• Title/Summary/Keyword: thermo stability

Search Result 154, Processing Time 0.034 seconds

Mineral Chemistry and Thermo-chemical Characterization of Wellsite, a Barrian Zeolite, from the Tertiary Formation in Gampo Area (감포 지역의 제3기 층에서 산출되는 Ba-제올라이트인 웰자이트의 광물화학 및 열화학적 특성)

  • 노진환;김기업
    • Journal of the Mineralogical Society of Korea
    • /
    • v.10 no.2
    • /
    • pp.105-113
    • /
    • 1997
  • Mineral description and mineralogical characterization were made for the wellsite, a barrian zeolite, which found as diagenetic alterations in the Miocene pyroclastic rocks in Gampo area. The wellsite occurs together with clinoptilolite, smectite and apatite as euhedral crystallites (0.2~0.4mm) forming interpenetraion twinning in the vesicles of altered pmice fragments. Compared to other reported wellsites, the wellsite is rather silicic (Si/(Al+Fe): 3.12-3.16) and Ca-rich. Unit cell dimensions and chemical formular determined from XRD, EMPA and TGA data are as follows:a=9.883$\AA$, b=14.204$\AA$, c=8.677$\AA$, $\beta$-124.764$^{\circ}$, (Ba0.57K0.36)(Ca1.18Na0.04)Al3.9Si12.1O32.13.9H2O.The cation composition of the Gampo wellsite, which shows an exchange reaction in the form of Ba2++Ca2+=2(K++Na-), is deviated far from the compositional range of a phillipsite-harmotome series. Due to higher abundance of divalent cations (Ca, Ba) and si in the wellsite, cimpared to those of the phillipsite and harmotome reported in other areas, the zeolite seems to be characteristic of higher water content (18.7 wt%) and higher thermal stability. XRD, chemical and thermo-chemical results of the wellsite reflects that wellsite is rather a Ba- and Ca-rich end member of a phillipsite-harmotome-wellsite series than an intermediate phase of phillipsite-harmotome series or a barrian variety of phillipste.

  • PDF

A Study on the Thermal Behavior Characteristic of Drum Brake considering Braking Patterns (제동 패턴을 고려한 드럼 브레이크의 열적 거동 특성에 대한 연구)

  • Lee, Kye-Sub;Son, Sung-Soo;Yang, Ki-Hyun
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.14 no.5
    • /
    • pp.145-154
    • /
    • 2006
  • Each part of drum brake system is loaded by continual mechanical force and thermal force every time of braking, so enough strength and stability are required. Thermal characteristic is one of the important factors in drum brake systems design. This paper presents the thermal performance such as temperature distribution and thermal contact stress of drum brake system considering several braking patterns; 80th heat braking test mode, heat fade braking test mode, general road mode, steep slope road mode and off road mode. Transient heat transfer analysis and Thermo elastic contact analysis is executed to obtain the temperature distribution, and to evaluate thermal stress of drum brake by using ABAQUS/Standard code. This procedure of analysis can effectively be used to improve the quality problem of brake system and to get design guideline of the new product.

Analysis of the thermal instability of laminated composite plates

  • H. Mataich;A. El Amrani;B. El Amrani
    • Coupled systems mechanics
    • /
    • v.13 no.2
    • /
    • pp.95-113
    • /
    • 2024
  • In this paper, we will analyse the thermo-elastic behavior of the plate element of a structure arranged in a climatically aggressive environment (extreme temperature), we use a refined four-variable thick plate theory to take the shear effect into consideration, the proposed theory less computationally expensive and more accurate so that it incorporates the shear effect into the formulation. The plate is assumed to be simply supported on its four edges, so exact (closed-form) solutions are found according to the Navier expansion, and the governing stability equations and associated boundary conditions of the problem are obtained via the virtual works principle. The plate studied ismade of laminated composite materials, so a parametric study is needed to see the effect of different types of parameters and coupling on the critical temperature value causing thermo-elastic instability of the plate and also on the natural frequency of free vibration, as well as for other parameters such as anisotropy, slenderness and aspect ratio of the plate and finally the lamination angle. Numerical results are obtained for specially orthotropic and antisymmetrical plates and are compared with those obtained by othertheoriesin the literature to validate the analysis approach used.

A Basic Study on Borehole Breakout under Room Temperature and High Temperature True Triaxial Compression (상온 및 고온 하 진삼축압축실험을 이용한 시추공의 파괴 거동 기초 연구)

  • Yoon, Jeonghwan;Min, Ki-Bok;Park, Eui-Seob;Jung, Yong-Bok
    • Tunnel and Underground Space
    • /
    • v.30 no.6
    • /
    • pp.559-572
    • /
    • 2020
  • This paper performs laboratory experiments for borehole stability considering temperature and true triaxial stress condition, and observes a thermo-mechanical behavior of the rock under stress and temperature conditions of deep underground. China yellow sandstone and Hwangdeung granite specimens were used to perform a true triaxial compression test. Mechanical tests were carried out under nine confining pressure conditions, and thermo-mechanical tests using granite samples were carried out under six confining pressure conditions at 60-100℃. In the mechanical tests, maximum principal stress at borehole breakout was proportional to intermediate principal stress. In the thermo-mechanical tests, it was confirmed that thermal stress is added to the stress field of the borehole with the increase in temperature, resulting in additional breakout progress. To analyze the results of the laboratory experiment, Mogi-Coulomb failure criterion was used. The results of traditional triaxial compression test on cylindrical specimens and borehole breakout under true triaxial compressions matched well with Mogi-Coulomb failure criterion.

Effect of MeOH/IPA Ratio on Coating and Fluxing of Organic Solderability Preservatives (유기 솔더 보존제의 코팅 및 플럭싱에 대한 메탄올/이소프로필알콜 비율의 영향)

  • Lee, Jae-Won;Kim, Chang Hyeon;Lee, Hyo Soo;Huh, Kang Moo;Lee, Chang Soo;Choi, Ho Suk
    • Korean Chemical Engineering Research
    • /
    • v.46 no.2
    • /
    • pp.402-407
    • /
    • 2008
  • Recent popularity in mobile electronics requires higher standard on the mechanical strength of electronic packaging. Thus, the method of soldering between chip and substrate in electronic packaging process is changing from conventional method using intermetallic compound to a new method using organic solderability preservative (OSP) in order to improve the stability and the reliability of final product. Since current organic solder preservatives have several serious problems like thermo-stability during packaging process, however, it is necessary to develop new OSPs having thermo-stability. The main purpose of this study is to investigate the effect of MeOH/IPA (Isopropyl alcohol) ratio on the fluxing of a new OSP, developed in previous research, andto find out an optimum formulation of flux components for the application of the OSP in current packaging process. As a result of this study, it was revealed that higher MeOH/IPA ratio in flux showed better performance of fluxing a new OSP.

Body Temperature Monitoring Using Subcutaneously Implanted Thermo-loggers from Holstein Steers

  • Lee, Y.;Bok, J.D.;Lee, H.J.;Lee, H.G.;Kim, D.;Lee, I.;Kang, S.K.;Choi, Y.J.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.29 no.2
    • /
    • pp.299-306
    • /
    • 2016
  • Body temperature (BT) monitoring in cattle could be used to early detect fever from infectious disease or physiological events. Various ways to measure BT have been applied at different locations on cattle including rectum, reticulum, milk, subcutis and ear canal. In other to evaluate the temperature stability and reliability of subcutaneous temperature (ST) in highly fluctuating field conditions for continuous BT monitoring, long term ST profiles were collected and analyzed from cattle in autumn/winter and summer season by surgically implanted thermo-logger devices. Purposes of this study were to assess ST in the field condition as a reference BT and to determine any location effect of implantation on ST profile. In results, ST profile in cattle showed a clear circadian rhythm with daily lowest at 05:00 to 07:00 AM and highest around midnight and rather stable temperature readings (mean${\pm}$standard deviation [SD], $37.1^{\circ}C$ to $37.36^{\circ}C{\pm}0.91^{\circ}C$ to $1.02^{\circ}C$). STs are $1.39^{\circ}C$ to $1.65^{\circ}C$ lower than the rectal temperature and sometimes showed an irregular temperature drop below the normal physiologic one: 19.4% or 36.4% of 54,192 readings were below $36.5^{\circ}C$ or $37^{\circ}C$, respectively. Thus, for BT monitoring purposes in a fever-alarming-system, a correction algorithm is necessary to remove the influences of ambient temperature and animal resting behavior especially in winter time. One way to do this is simply discard outlier readings below $36.5^{\circ}C$ or $37^{\circ}C$ resulting in a much improved mean${\pm}$SD of $37.6^{\circ}C{\pm}0.64^{\circ}C$ or $37.8^{\circ}C{\pm}0.55^{\circ}C$, respectively. For location the upper scapula region seems the most reliable and convenient site for implantation of a thermo-sensor tag in terms of relatively low influence by ambient temperature and easy insertion compared to lower scapula or lateral neck.

Fire Resistance and Thermal Stability Study of Fire-Retarded Polypropylene Systems by Using Cone Calorimeter and Thermogravimetry (콘 칼로리미터와 TGA를 이용한 할로겐 계통의 난연제를 첨가한 폴리프로필렌 수지의 난연성 및 열 안정성에 관한 연구)

  • 곽성복;정찬화;남재도;김준형;최미애
    • Polymer(Korea)
    • /
    • v.24 no.6
    • /
    • pp.777-786
    • /
    • 2000
  • Fire resistance and thermal stability of polypropylene composite systems were investigated by using several halogenated fire-retardants such as decabromodiphenyl oxide (DBDPO) and chlorinated paraffin wax (CPW). The fire resistance of composite systems was thoroughly examined by measuring limited oxygen index (LOI, ASTM D2863, ISO 4589) and characteristic properties of cone calorimetry(ASTM E1354, ISO 5660) heat release rates (HRR), time to ignition (TTI), total heat release (THR), effective heat of combustion (EHC), mass loss rates, etc. Comparing the cone calorimetry experimental results of the halogen flame retardants, DBDPO exhibited twice higher efficiency than CPW in polypropylene systems, and the LOI also showed similar trends to cone calorimetry. The thermo-oxidative stability of the composite systems was increased about 30-5$0^{\circ}C$ in thermogravimetry analysis.Collectively, the combustion, extinction and thermally-stable characteristics of flame retardants were identified in this study.

  • PDF

A study on the dynamic instabilities of a smart embedded micro-shell induced by a pulsating flow: A nonlocal piezoelastic approach

  • Atabakhshian, Vahid;Shooshtaria, Alireza
    • Advances in nano research
    • /
    • v.9 no.3
    • /
    • pp.133-145
    • /
    • 2020
  • In this study, nonlinear vibrations and dynamic instabilities of a smart embedded micro shell conveying varied fluid flow and subjected to the combined electro-thermo-mechanical loadings are investigated. With the aim of designing new hydraulic sensors and actuators, the piezoelectric materials are employed for the body and the effects of applying electric field on the stability of the system as well as the induced voltage due to the dynamic behavior of the system are studied. The nonlocal piezoelasticity theory and the nonlinear cylindrical shell model in conjunction with the energy approach are utilized to mathematically modeling of the structure. The fluid flow is assumed to be isentropic, incompressible and fully develop, and for more generality of the problem both steady and time dependent flow regimes are considered. The mathematical modeling of fluid flow is also carried out based on a scalar potential function, time mean Navier-Stokes equations and the theory of slip boundary condition. Employing the modified Lagrange equations for open systems, the nonlinear coupled governing equations of motion are achieved and solved via the state space problem; forth order numerical integration and Bolotin's method. In the numerical results, a comprehensive discussion is made on the dynamical instabilities of the system (such as divergence, flutter and parametric resonance). We found that applying positive electric potential field will improve the stability of the system as an actuator or vibration amplitude controller in the micro electro mechanical systems.

Novel Imidazolium Ionic Liquids Containing Quaternary Ammonium Iodide or Secondary Amine for Dye-sensitized Solar Cell

  • Seo, Dong-Wan;Lim, Young-Don;Lee, Soon-Ho;Ur, Soon-Chul;Kim, Whan-Gi
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.8
    • /
    • pp.2633-2636
    • /
    • 2011
  • A new type of ionic liquid based on N-(3-aminepropyl)imidazolium iodide, called IIQAI, which consists of imidazolium and quaternary ammonium salt, and APII-(hydroxyethyl, propyl, hexyl) were synthesized and used as ionic liquid in dye-sensitized solar cells. APII-hexyl is solid, whereas IIQAI, APII-(hydroxyethyl, propyl) are viscous liquids. The synthesized ionic liquid showed relative thermal stability compared to the commercial ionic liquid of DMII. Among them, IIQAI was more stable than the other ionic liquid because of the two salt groups. APII-hydroxyethyl, which contains two hydroxyl groups, showed low viscosity with good flow. New types of ionic liquids were examined by $^1H$-NMR spectroscopy, thermo gravimetric analysis (TGA). IIQAI enabled a solar energy conversion efficiency of 6.3%, which is slightly higher than that of the referenced (DMII, 6.2%).

Characteristic Studies of Plasma Treated unidirectional Hildegardia Populifolia Fabric

  • Prasad, C. Venkata;Lee, D.W.;Sudhakara, P.;Jagadeesh, D.;Kim, B.S.;Bae, S.I.;Song, J.I.
    • Composites Research
    • /
    • v.26 no.1
    • /
    • pp.54-59
    • /
    • 2013
  • This study deals with effect of plasma treatment on the properties of unidirectional ligno cellulosic fabric Hildegardia Populofolia (HDP) fabric. Thermal stability of the fabric was determined by differential scanning calorimetry (DSC) and Thermo gravimetric analysis (DSC). Morphological properties was analyzed by SEM analysis and found that the surface was rough upon plasma treatment which provides good interfacial adhesion with matrix during composite fabrication. Thermal stability and mechanical properties of the plasma treated fabric slightly increases compare to alkali and untreated fabric. It was observed that tensile properties of the fabric increases upon plasma treatment due to the formation of rough surface. SEM analysis indicates formation of rough surface on plasma treatment which helps in increasing the interfacial interaction between the matrix (hydrophobic) and fabric (hydrophilic).