• Journal of Welding and Joining
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• 제32권3호
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• pp.74-80
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• 2014

Due to environmental regulations (RoHS, WEEE and ELV) of the European Union, electronics and automotive electronics have to eliminate toxic substance from their devices and system. Especially, reliability issue of lead-free solder joint is increasing in car electronics due to ELV (End-of-Life Vehicle) banning from 2016. We have prepared engine control unit (ECU) modules soldered with Sn-40Pb and Sn-3.0Ag-0.5Cu (SAC305) solders, respectively. Degradation characteristics of solder joint strength were compared with various conditions of automobile environment such as cabin and engine room. Thermal cycle test (TC, $-40^{\circ}C$ ~ ($85^{\circ}C$ and $125^{\circ}C$), 1500 cycles) were conducted with automotive company standard. To compare shear strength degradation rate with eutectic and Pb-free solder alloy, we measured shear strength of chip components and its size from cabin and engine ECU modules. Based on the TC test results, finally, we have known the difference of degradation level with solder alloys and use environmental conditions. Solder joints degradation rate of engine room ECU is superior to cabin ECU due to large CTE (coefficient of thermal expansion) mismatch in field condition. Degradation rate of engine room ECU is 50~60% larger than cabin room electronics.

• Nuclear Engineering and Technology
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• 제55권12호
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• pp.4561-4569
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• 2023

A correct understanding of vibration-based degradation is crucial from the standpoint of maintenance for Steam Generators (SG) as crucial mechanical equipment in nuclear power plants. This study has established a novel approach to developing a model for investigating tube bundle degradation according to crack growth caused by two-phase Flow-Induced Vibration (FIV). An important step in the approach is to calculate the two-phase flow field parameters between the SG tube bundles in various zones using the porous media model to determine the velocity and vapor volume fraction. Afterward, to determine the vibration properties of the tube bundles, the Fluid-Solid Interaction (FSI) analysis is performed in eighteen thermal-hydraulic zones. Tube bundle degradation based on crack growth using the sixteen most probable initial cracks and within each SG thermal-hydraulic zone is performed to calculate useful lifetime. Large Eddy Simulation (LES) model, Paris law, and Wiener process model are considered to model the turbulent crossflow around the tube bundles, simulation of elliptical crack growth due to the vibration characteristics, and estimation of SG tube bundles degradation, respectively. The analysis shows that the tube deforms most noticeably in the zone with the highest velocity. As a result, cracks propagate more quickly in the tube with a higher height. In all simulations based on different initial crack sizes, it was observed that zone 16 experiences the greatest deformation and, subsequently, the fastest degradation, with a velocity and vapor volume fraction of 0.5 m/s and 0.4, respectively.

• Nuclear Engineering and Technology
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• 제54권12호
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• pp.4514-4521
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• 2022

In this study, the effects of heat and radiation on the degradation behaviour of fluoroelastomer under simulated normal operation and a severe accident environment were investigated using sequential testing of gamma irradiation and thermal degradation. Tensile properties and Shore A hardness were measured, and thermogravimetric analysis was used to evaluate the degradation behaviour of fluoroelastomer. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the structural changes of the fluoroelastomer. Heat and radiation generated in nuclear power plant break and deform the chemical bonds, and fluoroelastomer exposed to these environments have decreased C-H and functional groups that contain oxygen and double bonds such as C-O, C=O and C=C were generated. These functional groups were formed by auto oxidation by reacting free radicals generated from the cleaved bond with oxygen in the atmosphere. In this auto oxidation reaction, crosslinks were generated where bonded to each other, and the mobility of molecules was decreased, and as a result, the fluoroelastomer was hardened. This hardening behaviour occurred more significantly in the severe accident environment than in the normal operation condition, and it was found that thermal stability decreased with the generation of unstable structures by crosslinking.

• 청정기술
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• 제15권3호
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• pp.186-193
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• 2009

본 연구에서는 상용운전 중에 있는 반연속식 로터리 킬른형 열분해반응기에 지자체에서 발생되는 필름형 혼합 폐플라스틱을 투입한 후 열분해하여 얻은 저급의 열분해유를 세 형태의 반응온도 프로그램에서 분해반응시키고, 여기에서 얻어지는 생성유의 특성을 논의하였다. 원료인 저급 열분해유의 특성은 원소분석 및 발열량 분석, SIMDIST 분석으로 확인하였고, 각 반응온도 프로그램에 따른 분해반응 결과는 각 성분의 수율분포, 액상 생성물의 누적수율과 생성비 등으로 논의하였다. 연구결과는 한 단계 반응온도 프로그램에 비해 다단계 반응온도 프로그램의 경우가 원하는 생성물인 오일수율이 높았고, 상대적으로 잔류물의 수율은 낮게 나타났다. 연속적인 열분해반응에서 반응온도 프로그램은 생성물의 수율분포 등 생성유 특성에 많은 영향을 주었다.

• 마이크로전자및패키징학회지
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• 제22권1호
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• pp.27-34
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• 2015

The correlation between crack propagation and localized recrystallization are compared in a series of cross section analyses on thermal cycled edgebond and underfilm material applied wafer level chip scale package (WLCSP) components with a baseline of no-material applied WLCSP components. The results show that the crack propagation distribution and recrystallization region correlation can explain potential degradation mechanisms and support the damage accumulation history in a more efficient way. Edgebond material applied components show a shift of damage accumulation to a more localized region, thus potentially accelerated the degradation during thermal cycling. Underfilm material applied components triggered more solder joints for a more wider distribution of damage accumulation resulting in a slightly improved thermal cycling performance compared to no-material applied components. Using an analysis on localized distribution of recrystallized areas inside the solder joint showed potential value as a new analytical approach.

• 제어로봇시스템학회논문지
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• 제22권6호
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• pp.463-469
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• 2016

This paper presents a composite camera calibration method to determine thermal degradation of power distribution equipment by combining an infrared (IR) camera and a color camera. A calibration jig was first constructed to match the properties of the two cameras. Our calibration and visualization techniques allow for the display of two images, one from the color camera and the other from the IR camera with different field of views (FOVs), on the screen at the same time. To confirm its validity, several case studies have been developed to analyze thermal deterioration limits of indoor and outdoor power distribution facilities.

• 한국표면공학회지
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• 제39권4호
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• pp.147-152
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• 2006

Failure mechanisms of electron beam physical vapor deposited thermal barrier coatings(EB-PVD TBCs) that occur during thermal cyclic oxidation were investigated. The investigations include microstructural degradation of NiCrAIY bond coat, thermally grown oxides(TGOs) along the ceramic top coat-substrate interface and fracture path within TBCs. The microstructural degradation of the bond coat during cyclic oxidation created Al depleted zones, resulting in reduction of NiAl and ${\gamma}$-Ni solid solution phase. It was observed that the fracture took placed primarily within the TGOs or at the interfaces between TGOs and bond coat.

• 한국세라믹학회지
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• 제52권1호
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• pp.23-27
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• 2015

Recently, the use of ion-exchange strengthened glass has increased sharply, as it is now used as the cover glass for smart phone devices. Therefore, many researchers are focusing on methods that can be used to strengthen ion-exchange glass. However, research on how the improved strength can be maintained under thermal environment of device manufacturing is still insufficient. We tested the degradation of the characteristics of ion-exchange soda-lime glass samples, including their surface compressive stress characteristics, the depth of the ion-exchange layer (DOL), flexural strength, hardness, and modulus of rupture (MOR) values. Degradation of the characteristics of the ion-exchange glass samples occurred when they were heat-treated at a temperature that exceeded $350^{\circ}C$.

• 대한기계학회논문집A
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• 제31권3호
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• pp.295-303
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• 2007

Degradation behaviors of filament-winded composites have been evaluated under the accelerated environmental test of high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP showed little degradation while GFRP did high reduction by 25% under the influence of high temperature and water However for water-immersed $90^{\circ}$ composites tensile strength of both CFRP and GFRP showed high reduction. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites. In case of shear strength and modulus, both CFRP and GFRP showed high reduction by water-Immersion test but did a slight increase by high temperature and thermal impact conditions.

• 한국세라믹학회지
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• 제50권6호
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• pp.523-527
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• 2013

Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.