• Mass Spectrometry Letters
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• 제12권4호
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• pp.131-136
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• 2021

Collision-induced dissociation of peptides involves a series of proton-transfer reactions in the activated peptide. To describe the kinetics of energy-variable dissociation, we considered the heat capacity of the peptide and the Marcus-theory-type proton-transfer rate. The peptide ion was activated to the high internal energy states by collision with a target gas in the collision cell. The mobile proton in the activated peptide then migrated from the most stable site to the amide oxygen and subsequently to the amide nitrogen (N-protonated) of the peptide bond to be broken. The N-protonated intermediate proceeded to the product-like complex that dissociated to products. Previous studies have suggested that the proton-transfer equilibria in the activated peptide affect the dissociation kinetics. To take the extent of collisional activation into account, we assumed a soft-sphere collision model, where the relative collision energy was fully available to the internal excitation of a collision complex. In addition, we employed a Marcus-theory-type rate equation to account for the proton-transfer equilibria. Herein, we present results from the integrated thermochemical approach using a tryptic peptide of ubiquitin.

• 자원리싸이클링
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• 제32권6호
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• pp.79-89
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• 2023

최근 탄소 중립 이슈와 함께 가장 많은 조명을 받고 있는 환경 문제로는 폐플라스틱 처리 문제가 있다. 폐플라스틱의 재활용 기술 중에서도 고온의 조건에서 유기물을 전환하여 원료 및 에너지로 재활용하는 열화학적 재활용 기술은 그동안 폐플라스틱에 주로 이용되어 왔던 물질재활용의 한계를 넘어선 기술로 평가 받고 있다. 열화학적 재활용 기술은 폐플라스틱을 원래 플라스틱의 원료로 재순환할 수 있는 순환경제의 핵심 기술로 부각되고 있으며 후속공정 및 최종 생산품의 활용 방법에 따라서 원료(Chemical recycling) 및 에너지(Waste to energy)로 재활용이 가능한 장점을 가지고 국내 뿐 아니라 세계적으로 주목을 받고 있다. 본 논문에서는 열화학적 재활용의 대표적인 세가지 기술인 연소, 가스화, 열분해에 대하여 살펴보고 최근 주요 기술 동향을 제시하고자 한다.

• JSTS:Journal of Semiconductor Technology and Science
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• 제14권1호
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• pp.92-95
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• 2014

In this work we have synthesized ZnS:Mn nanocrystals (NCs) using a simple one step thermochemical method. $Zn(NO_3)_2$ and $Na_2S_2O_3$ were used as the precursors and $Mn(NO_3)_2$ was the source of impurity. Thioglycolic acid (TGA) was used as the capping agent and the catalyst of the reaction. The structure and optical property of the NCs were characterized by means of X- ray diffraction (XRD), HRTEM, UV-visible optical spectroscopy and photoluminescence (PL). X-ray diffraction (XRD) and transmission electron microscopy (TEM) analyses demonstrated cubic phase ZnS:Mn NCs with an average size around 3 nm. Synthesized NCs exhibited band gap of about 4 eV. Photoluminescence spectra showed a yellow-orange emission with a peak located at 585 nm, demonstrating the Mn incorporation inside the ZnS particles.

• 한국응용과학기술학회지
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• 제35권2호
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• pp.540-559
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• 2018

액상 바이오연료를 생산할 수 있는 하수슬러지는 자국의 에너지 안보와 지속가능한 생산이 가능하고 경제적인 원료로 여겨지고 있다. 열화학적 기술은 하수슬러지를 에너지화, 연료화할 수 있는 가장 효과적인 방법이다. 일반적으로 하수슬러지는 수분 함량이 80% 이상으로 높은 금속 함량과 14 ~ 20 MJ/kg의 발열량을 갖고 있다. 본 논문에서는 하수슬러지를 활용한 액상 바이오연료를 생산하는 열분해 반응, 전이에스테르화 반응, 초임계 반응 기술에 대해 살펴보고자 한다. 또한, 하수슬러지 유래 액상 바이오연료의 연료적 특성과 액상 바이오연료와 관련한 국내 법에 대해 검토하였다.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.503-512
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• 2012

There is a new power generation system such as direct coal fuel cell (DCFC) with a solid oxide electrolyte operated at relatively high temperature. In the system, it is of great importance to feed coal continuously into anodic electrode surface for its better contact, otherwise it would reduce electrochemical conversion of coal. For that purpose, it is required to improve the electrochemical conversion efficiency by using either rigorous mixing condition such as fluidized bed condition or just by recirculating coal particle itself successively into the reaction zone of the system. In this preliminary study, we followed the second approach to investigate how significantly particle recycle would affect the coal conversion efficiency. As a first phase, coal conversion was analyzed and evaluated from the thermochemical reaction of carbon with air under particle recirculating condition. The coal conversion efficiency was obtained from raw data measured by two different techniques. Effects of temperature and fuel properties on the coal conversion are specifically examined from the thermochemical reaction.

• 한국입자에어로졸학회지
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• 제10권3호
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• pp.99-108
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• 2014

Liquid filtration by membrane filters is essential for the preparation of ultrapure water in semiconductor manufacturing processes. The separation of submicrometer particles suspended in ultrapure water with a laminated fibrous membrane filter was studied numerically and experimentally in the present work. We found that an electrical double layer around a single fiber expanded to a large extent at a low ion concentration, as in ultrapure water, and deformed toward the upstream of the fiber with increasing filtration velocity. Since an increase in the electrical double-layer thickness leads to a decrease in the electrical potential gradient, particles with the same polarity as the fiber approach the fiber more easily and are captured at a high filtration velocity. Experimental results also confirmed that the collection efficiency of polystyrene latex(PSL) particles through a PTFE filter became higher as the filtration velocity increased.

• 한국분말재료학회지
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• 제1권2호
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• pp.208-216
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• 1994

A radically new approach to the in situ synthesis of the consituent phases of a composite structure has enabled the production of a new WC/Co materials with an ultrafine microstructure. The process for synthesizing nanophase WC/Co powders consists of spray drying from solution to form a homogeneous precursor powder, and thermochemical conversion of the precursor powder to the nanophase WC/Co powder. Near theoretical density of pure nanophase WC-10 wt%Co has been obtained in only 30 sec at 140$0^{\circ}C$. But WC particles were grown up very rapidly with longer sintering time to get full density. To overcome coarsening of WC particle during sintering, VC, TaC and VC/TaC were used as the grain growth inhibitor with different amount respectively. VC/TaC doped WC-10 wt%Co was shown superior hardness and TRS and microstructure was maintained ultrafine scale (average WC size is less than 0.1 ${\mu}{\textrm}{m}$).

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.75-87
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• 1996

This review is presented under the following headings: 1.Introduction 1.1 Brief review of the properties of AlN 1.2 Historical survey of work on ceramic and single crystal AlN 2.Thermochemical background 3.Crystal growth 4.Doping 5.Potential applications and future work The known properties of AlN which make it of interest for various are discussed briefly. The properties include chemical stability, crystal structure and lattice constants, refractive indices and other optical properties, dielectric constant, surface acoustic wave velocity and thermal conductivity. The history of work in single crystals, thin films and ceramics are outlined and the thermochemistry of AlN reviewed together with some of the relevant properties of aluminium and nitrogen; the problems encountered in growing crystals of AlN are shown to arise directly from these thermochemical relationships. Methods have been reported in the literature for growing AlN crystals from melts, solution and vapour and these methods are compared critically. It is proposed that the only practicable approach to the growth of AlN is by vapour phase methods. All vapour based procedures share the share the same problems: $.$the difficulty of preventing contamination by oxygen & carbon $.$the high bond energy of molecular nitrogen $.$the refractory nature of AlN (melting point~3073K at 100ats.) $.$the high reactivity of Al at high temperatures It is shown that the growth of epitactic layers and polycrystalline layers present additional problems: $.$chemical incompatibility of substrates $.$crystallographic mismatch of substrates $.$thermal mismatch of substrates The result of all these problems is that there is no good substrate material for the growth of AlN layers. Organometallic precursors which contain an Al-N bond have been used recently to deposit AlN layers but organometallic precursors gave the disadvantage of giving significant carbon contamination. Organometallic precursors which contain an Al-N bound have been used recently to deposit AlN layers but organometallic precursors have the disadvantage of giving significant carbon contamination. It is conclude that progress in the application of AlN to optical and electronic devices will be made only if considerable effort is devoted to the growth of larges, pure (and particularly, oxygen-free) crystals. Progress in applications of epi-layers and ceramic AlN would almost certainly be assisted also by the availability of more reliable data on the pure material. The essential features of any stategy for the growth of AlN from the vapour are outlined and discussed.

• Nuclear Engineering and Technology
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• 제45권3호
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• pp.401-414
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• 2013

HTR50S is a small modular reactor system based on HTGR. It is designed for a triad of applications to be implemented in successive stages. In the first stage, a base plant for heat and power is constructed of the fuel proven in JAEA's $950^{\circ}C$, 30MWt test reactor HTTR and a conventional steam turbine to minimize development risk. While the outlet temperature is lowered to $750^{\circ}C$ for the steam turbine, thermal power is raised to 50MWt by enabling 40% greater power density in 20% taller core than the HTTR. However the fuel temperature limit and reactor pressure vessel diameter are kept. In second stage, a new fuel that is currently under development at JAEA will allow the core outlet temperature to be raised to $900^{\circ}C$ for the purpose of demonstrating more efficient gas turbine power generation and high temperature heat supply. The third stage adds a demonstration of nuclear-heated hydrogen production by a thermochemical process. A licensing approach to coupling high temperature industrial process to nuclear reactor will be developed. The low initial risk and the high longer-term potential for performance expansion attract development of the HTR50S as a multipurpose industrial or distributed energy source.