• Title/Summary/Keyword: thermal-degradation

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An experimental study of behavior of defrosting on the fin-tube heat exchanger (핀-관 열교환기에 대한 제상 거동에 관한 실험적 연구)

  • Lee, Kwan-Soo;Kim, Kyu-Woo;Ji, Sung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.6
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    • pp.649-657
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    • 1998
  • In this study, the effects of the various conditions of frosting and defrosting on the behavior of defrosting in a fin-tube heat exchanger have been examined experimentally. The electric heater is used for defrosting in a fin-tube heat exchanger It is shown that there are several local maxima in the water draining rate. The amount of residual water on the heat exchanger after the completion of defrosting is kept constant due to surface tension on the heat exchanger. Without considering the degradation of the thermal performance due to the frosting, the defrosting efficiency is improved with increasing amount of the frost irrespective of the frosting condition. The defrosting behavior is affected by the frosting density as well as the frost accumulation, which vary with the experimental operating conditions during the frosting period. The heat loss to the surrounding air decreases, and the melting and defrosting efficiencies show high values with decreasing heat input.

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Identification of the Genes Involved in the Fruiting Body Production and Cordycepin Formation of Cordyceps militaris Fungus

  • Zheng, Zhuang-Li;Qiu, Xue-Hong;Han, Ri-Chou
    • Mycobiology
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    • v.43 no.1
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    • pp.37-42
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    • 2015
  • A mutant library of Cordyceps militaris was constructed by improved Agrobacterium tumefaciens-mediated transformation and screened for degradation features. Six mutants with altered characters in in vitro and in vivo fruiting body production, and cordycepin formation were found to contain a single copy T-DNA. T-DNA flanking sequences of these mutants were identified by thermal asymmetric interlaced-PCR approach. ATP-dependent helicase, cytochrome oxidase subunit I and ubiquitin-like activating enzyme were involved in in vitro fruiting body production, serine/threonine phosphatase involved in in vivo fruiting body production, while glucose-methanol-choline oxidoreductase and telomerase reverse transcriptase involved in cordycepin formation. These genes were analyzed by bioinformatics methods, and their molecular function and biology process were speculated by Gene Ontology (GO) analysis. The results provided useful information for the control of culture degeneration in commercial production of C. militaris.

Fire Retardancy and Mechanical Properties of Paper Sludge-Wood Particle Mixed Board (제지 슬러지-목재 파티클 혼합보드의 내화성과 기계적 성질)

  • Son, Jung-Il;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.54-65
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    • 1994
  • This research carried out to investigate the effects of inorganic materials in paper sludge on the thermal degradation and of paper sludge addition on physical and mechanical properties of paper sludge-wood particle mixed boards in comparison with unmodified particleboards. Also these unmodified particleboards and paper sludge-wood particle mixed boards were soaked in aqueous solutions of fire-retardant chemicals(diammonium phosphate and zinc chloride), and their fire retardancy were tested by oxygen index method and ISO ignition test to determine the feasibility of paper sludge, industrial waste, as a recyclable resource in fabrication of fire-resisting panels for building material. Since the redrying of fire-retardant treated particleboards and paper sludge-wood particle mixed boards were made by press drying method, this process was a simple and effective method. On the other hand, flexural bending strength and internal bonding strength were also analysed to evaluate mechanical properties through standard method.

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Friction and Wear Behavior of Carbon/Carbon Composites for Aircraft Brake Material (항공기 브레이크 재료용 탄소/탄소 복합재료의 마찰 및 마모 거동)

  • 우성택;윤재륜
    • Tribology and Lubricants
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    • v.9 no.1
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    • pp.62-69
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    • 1993
  • Friction and wear behavior of a carbon/carbon composite material for aircraft brake material was experimentally investigated. Friction and wear test setup was designed and built for the experiment. Friction and wear tests were conducted under various sliding conditions. Friction coefficients were measured and processed by a data acquisition system and amount of wear measured by a balance. Stainless steel disk was used as the counterface material. Temperature was also measured by inserting thermocouple 2.5 mm beneath the sliding surface of the carbon/carbon composite specimen. Wear surfaces were observed by SEM, and analyzed by EDAX. The experimental results showed that sliding speed and normal force did not have significant effects on friction coefficient and wear factor of the composite. Temperature increase just below the surface was not large enough to cause any thermal degradation or oxidation which occurred at higher temperature when tested by TGA. Wear film was generated both on the specimen and on the counterface at relatively low sliding speed but cracks, grooves, and wear debris were observed at high sliding speed. Friction coefficient remained almost constant when the sliding speed or normal load was varied. It is believed that the adhesive and abrasive components contributed mainly to the friction coefficient. Wear behavior at low sliding speed was governed by wear film formation and adhesive wear mechanism. At high speed, fiber orientation, ploughing by counterface asperities, and fiber breakage dominated wear of the carbon/carbon composite.

Effects of constituents in CNT pastes on the field emission characteristics of carbon nanotubes

  • Yoon, Seung-Il;Kim, Sam-Soo;Lee, Yang-Kyu;Kim, Tae-Kwon;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1206-1209
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    • 2006
  • Carbon nanotubes (CNTs) have been significantly used for the field emitters for display applications. However, the lifetime of CNT emitters which are formed by screen printing technique is not guaranteed yet, because the constituents in CNT paste affect the lifetime of CNTs. The CNT pastes for screen printing are normally composed of organic vehicles (nitro cellulose, ethyl cellulose, etc) and additives (glass frits, ITO, etc) with CNTs. In this study, the effects of constituents in CNT pastes on the lifetime and emission characteristics of CNTs were investigated by thermal and electrical analysis. Use of glass frits worsened the lifetime and electron emission of CNTs. However, an addition of ITO to CNT paste rather improved the lifetime of CNTs. Degradation of CNTs was small when nitro cellulose was used in CNT paste as an organic vehicle.

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Effect of Hydrogen Radicals for Ion Implanted CVD Diamond Using Remote Hydrogen Plasma Treatment(RHPT)

  • Won, Jaihyung;Hatta, Akimitsu;Yagi, Hiromasa;Wang, Chunlei;Jiang, Nan;Jeon, Hyeongmin;Deguehi, Masahiro;Kitabatake, Makoto;Ito, Toshimichi;Sasaki, Takatomo;Hiraki, Akio
    • The Korean Journal of Ceramics
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    • v.4 no.1
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    • pp.15-19
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    • 1998
  • Defects formation of Chemical Vapor Deposition (CVD) diamond on $^4He^{2+}$ irradiation and after remote hydrogen plasma treatment(RHPT) were investigated by cathodoluminescence(CL). As calculated in the TRIM simulation, the light elements of $^4He^{2-}$ can be penetrated into the diamond bulk structure at 3~4 $\mu\textrm{m}$ depth. The effects of the implantation region were observed when 5 keV~20 keV electron energy (insight 0.3~4.0$\mu\textrm{m}$) of CL measurement was irradiated to diamond at temperature 80 K. After the RHPT, rehybridization of irradiation damaged diamond was studied. The intensity of 5RL center(intrinsic defect of C) was diminished. The 2.16 eV center (N-V center) occurring usually by annealing could not be seen after RHPT. The diamond was rehybridized by hydrogen radicals without etching and thermal degradation by the RHPT.

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A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(I) (산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(I))

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.18 no.1
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    • pp.49-60
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    • 2009
  • Fabrication and oxidants formation of 1 and 2 component metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru, Pt, Sn, Sb and Gd) were used for the 1 and 2 component electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1 h. The removed RhB per 2 min and unit W for one component electrode decreased in the following sequences: Ru/Ti>Sb/Ti>Pt/Ti>Gd/Ti>Sn/Ti. The concentration of oxidants generated in 1 and 2 component electrodes was in the order of: $ClO_2$> free Cl>$H_2O_2>O_3$. OH radical was not generated from in entire one and two component electrodes. RhB degradation rate and generated oxidants of the Ru-Sn=9:1 electrode was higher than that of the two component electrode. The exact relationship between the removal of RhB and the generated oxidants concentration was not obvious. However, it was assumed that electrode with high RhB decolorization had high oxidant concentration.

Characteristics of Sr0.92Y0.08TiO3-δ Anode in Humidified MethaneFuel for Intermediate Temperature Solid Oxide Fuel Cells

  • Park, Eun Kyung;Yun, Jeong Woo
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.33-40
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    • 2016
  • Sr0.92Y0.08TiO3-δ (SYT) was investigated as an alternative anode in humidified CH4 fuel for SOFCs at low temperatures (650 ℃-750 ℃) and compared with the conventional Ni/yttria-stabilized zirconia (Ni/YSZ) anode. The goal of the study was to directly use a hydrocarbon fuel in a SOFC without a reforming process. The cell performance of the SYT anode was relatively low compared with that of the Ni/YSZ anode because of the poor electrochemical catalytic activity of SYT. In the presence of CH4 fuel, however, the cell performance with the SYT anode decreased by 20%, in contrast to the 58% decrease in the case of the Ni/YSZ anode. The severe degradation of cell performance observed with the Ni/YSZ anode was caused by carbon deposition that resulted from methane thermal cracking. Carbon was much less detected in the SYT anode due to the catalytic oxidation. Otherwise, a significant amount of bulk carbon was detected in the Ni/YSZ anode.

Mechanical Properties of Carbon/Phenolic Ablative Composites (Carbon/Phenolic 내열 복합재료의 기계적 특성)

  • Kim, P.W.;Hong, S.H.;Kim, Y.C.;Yeh, B.H.;Jung, B.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.160-163
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    • 1999
  • The mechanical properties and failure behaviour of carbon/phenolic composites were inverstigated by tension and compression. Carbon/phenolic composites were fabricated by infiltration of matrix into 8 harness satin woven fabric of PAN-based carbon fibers. The tensile and compressive tests were performed at 25℃ under air atmosphere and, at 400℃ and 700℃ under N₂ atmosphere. The tensile strengths of carbon/phenolic composites in with-laminar/0° warp direction were about 10 times higher than those in with-laminar/45° warp direction, which was analyzed due to a change of fracture mode from fiber pull-out by shear to tensile fracture of fibers. The fracture of carbon/phenolic composites in with-laminar/45° direction was analyzed due to delamination by buckling. Tensile and compressive strength of carbon/phenolic composites decreased to about 50% at 400℃, and to about 10% at 700℃ compared to that at room temperature. The main reason for the decrease of tensile or compressive strength with increasing temperature was analyzed due to a reduction of bond strength between fibers and matrix resulting from thermal degradation of phenolic resin.

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Development and mechanical properties of bagasse fiber reinforced composites

  • Cao, Yong;Goda, Koichi;Shibata, Shinichi
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.283-298
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    • 2007
  • Environment-friendly composites reinforced with bagasse fiber (BF), a kind of natural fiber as the remains from squeezed sugarcane, were fabricated by injection molding and press molding. As appropriate matrices for injection molding and press molding, polypropylene (PP) and polycaprolactone-cornstarch (PCL-C) were selected, as a typical recyclable resin and biodegradable resin, respectively. The mechanical properties of BF/PP composites were investigated in view of fiber mass fraction and injection molding conditions. And the mechanical properties and the biodegradation of BF/PCL composites were also evaluated. In the case of injection molding, the flexural modulus increased with an increase in fiber mass fraction, and the mechanical properties decreased with an increase in cylinder temperature due to the thermal degradation of BF. The optimum conditions increasing the flexural properties and the impact strength were $90^{\circ}C$ mold temperature, 30 s injection interval, and in the range of 165 to $185^{\circ}C$ cylinder temperature. On the other hand, as to BF/PCL-C fully-green composites, both the flexural properties and the impact strength increased with an increase in fiber mass fraction. It is considered that the BF compressed during preparation could result in the enhancement in mechanical properties. The results of the biodegradability test showed the addition of BF caused the acceleration of weight loss, which increased further with increasing fiber content. This reveals that the addition and the quantities of BF could promote the biodegradation of fully-green composites.