• Title/Summary/Keyword: thermal-degradation

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Stabilities of Anthocyanin Pigmenta obtained from Crab Apple (Malus prunifolia Wild. Borkh. "Red Fruit") by Ethanol Extraction (꽃사과(Malus prunifolia Wild. Borkh. "Red Fruit")에서 에탄올 추출한 안토시안 색소의 안정성)

  • 김용환
    • The Korean Journal of Food And Nutrition
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    • v.12 no.1
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    • pp.85-90
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    • 1999
  • The characcteristics of anthocyanin pigments from crab apple (Malus prunifolia Wild. Borkh. "red fruit") by ethanol extract were investigated at various condition of light temperature sugar, organic acid me-tal ion and pH. The pigments were stable(over the 60%) on the light irradiation throughout 20 days sto-rage period at room temperature and in the pesenc of Al-foil red blue green and yellow cover were rage period at room temperature and in the pesence of Al-foil red blue green and yellow cover were very stable. The pigments also showed high thermal stbility(over the 67% at 115$^{\circ}C$ 10min) at pH2.5 respectively. The pigments with added organic acid greatly increased thickness of red color. The pig-ments with added metal ions at pH 2.5 such as Na+ K+, Mg2+ Ca2+ and Mn2+ were stable throughout 20 days storage period at $25^{\circ}C$. But Cu2+ addition showed the rapidly degradation of the pigments and Al3+ addition induced the color conversion from red to redish violet. The thickness of the red color of anthocyanin pigments increased increased as the pH decreased. These results indicated that crab apple antho-cyanin pigments might be potental source of natural food colorant. colorant.

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Electrical Properties about Thermal and Water Degradation of Epoxy Powder for Bus Duct (부스닥트용 에폭시 분체도료의 열 및 수중열화에 대한 전기적 특성)

  • Kim, Hyun-Hee;Kim, Sang-Hyun
    • Fire Science and Engineering
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    • v.23 no.3
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    • pp.17-22
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    • 2009
  • Epoxy powder is being in use for insulation materials widely. Especially, in cause of coating insulation can be caused electrical fire and explosion by Joul's heat. This study has been compared and examined around breakdown, arc discharge, and V-t about insulation of Epoxy powder. Also, it has been researched about insulation which is cause of electrical fire and its basic data. According to temperature change, sample KS was stable before the Tg to be about $8{\sim}10%$ decrease in the breakdown test. In case of V-t and arc discharge, it had been kept up suitable characteristic. Also, in case of electrical characteristic, sample KS has excellent capacity.

The Effects of Electron Beam Irradiation on Thermal and Mechanical Properties of Electrospun Nylon 66 Nano-web (전기방사된 나일론66 나노웹의 열적·기계적 특성에 전자선 조사가 미치는 영향)

  • Jeun, Joon Pyo;Kang, Hyo-Kyoung;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.1
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    • pp.69-73
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    • 2011
  • Polyamide 66 (PA66) nanofibers with Triallyl cyanurate (TAC) were obtained by electrospinning of formic acid and chloroform solution. Electron beam irradiation of PA66 nanofiber with and without TAC was carried out over a range of absorbed doses (20~100 kGy) in nitrogen. The characterization of the irradiated PA66 nanofibers and PA66 nanofibers with TAC was done by scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA) and universal testing machine (UTM). The results of the SEM image analysis confirmed that the morphology of PA66 nanofibers was not altered by electron beam. The amount of TAC in PA66 nanofiber with TAC was identified by $^1H-NMR$ analysis. The degradation temperature of PA66 nanofibers with TAC at an absorbed dose of 20~100 kGy was higher than the irradiated PA66 nanofiber without TAC. On the other hand, the decreasing rate of modulus of irradiated PA66 nanofibers with TAC was less than PA66 nanofibers.

Recent Trend in Catalysis for Degradation of Toxic Organophosphorus Compounds (유기인 계열 독성화합물 분해를 위한 촉매반응의 최신 연구 동향)

  • Kye, Young-Sik;Jeong, Keunhong;Kim, Dongwook
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.513-522
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    • 2019
  • Catalysts based on organic compounds, transition metal and metal-organic frameworks (MOFs) have been applied to degrade or remove organophosphorus toxic compounds (OPs). During the last 20 years, various MOFs were designed and synthesized to suit application purposes. MOFs with $Zr_6$ based metal node and organic linker were widely used as catalysts due to their tunability for the pore size, porosity, surface area, Lewis acidic sites, and thermal stability. In this review, effect on catalytic efficiency between MOFs properties according to the structure, stability, particle size, number of connected-ligand, organic functional group, and so on will be discussed.

Preparation and Characterization of the Polymeric Antioxidant for Improving the Chemical Durability of Polymer Electrolyte Membranes (고분자 전해질 막의 화학적 내구성 향상을 위한 고분자형 산화방지제 제조 및 특성 분석)

  • LEE, BYEOL-NIM;KODIR, ABDUL;LEE, HYEJIN;SHIN, DONGWON;BAE, BYUNGCHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.308-314
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    • 2021
  • Chemical durability issue in polymer electrolyte membranes has been a challenge for the commercialization of polymer electrolyte membrane fuel cells (PEMFCs). In this study, we proposed a manufacturing method of Nafion composite membrane containing a stable polyimide antioxidant to improve the chemical durability of the membrane. The thermal casting of the Nafion solution with poly (amic acid) induced polyimide reaction. We evaluated proton conductivity, oxidative stability with ex-situ Fenton's test, and fluoride ion emission to analyze the effect of polyimide antioxidants. We confirmed that incorporating the polyimide antioxidant improves the chemical durability of the Nafion membrane while maintaining inherent proton conductivity.

Prospects on the Use of Corrosion Rate Measurement Method for Stainless Steel (스테인리스 강의 부식 측정방법의 이용과 전망)

  • Choi, Yongseon;Lee, Jaewon;Park, Eunoak;Lee, Kiyoung
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.294-301
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    • 2021
  • As the number of cases of performance degradation owing to corrosion of plant during processing in industries increases, the cost of maintaining industrial factory is increasing year by the year. Most of the materials of the facilities are consist of stainless steel (SS) such as austenite SS, ferrite SS, martensite SS, and duplex SS. Among them austenite SS is cheap and has excellent corrosion resistance and heat resistance. Corrosion is the consumption and change of metals by altering chemical and electrical reactions. The types of SS corrosion include pitting corrosion, crevice corrosion, galvanic corrosion, stress corrosion cracking, and thermal corrosion. The corrosion of SS is not only investigated various environmental factors but also the measurement of the corrosion rate. Therefore, it aims to understand comprehensive corrosion rates in various environments using qualitative, quantitative and electrochemical methods.

Measurement of fast ion life time using neutron diagnostics and its application to the fast ion instability at ELM suppressed KSTAR plasma by RMP

  • Kwak, Jong-Gu;Woo, M.H.;Rhee, T.
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1860-1865
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    • 2019
  • The confinement degradation of the energetic particles during RMP would be a key issue in success of realizing the successful energy production using fusion plasma, because a 3.5 MeV energetic alpha particle should be able to sustain the burning plasma after the ignition. As KSTAR recent results indicate the generation of high-performance plasma(${\beta}_p{\sim}3$), the confinement of the energetic particles is also an important key aspect in neutral beam driven plasma. In general, the measured absolute value of the neutron intensity is generally used for to estimating the confinement time of energetic particles by comparing it with the theoretical value based on transport calculations. However, the availability of, but for its calculation process, many accurate diagnostic data of plasma parameters such as thermal and incident fast ion density, are essential to the calculation process. In this paper, the time evolution of the neutron signal from an He3 counter during the beam blank has permitted to facilitate the estimation of the slowing down time of energetic particles and the method is applied to investigate the fast ion effect on ELM suppressed KSTAR plasma which is heated by high energy deuterium neutral beams.

Lifetime Prediction on PVC Insulation Material for IV and HIV Insulated Wire (IV와 HIV 절연 전선용 PVC 절연재료의 수명 예측)

  • Park, Hyung-Ju
    • Journal of the Korean Society of Safety
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    • v.34 no.1
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    • pp.8-13
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    • 2019
  • Weight and elongation changes of IV and HIV insulations were measured simultaneously at several given temperature of $80^{\circ}C$, $90^{\circ}C$ and $100^{\circ}C$. And the lifetime was predicted using the Arrhenius model. Based on the initial weight values, a 50% elongation reduction was seen at 6.96% for the IV insulation and 10.29% for the HIV insulation. The activation energy from the slope of the lifetime regression equation was calculated as 92.895 kJ/mol(0.9632 eV) for the IV insulation and 95.213 kJ/mol(0.9873 eV) for the HIV insulation. Also, the expected lifetime at the operating temperature of $30^{\circ}C$ to $90^{\circ}C$ is 2.02 to 94.32 years, and longer lifetime was predicted on HIV insulated wires than on IV insulated wires. As a result, it was found that the thermal characteristics of the HIV insulated wires were about 12.44% better than those of IV insulated wires under the same conditions of use.

Effect of Occupants' Active Behaviour of Environmental Control on Indoor Environment in Summer's High School Classroom (하절기 고등학교 교실에서 재실자의 적극적 환경조절행동이 실내환경에 미치는 영향)

  • Kwak, Ro-Yeul
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.5
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    • pp.181-190
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    • 2019
  • In high school classrooms, it is reported that ventilation is often insufficient, increasing health risks among students. Therefore, indoor air quality in school classrooms is very important in terms of students' health and learning abilities. In this study, the effect of window opening, which is a control mechanism for air control in summer high school classrooms, on the change in air and indoor environment of the classroom was analyzed and physical conditions of indoor and air environment were observed during the classroom course, and satisfaction of the students and teachers was assessed with questionnaires. It was found that change rate of $CO_2$ concentration in classroom was effectively reduced by carrying out activity of opening the window by active environment control activity of occupants at break time, intermission time and cleaning time. And optimal window opening by students was presented to prevent unpleasantness and degradation of indoor air quality and the effects were analyzed.

Sensitivity Analysis on Design Factor of Ground Heat Exchanger for Optimum Design of Vertical Ground Source Heat Pump System (수직밀폐형 지중열교환기의 최적설계를 위한 설계인자 영향도 분석)

  • Bae, Sangmu;Kim, Hongkyo;Nam, Yujin
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.3
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    • pp.87-93
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    • 2018
  • Ground source heat pump(GSHP) system is one of the high efficiency heat source systems which utilizes the constant geothermal energy of a underground water or soil. However, the design of conventional GSHP system in the domestic market is dependent on the experience of the designer and the installer, and it causes increase of initial installation cost or degradation of system performance. Therefore, it is necessary to develop a guideline and the optimal design method to maintain stable performance of the system and reduce installation cost. In this study, in order to optimize the GSHP system, design factors according to ground heat exchanger(GHX) type have been examine by simulation tool. Furthermore, the design factors and the correlation of a single U-tube and a double U-tube were analyzed quantitatively through sensitivity analysis. Results indicated that, the length of the ground heat exchanger was greatly influenced by grout thermal conductivity for single U-tube and pipe spacing for double U-tube.