• Title/Summary/Keyword: thermodynamics ratios

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Effect of Stagnation Temperature on the Supersonic Flow Parameters with Application for Air in Nozzles

  • Zebbiche, Toufik;Youbi, ZineEddine
    • International Journal of Aeronautical and Space Sciences
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    • v.7 no.1
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    • pp.13-26
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    • 2006
  • When the stagnation temperature of a perfect gas increases, the specific heat for constant pressure and ratio of the specefic heats do not remain constant any more and start to vary with this temperature. The gas remains perfect: its state equation remains always valid, with exception that it will be named by calorically imperfect gas. The aim of this research is to develop the relations of the necessary thermodynamics and geometrical ratios. and to study the supersonic flow at high temperature. lower than the threshold of dissociation. The results are found by the resolution of nonlinear algebraic equations and integration of complex analytical functions where the exact calculation is impossible. The dichotomy method is used to solve the nonlinear equation. and the Simpson algorithm for the numerical integration of the found integrals. A condensation of the nodes is used. Since. the functions to be integrated have a high gradient at the extremity of the interval of integration. The comparison is made with the calorifcally perfect gas to determine the error made by this last. The application is made for the air in a supersonic nozzle.

Detection and Analysis of DNA Hybridization Characteristics by using Thermodynamic Method (열역학법을 이용한 DNA hybridization 특성 검출 및 해석)

  • Kim, Do-Gyun;Gwon, Yeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.6
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    • pp.265-270
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    • 2002
  • The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and application area. So, the improvement of DNA hybridization detection method is very important for the determination of this hybridization reaction. Several molecular biological techniques require accurate predictions of matched versus mismatched hybridization thermodynamics, such as PCR, sequencing by hybridization, gene diagnostics and antisense oligonucleotide probes. In addition, recent developments of oligonucleotide chip arrays as means for biochemical assays and DNA sequencing requires accurate knowledge of hybridization thermodynamics and population ratios at matched and mismatched target sites. In this study, we report the characteristics of the probe and matched, mismatched target oligonucleotide hybridization reaction using thermodynamic method. Thermodynamic of 5 oligonucleotides with central and terminal mismatch sequences were obtained by measured UV-absorbance as a function of temperature. The data show that the nearest-neighbor base-pair model is adequate for predicting thermodynamics of oligonucleotides with average deviations for $\Delta$H$^{0}$ , $\Delta$S$^{0}$ , $\Delta$G$_{37}$ $^{0}$ and T$_{m}$, respectively.>$^{0}$ and T$_{m}$, respectively.

Energy and Exergy Aanalyses of Drying of Eggplant Slices in a Cyclone Type Dryer

  • Akpinar E. Kavak
    • Journal of Mechanical Science and Technology
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    • v.19 no.2
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    • pp.692-703
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    • 2005
  • In this paper, the energy and exergy analyses of the drying process of thin layer of eggplant slices are investigated. Drying experiments were conducted at inlet temperatures of drying air of 55, 65 and $75^{\circ}C$ and at drying air velocities of 1 and $1.5\;ms^{-1}$ in a cyclone type dryer. Using the first law of thermodynamics, energy analysis was carried to estimate the ratios of energy utilization. However, exergy analysis was accomplished to determine type and magnitude of exergy losses during the drying process by applying the second law of thermodynamics. It was deduced that eggplant slices are sufficiently dried in the ranges between $55-75^{\circ}C$ of drying air temperature and at 1 and $1.5\;ms^{-1}$ of drying air velocity during 12000-21600 s despite the exergy losses of $0-0.739\;kJs^{-l}.

Effect of the Stagnation Temperature on the Normal Shock Wave

  • Zebbiche, Toufik
    • International Journal of Aeronautical and Space Sciences
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    • v.10 no.1
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    • pp.1-14
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    • 2009
  • When the stagnation temperature increases, the specific heat does not remain constant and start to vary with this temperature. The gas is perfect, it's state equation remains always valid, except, it was called by gas calorically imperfect or gas at high temperatures. The purpose of this work is to develop a mathematical model for a normal shock wave normal at high temperature when the stagnation temperature is taken into account, less than the dissociation of the molecules as a generalisation model of perfect for constant heat specific. A study on the error given by the perfect gas model compared to our model is presented in order to find a limit of application of the perfect gas model. The application is for air.

Exergy Analysis of Regenerative Gas Turbine Systems with Afterfogging (압축기 출구 물분사가 있는 재생 가스터빈 시스템의 엑서지 해석)

  • Kim, Kyoung-Hoon;Ko, Hyung-Jong;Kim, Se-Woong
    • Journal of the Korean Society of Industry Convergence
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    • v.13 no.1
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    • pp.31-39
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    • 2010
  • An exergy analysis is carried out for the regenerative gas turbine cycle which has a potential of enhanced thermal efficiency and specific power owing to the more possible water injection than that of inlet fogging under the ambient conditions. Using the analysis model in the view of the second law of thermodynamics, the effects of pressure ratio, water injection ratio and ambient temperature are investigated on the performance of the system such as exergetic efficiency, heat recovery ratio of recuperator, exergy destruction or loss ratios, and on the optimal conditions for maximum exergy efficiency. The results of computation for the typical cases show that the regenerative gas turbine system with afterfogging can make a notable enhancement of exergy efficiency.

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Glass Forming Stability in Chalcogenide-based GeSbSe Materials for IR-Lens (적외선 렌즈용 Ge-Sb-Se계 칼코게나이드의 유리안정성 평가)

  • Jung, Gun-Hong;Kong, Heon;Yeo, Jong-Bin;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.4
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    • pp.204-209
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    • 2017
  • Thermal and structural stability in the glass transition region of chalcogenide glasses has been investigated in terms of thermodynamics for application to various optoelectronic devices. In this study, the compositions of $Ge_xSb_{20}Se_{80-x}$ (x = 10, 15, 20, 25, and 30) were selected to investigate the glass stability according to germanium ratios. The chalcogenide bulks were fabricated by using a traditional melt-quenching method. Thin films were deposited by a thermal evaporation system, maintaining the deposition ratio of $3{\sim}5{\AA}$ in order to have uniformity. The thermal and structural properties were measured by a differential scanning calorimeter (DSC) and X-ray diffraction (XRD). The DSC analysis provided thermal parameters and theoretical glass region stabilities. The XRD analysis supported the theoretical stabilities because of where the crystallization peak data occurred.

Exergy Analysis of Regenerative Steam-Injection Gas Turbine Systems (증기분사 재생 가스터빈 시스템의 엑서지 해석)

  • Kim, Kyoung-Hoon;Jung, Young-Guan;Han, Chul-Ho
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.4
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    • pp.45-54
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    • 2009
  • An exergy analysis is carried out for the regenerative steam-injection gas turbine systems which has a potential of enhanced thermal efficiency and specific power. Using the analysis model in the view of the second law of thermodynamics, the effects of pressure ratio, steam injection ratio, ambient temperature and turbine inlet temperature are investigated on the performance of the system such as exergetic efficiency, heat recovery ratio of heat exchangers, exergy destruction, loss ratios, and on the optimal conditions for maximum exergy efficiency. The results of computation show that the regenerative steam-injection gas turbine system can make a notable enhancement of exergy efficiency and reduce irreversibilities of the system.

Combustion Characteristics of Landfill Gas in Constant Volume Combustion Chamber for Large Displacement Volume Engine (I) - Fundamental Characteristics - (대형기관 모사 정적연소실에서 매립지 가스의 연소특성에 대한 연구 (I) - 기초 특성 -)

  • Ohm, Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.733-741
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    • 2013
  • This is the first paper on the combustion characteristics of landfill gas in a constant volume combustion chamber for a large displacement volume commercial engine, and it discusses the fundamental characteristics of fuel from the viewpoint of thermochemistry and thermodynamics and compares these results with experimental ones. The results show that the final pressures obtained from theoretical analysis vary under the same heating value owing to the change in the constant volume specific heat owing to the difference in the burned gas composition according to the fuel gas compositions; furthermore, the stoichiometric ratios and trends of analytical and experimental pressures coincide very well, although some minor differences are observed between the two. The root cause of the difference is the heat transfer, which changes the specific heat and lowers the temperature considerably, in the real combustion process. In addition, the large chamber volume and ignition position promote the heat transfer to the wall. Finally, the fuel conversion efficiency increases as the methane mol fraction decreases, and it is maximum when the stoichiometric ratio ranges from 0.8 to 0.9. These increases due to the composition and stoichiometric ratio could sufficiently compensate the decrease due to the specific heat ratio drop, LFG might be more advantageous than pure methane in a real engine.