• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.12
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• pp.781-788
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• 2008

A dynamic model has been developed to simulate dynamic operation of a real double-effect absorption chiller. Dynamic behavior of working fluids in main components was modeled in first-order nonlinear differential equations based on heat and mass balances. Mass transport mechanisms among the main components were modeled by valve throttling, 'U' tube overflow and solution sub-cooling. The nonlinear dynamic equations coupled with the subroutines to calculate thermodynamic properties of working fluids were solved by a numerical method. The dynamic performance of the model was compared with the test data of a commercial medium chiller. The model showed a good agreement with the test data except for the first 5,000 seconds during which different flow rates of the weak solution caused some discrepancy. It was found that the chiller dynamics is governed by the inlet temperatures of the cooling water and the chilled water when the heat input to the chiller is relatively constant.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.3
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• pp.220-226
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• 2019

Magnesium hydride has a high hydrogen storage capacity (7.6 wt.%), and is cheap and lightweight, thus advantageous as a hydrogen storage alloy. However, Mg-based hydrides undergo hydrogenation/dehydrogenation at high temperature and pressure due to their thermodynamic stability and high oxidation reactivity. MWCNTs exhibit prominent catalytic effect on the hydrogen storage properties of $MgH_2$, weakening the interaction between Mg and H atoms and reducing the activation energy for nucleation of the metal phase by co-milling Mg with carbon nanotubes. Therefore, it is suggested that combining transition metals with carbon nanotubes as mixed dopants has a significant catalytic effect on the hydrogen storage properties of $MgH_2$. In this study, Material life cycle evaluation was performed to analyze the environmental impact characteristics of Mg-CaO-10 wt.% MWCNTs composites manufacturing process. The software of material life cycle assessment (MLCA) was Gabi 6. Through this, environmental impact assessment was performed for each process.

• Korean Journal of Metals and Materials
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• v.48 no.3
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• pp.194-202
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• 2010

Application of a stronger and more durable material for reactor pressure vessels (RPVs) might be an effective way to insure the integrity and increase the efficiency of nuclear power plants. A series of research projects to apply the SA508 Gr.4 steel in ASME code to RPVs are in progress because of its excellent strength and durability compared to commercial RPV steel (SA508 Gr.3 steel). In this study, the microstructural characteristics and mechanical properties of SA508 Gr.3 Mn-Mo-Ni low alloy steel and SA508 Gr.4N Ni-Mo-Cr low alloy steel were investigated. The differences in the stable phases between these two low alloy steels were evaluated by means of a thermodynamic calculation using ThermoCalc. They were then compared to microstructural features and correlated with mechanical properties. Mn-Mo-Ni low alloy steel shows the upper bainite structure that has coarse cementite in the lath boundaries. However, Ni-Mo-Cr low alloy steel shows the mixture of lower bainite and tempered martensite structure that homogeneously precipitates the small carbides such as $M_{23}C_6$ and $M_7C_3$ due to an increase of hardenability and Cr addition. In the mechanical properties, Ni-Mo-Cr low alloy steel has higher strength and toughness than Mn-Mo-Ni low alloy steel. Ni and Cr additions increase the strength by solid solution hardening. In addition, microstructural changes from upper bainite to tempered martensite improve the strength of the low alloy steel by grain refining effect, and the changes in the precipitation behavior by Cr addition improve the ductile-brittle transition behavior along with a toughening effect of Ni addition.

• International Journal of Computer Science & Network Security
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• v.21 no.6
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• pp.47-53
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• 2021

The article deals with the problems of application of microwave methods in systems of geoecological monitoring of natural environments and resources of the agro-industrial complex. It is noted that the methods of microwave radiometry make it possible, by the power of the measured intrinsic radio-thermal radiation of the atmosphere, when solving inverse problems using empirical and semi-empirical models, to determine such parameters of the atmosphere as thermodynamic temperature, humidity, water content, moisture content, precipitation intensity, and the presence of different fractions of clouds.In addition to assessing the meteorological parameters of the atmosphere and the geophysical parameters of the underlying surface based on the data of microwave radiometric measurements, it is possible to promptly detect and study pollution of both the atmosphere and the earth's surface. A technique has been developed for the analysis of sources of measurement error and their numerical evaluation, because they have a significant effect on the accuracy of solving inverse problems of reconstructing the values of the physical parameters of the probed media.To analyze the degree of influence of the limited spatial selectivity of the antenna of the microwave radiometric system on the measurement error, we calculated the relative measurement error of the ratio of radio brightness contrasts in two angular directions. It has been determined that in the system of geoecological monitoring of natural environments, the effect of background noise is maximal with small changes in the radiobrightness temperature during angular scanning and high sensitivity of the receiving equipment.

• Journal of the Korean Chemical Society
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• v.25 no.4
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• pp.228-235
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• 1981

Ultraviolet spectrophotometric investigation were carried out on the systems of pyridine, ${\beta}$-picoline and 3,5-lutidine with iodine in carbon tetrachloride. The results reveal the formation of one to one molecular complexes of the type, $C_5H_5N{\cdot}I_2$, ${\beta}-C_5H_4(CH_3)N{\cdot}I_2$ and 3,5-$C_5H_3(CH_3)_2N{\cdot}I_2$. The equrilibrium constants of complexes were obtained in consideration of that absorption maxima have the blue shift with the increasing temperatures according to the formation of the charge transfer complexes. The thermodynamic parameters, ${\Delta}H$, ${\Delta}G$ and ${\Delta}S$ for the formation of the charge transfer complexes were calculated from these values. These results indicated that the relative stabilities of the pyridine, ${\beta}$-picoline and 3,5-lutidine complexes with iodine increase in the order, pyridine < ${\beta}$-picoline < 3,5-lutidine. These results were supposed to be the influence resulted from increase of electron density by the positive inductive effect and the dipole moment of the steric hindrance effect. And this results were compared and discussed with polymethylbenzene-iodine CT-complexes.

• Bulletin of the Korean Chemical Society
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• v.30 no.11
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• pp.2691-2696
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• 2009

Effects of representative group II and transition metal ions on the stability of the $poly(dA){\cdot}[poly(dT)]_2$ triplex were investigated by the van’t Hoff plot constructed from a thermal melting curve. The transition, $poly(dA){\cdot}[poly(dT)]_2\;{\rightarrow}\;poly(dA){\cdot}poly(dT)\;+\;poly(dT)$, was non-spontaneous with a positive Gibb’s free energy, endothermic (${\Delta}H^{\circ}$ > 0), and had a favorable entropy change (${\Delta}S^{\circ}$ > 0), as seen from the negative slope and positive y-intercept in the van’t Hoff plot. Therefore, the transition is driven by entropy change. The $Mg^{2+}$ ion was the most effective at stabilization of the triplex, with the effect decreasing in the order of $Mg^{2+}\;>\;Ca^{2+}\;>\;Sr^{2+}\;>\;Ba^{2+}$. A similar stabilization effect was found for the duplex to single strand transition: $poly(dA){\cdot}poly(dT)\;+\;poly(dT)\;→\;poly(dA)\;+\;2poly(dT)$, with a larger positive free energy. The transition metal ions, namely $Ni_{2+},\;Cu_{2+},\;and\;Zn_{2+}$, did not exhibit any effect on triplex stabilization, while showing little effect on duplex stabilization. The different effects on triplex stabilization between group II metal ions and the transition metal ions may be attributed to their difference in binding to DNA; transition metals are known to coordinate with DNA components, including phosphate groups, while group II metal ions conceivably bind DNA via electrostatic interactions. The $Cd_{2+}$ ion was an exception, effectively stabilizing the triplex and melting temperature of the third strand dissociation was higher than that observed in the presence of $Mg_{2+}$, even though it is in the same group with $Zn_{2+}$. The detailed behavior of the $Cd_{2+}$ ion is currently under investigation.

• Ocean Science Journal
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• v.43 no.4
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• pp.195-208
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• 2008

This paper evaluates whether a thermodynamic ocean-carbon model can be used to predict the monthly mean global fields of the surface-water partial pressure of $CO_2$ ($pCO_{2SEA}$) from sea surface salinity (SSS), temperature (SST), and/or nitrate ($NO_3$) concentration using previously published regional total inorganic carbon ($C_T$) and total alkalinity ($A_T$) algorithms. The obtained $pCO_{2SEA}$ values and their amplitudes of seasonal variability are in good agreement with multi-year observations undertaken at the sites of the Bermuda Atlantic Timeseries Study (BATS) ($31^{\circ}50'N$, $60^{\circ}10'W$) and the Hawaiian Ocean Time-series (HOT) ($22^{\circ}45'N$, $158^{\circ}00'W$). By contrast, the empirical models predicted $C_T$ less accurately at the Kyodo western North Pacific Ocean Time-series (KNOT) site ($44^{\circ}N$, $155^{\circ}E$) than at the BATS and HOT sites, resulting in greater uncertainties in $pCO_{2SEA}$ predictions. Our analysis indicates that the previously published empirical $C_T$ and $A_T$ models provide reasonable predictions of seasonal variations in surface-water $pCO_{2SEA}$ within the (sub) tropical oceans based on changes in SSS and SST; however, in high-latitude oceans where ocean biology affects $C_T$ to a significant degree, improved $C_T$ algorithms are required to capture the full biological effect on $C_T$ with greater accuracy and in turn improve the accuracy of predictions of $pCO_{2SEA}$.

• Journal of the Korean Chemical Society
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• v.34 no.5
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• pp.483-489
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• 1990

The rate of hydrolysis of insecticidal 2-chloro-l-(2,4,5-trichlorophenyl)-vinyldimethylphosphate(Gardona) have been investigated in 25${\%}$ aqueous methanol. Studies at varying pH suggest that the hydrolysis of Gardona proceeds through the bimolecular (Ad$_{N-E}$) mechanism involving the transition state and carbanion intermediate as evidenced by solvent effect (m < 0.4, n < 0.7, [m] ${\ll}$ [l](associative SN$_2$ type)), thermodynamic parameters (${\{Delta}S^{\neq}$ = -27∼-32 e.u. & ${\{Delta}H^{\neq}$ = 13∼18 Kcal/mole), hydrolysis rate equation (k = k$_A+_B$ [OH-]), general base catalysis and hydrolysis product analysis, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.4
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• pp.391-397
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• 2010

Performance tests of a liquid-oxygen pump were carried out using liquid nitrogen (LN2) as a working fluid in a cryogenic turbopump test facility in Korea Aerospace Research Institute (KARI). The tests were performed at 30-55% of the design rotational speed, and the results were compared with those from a water test. The experimental results confirmed the similarity of the hydraulic performance, which allows the prediction of the pump performance at a design rotational speed of 20,000 rpm. The overall cavitation performance of the pump in the cryogenic environment was better than that in the water environment for all ranges of flow rates and rotational speeds. Critical cavitation number at the design flow rate was determined as 0.012 from the cryogenic test, and as 0.024 from the water test. The improved cavitation performance is due to the thermodynamic effect in cryogenic fluids.

• Journal of the Korean Chemical Society
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• v.56 no.6
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• pp.692-699
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• 2012

The aim of the present study is to explore the possibility of utilizing loess and fly ash as well as activated carbon for the adsorptive removal of PCBs in transformer oil. Here, we investigated the effect of various factors such as temperature (5, 25, 55), contact time (30 min-3 day) and adsorbent does (1, 2.5, 5, 10 g) in detail. It was found that PCBs adsorption rate from transformer oil by activated carbon is more favored than loess at the equilibrium time of 60 minutes. The equilibrium data for both activated carbon and loess is fitted well to the Freundlich isotherm model. The rate constant and activation energy of PCBs adsorption in transformer oil on each adsorbent was analyzed by fitting a kinetic model at 5, 25 and $55^{\circ}C$. From the thermodynamic parameters, the PCBs adsorption process for transformer oil/activated carbon and loess system is spontaneous and endothermic in nature.