정렬방향으로의 열전특성)

  • Lee, Yong-Joong
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.456-460
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    • 2011
  • Microelectromechanical systems (MEMS)-fabricated suspended devices were used to measure the in-plane electrical conductivity, Seebeck coefficient, and thermal conductivity of 304 nm and 516 nm thick InGaAlAs films with 0.3% ErAs nanoparticle inclusions by volume. The suspended device allows comprehensive thermoelectric property measurements from a single thin film or nanowire sample. Both thin film samples have identical material compositions and the sole difference is in the sample thickness. The measured Seebeck coefficient, electrical conductivity, and thermal conductivity were all larger in magnitude for the thicker sample. While the relative change in values was dependent on the temperature, the thermal conductivity demonstrated the largest decrease for the thinner sample in the measurement temperature range of 325 K to 425 K. This could be a result of the increased phonon scattering due to the surface defects and included ErAs nanoparticles. Similar to the results from other material systems, the combination of the measured data resulted in higher values of the thermoelectric figure of merit (ZT) for the thinner sample; this result supports the theory that the reduced dimensionality, such as in twodimensional thin films or one-dimensional nanowires, can enhance the thermoelectric figure of merit compared with bulk threedimensional materials. The results strengthen and provide a possible direction in locating and optimizing thermoelectric materials for energy applications.

Improvement of Thermoelectric Properties of Bismuth Telluride Thin Films using Rapid Thermal Processing (Bismuth Telluride 박막의 열전특성 개선을 위한 급속 열처리효과)

  • Kim, Dong-Ho;Lee, Gun-Hwan
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.292-296
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    • 2006
  • Effects of rapid thermal annealing of bismuth telluride thin films on their thermoelectric properties were investigated. Films with four different compositions were elaborated by co-sputtering of Bi and Te targets. Rapid thermal treatments in range of $300{\sim}400^{\circ}C$ were carried out during 10 minutes under the reducing atmosphere (Ar with 10% $H_2$). As the temperature of thermal treatment increased, carrier concentrations of films decreased while their mobilities increased. These changes were clearly observed for the films close to the stoichiometric composition. Rapid thermal treatment was found to be effective in improving the thermoelectric properties of $Bi_2Te_3$ films. Recrystallization of $Bi_2Te_3$ phase has caused the enhancement of thermoelectric properties, along with the decrease of the carrier concentration. Maximum values of Seebeck coefficient and power factor were obtained for the films treated at $400^{\circ}C$ (about $-128{\mu}V/K$ and $9{\times}10^{-4}\;W/K^2m$, respectively). With further higher temperature ($500^{\circ}C$), thermoelectric properties deteriorated due to the evaporation of Te element and subsequent disruption of film's structure.

Thermoelectric properties of La(1-x)MxCoO3(M=Sr, Ca;x=0, 0.1) ceramics for thermal sensors

  • Kang, Min-Gyu;Cho, Kwang-Hwan;Kang, Chong-Yun;Kim, Jin-Sang;Kim, Sang-Sig;Yoon, Seok-Jin
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.234-238
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    • 2009
  • We have investigated the effects of dopant on the thermoelectric properties that $La_{(1-x)}M_xCoO_3$(M=Sr, Ca;x=0, 0.1) bulk ceramics fabricated by the conventional solid state reaction method. The Seebeck coefficient of $La_{(1-x)}M_xCoO_3$(M=Sr, Ca;x=0, 0.1) bulk ceramics was measured at wide temperature range from 300 K to 673 K. The thermoelectric properties(Seebeck coefficient and electrical resistivity) depend strongly on the kinds of dopants. Sr and Ca dopant decrease the Seebeck coefficient. Density of sintered $La_{0.9}Sr_{0.1}CoO_3$ ceramic at 1523 K was 7.12 $g/cm^2$ and Seebeck coefficient was 35 ${\mu}V/K$ at 663 K. However, the electrical resistivity of the Sr doped sample was low and stable.

Fabrication of a Micro Cooler using Thermoelectric Thin Film (열전박막을 이용한 마이크로 냉각소자 제작)

  • Han, S.W.;Choi, H.J.;Kim, B.I.;Kim, B.M.;Kim, D.H.;Kim, O.J.
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1459-1462
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    • 2007
  • In general a thermoelectric cooler (TEC) consists of a series of P type and N type thermoelectric materials sandwiched between two wafers. When a DC current passes through these materials, three different effects take place; Peltier effect, Joule heating effect and heat transfer by conduction due to temperature difference between hot and cold plates. In this study we have developed a micro TEC using $Bi_2Te_3$ (N type) and $Bi_{0.5}Sb_{1.5}Te_3$ (P type) thin films. In order to improve that performance of a micro TEC, we made 10 um height TE legs using special PR only for lift-off. We measured COP (coefficient of performance) and temperature difference between hot and cold connectors with current.

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Properties of Thermoelectric Power in PbS Thin Films by Chemical Bath Deposition (화학 반응에 의한 PbS 박막의 열기전력 특성)

  • Cho, Jong-Rae;Cho, Jung-Ho;Kim, Kang-Eun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.21-24
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    • 2000
  • Properties of thermoelectric power in PbS thin films by chemical bath deposition were investigated The qualified PbS thin film was gained with the amounts of Thiourea($4-8ml/{\ell}$ ), Triethanolamine (1-2ml) and NaOH(l0ml). The molecular ratio of Pb and S was 3 : 7. Satisfied crystallization rate and deposition rate of PbS were greater at $50^{\circ}C$ than at $30^{\circ}C$. The constant of thermoelectric power in PbS was nearly $ 500uv/^{\circ}k$. The PbS thin film was changed from p-type to n-type semiconductor at around $200^{\circ}C$. In case of heat treatment at $300^{\circ}C$, the sample kept the characteristic of p-type semiconductors up to $250^{\circ}C$.

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