• 제목/요약/키워드: thermodynamics ratios

검색결과 8건 처리시간 0.015초

Effect of Stagnation Temperature on the Supersonic Flow Parameters with Application for Air in Nozzles

  • Zebbiche, Toufik;Youbi, ZineEddine
    • International Journal of Aeronautical and Space Sciences
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    • 제7권1호
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    • pp.13-26
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    • 2006
  • When the stagnation temperature of a perfect gas increases, the specific heat for constant pressure and ratio of the specefic heats do not remain constant any more and start to vary with this temperature. The gas remains perfect: its state equation remains always valid, with exception that it will be named by calorically imperfect gas. The aim of this research is to develop the relations of the necessary thermodynamics and geometrical ratios. and to study the supersonic flow at high temperature. lower than the threshold of dissociation. The results are found by the resolution of nonlinear algebraic equations and integration of complex analytical functions where the exact calculation is impossible. The dichotomy method is used to solve the nonlinear equation. and the Simpson algorithm for the numerical integration of the found integrals. A condensation of the nodes is used. Since. the functions to be integrated have a high gradient at the extremity of the interval of integration. The comparison is made with the calorifcally perfect gas to determine the error made by this last. The application is made for the air in a supersonic nozzle.

열역학법을 이용한 DNA hybridization 특성 검출 및 해석 (Detection and Analysis of DNA Hybridization Characteristics by using Thermodynamic Method)

  • 김도균;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권6호
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    • pp.265-270
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    • 2002
  • The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and application area. So, the improvement of DNA hybridization detection method is very important for the determination of this hybridization reaction. Several molecular biological techniques require accurate predictions of matched versus mismatched hybridization thermodynamics, such as PCR, sequencing by hybridization, gene diagnostics and antisense oligonucleotide probes. In addition, recent developments of oligonucleotide chip arrays as means for biochemical assays and DNA sequencing requires accurate knowledge of hybridization thermodynamics and population ratios at matched and mismatched target sites. In this study, we report the characteristics of the probe and matched, mismatched target oligonucleotide hybridization reaction using thermodynamic method. Thermodynamic of 5 oligonucleotides with central and terminal mismatch sequences were obtained by measured UV-absorbance as a function of temperature. The data show that the nearest-neighbor base-pair model is adequate for predicting thermodynamics of oligonucleotides with average deviations for $\Delta$H$^{0}$ , $\Delta$S$^{0}$ , $\Delta$G$_{37}$ $^{0}$ and T$_{m}$, respectively.>$^{0}$ and T$_{m}$, respectively.

Energy and Exergy Aanalyses of Drying of Eggplant Slices in a Cyclone Type Dryer

  • Akpinar E. Kavak
    • Journal of Mechanical Science and Technology
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    • 제19권2호
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    • pp.692-703
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    • 2005
  • In this paper, the energy and exergy analyses of the drying process of thin layer of eggplant slices are investigated. Drying experiments were conducted at inlet temperatures of drying air of 55, 65 and $75^{\circ}C$ and at drying air velocities of 1 and $1.5\;ms^{-1}$ in a cyclone type dryer. Using the first law of thermodynamics, energy analysis was carried to estimate the ratios of energy utilization. However, exergy analysis was accomplished to determine type and magnitude of exergy losses during the drying process by applying the second law of thermodynamics. It was deduced that eggplant slices are sufficiently dried in the ranges between $55-75^{\circ}C$ of drying air temperature and at 1 and $1.5\;ms^{-1}$ of drying air velocity during 12000-21600 s despite the exergy losses of $0-0.739\;kJs^{-l}.

Effect of the Stagnation Temperature on the Normal Shock Wave

  • Zebbiche, Toufik
    • International Journal of Aeronautical and Space Sciences
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    • 제10권1호
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    • pp.1-14
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    • 2009
  • When the stagnation temperature increases, the specific heat does not remain constant and start to vary with this temperature. The gas is perfect, it's state equation remains always valid, except, it was called by gas calorically imperfect or gas at high temperatures. The purpose of this work is to develop a mathematical model for a normal shock wave normal at high temperature when the stagnation temperature is taken into account, less than the dissociation of the molecules as a generalisation model of perfect for constant heat specific. A study on the error given by the perfect gas model compared to our model is presented in order to find a limit of application of the perfect gas model. The application is for air.

압축기 출구 물분사가 있는 재생 가스터빈 시스템의 엑서지 해석 (Exergy Analysis of Regenerative Gas Turbine Systems with Afterfogging)

  • 김경훈;고형종;김세웅
    • 한국산업융합학회 논문집
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    • 제13권1호
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    • pp.31-39
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    • 2010
  • An exergy analysis is carried out for the regenerative gas turbine cycle which has a potential of enhanced thermal efficiency and specific power owing to the more possible water injection than that of inlet fogging under the ambient conditions. Using the analysis model in the view of the second law of thermodynamics, the effects of pressure ratio, water injection ratio and ambient temperature are investigated on the performance of the system such as exergetic efficiency, heat recovery ratio of recuperator, exergy destruction or loss ratios, and on the optimal conditions for maximum exergy efficiency. The results of computation for the typical cases show that the regenerative gas turbine system with afterfogging can make a notable enhancement of exergy efficiency.

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적외선 렌즈용 Ge-Sb-Se계 칼코게나이드의 유리안정성 평가 (Glass Forming Stability in Chalcogenide-based GeSbSe Materials for IR-Lens)

  • 정건홍;공헌;여종빈;이현용
    • 한국전기전자재료학회논문지
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    • 제30권4호
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    • pp.204-209
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    • 2017
  • Thermal and structural stability in the glass transition region of chalcogenide glasses has been investigated in terms of thermodynamics for application to various optoelectronic devices. In this study, the compositions of $Ge_xSb_{20}Se_{80-x}$ (x = 10, 15, 20, 25, and 30) were selected to investigate the glass stability according to germanium ratios. The chalcogenide bulks were fabricated by using a traditional melt-quenching method. Thin films were deposited by a thermal evaporation system, maintaining the deposition ratio of $3{\sim}5{\AA}$ in order to have uniformity. The thermal and structural properties were measured by a differential scanning calorimeter (DSC) and X-ray diffraction (XRD). The DSC analysis provided thermal parameters and theoretical glass region stabilities. The XRD analysis supported the theoretical stabilities because of where the crystallization peak data occurred.

증기분사 재생 가스터빈 시스템의 엑서지 해석 (Exergy Analysis of Regenerative Steam-Injection Gas Turbine Systems)

  • 김경훈;정영관;한철호
    • 한국추진공학회지
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    • 제13권4호
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    • pp.45-54
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    • 2009
  • 열효율과 비동력을 대폭 향상시킬 수 있는 잠재성을 가진 증기분사 재생 가스터빈 시스템에 대해 엑서지 해석을 수행하였다. 열역학 제2법칙을 근거로 한 해석 모델을 이용하여 압력비, 증기분사율, 주위 온도, 터빈입구온도 등 주요 설계변수들의 변화에 따라 엑서지 효율, 열교환기의 엑서지 회수율, 엑서지 파괴율 및 손실률 등 시스템의 성능과 최대 엑서지 효율에 미치는 영향을 조사하였다. 계산 결과 재생 증기분사 가스터빈 시스템은 시스템의 엑서지 효율을 대폭 증대시키고 비가역성을 감소시킨다는 사실을 확인하였다.

대형기관 모사 정적연소실에서 매립지 가스의 연소특성에 대한 연구 (I) - 기초 특성 - (Combustion Characteristics of Landfill Gas in Constant Volume Combustion Chamber for Large Displacement Volume Engine (I) - Fundamental Characteristics -)

  • 엄인용
    • 대한기계학회논문집B
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    • 제37권8호
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    • pp.733-741
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    • 2013
  • 본 논문은 대형 상용기관을 모사한 정적연소실에서 매립지 가스의 연소 특성에 대한 복수의 논문 중 첫 논문으로, 연소특성을 연소화학양론 및 열역학적 측면에서 분석하고 이를 실험 결과와 비교하였다. 연소화학양론 및 열역학적 분석에서 연료조성과 당량비에 따라 기연가스의 조성이 변화하고 이에따라 정적비열이 변화하여 동일 발열량에 최종압력은 변화하며, 이것은 실제 연소압력 측정결과와 대체로 일치한다. 연료조성과 당량비에 따른 상대적 압력변화 및 연소기간도 분석결과와 실험결과가 경향상 일치한다. 분석과 실험 결과 사이의 차이는 열전달량의 차이에 기인한 온도저하 및 이에 따른 정적비열의 변화가 주요 원인이며, 연소실 체적과 점화위치도 연소기간과 온도에 큰 영향을 준다. 최종적으로 정적연소에서 연료변환효율은 메탄 분율이 작을수록 그리고 당량비 0.8 ~ 0.9 사이에서 최대가 되며, 이러한 연료변환효율의 증가는 실물기관에서 비열비 감소의 효과를 상쇄하고 남으므로 순수 메탄보다 LFG의 연소가 효율 면에서 유리하다.