• 제목/요약/키워드: thermal-degradation

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지방 조직 유화를 위한 집속형 초음파 변환기 설계 및 제작에 관한 연구 (A Study on the Design and Fabrication of Fat Emulsification Adapted Focused Ultrasonic Transducer)

  • 김주영;김재영;정현두;노시철;문창수;문치웅;최흥호
    • 전자공학회논문지
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    • 제52권11호
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    • pp.127-134
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    • 2015
  • 초음파를 이용한 조직 자극 기법은 지속적으로 연구, 개발되고 있으며, 최근 미용 및 비만 치료에 대한 관심이 높아짐에 따라 초음파 지방 제거술에 대한 다양한 연구가 진행되고 있다. 본 연구에서는 초음파 지방 제거술을 위한 초음파 변환기를 설계하고, 조사조건에 따른 집속영역의 형태와 열 변성 영역을 시뮬레이션 하였다. 이를 통하여 제원을 검증하였으며, 제작된 변환기의 초음파 방사 특성 및 가열 특성을 측정하여 유효성을 평가하였다. 또한 복합 구조의 매질을 대상으로 초음파 가열 특성을 예측하였으며 제작된 변환기의 집속점 형태 및 가열 특성이 지방층을 충분히 유화시킬 수 있을 것으로 판단하였다. 본 연구의 결과는 보다 효율적이고 안전한 초음파 지방 제거술의 기초 연구로 활용될 것으로 사료된다.

Post-fire Repair of Concrete Structural Members: A Review on Fire Conditions and Recovered Performance

  • Qiu, Jin;Jiang, Liming;Usmani, Asif
    • 국제초고층학회논문집
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    • 제10권4호
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    • pp.323-334
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    • 2021
  • Concrete structures may rarely collapse in fire incidents but fire induced damage to structural members is inevitable as a result of material degradation and thermal expansion. This requires certain repairing measures to be applied to restore the performance of post-fire members. A brief review on investigation of post-fire damage of concrete material and concrete structural members is presented in this paper, followed by a review of post-fire repair research regarding various types of repairing techniques (FRP, steel plate, and concrete section enlargement) and different type of structural members including columns, beams, and slabs. Particularly, the fire scenarios adopted in these studies leading to damage are categorized as three levels according to the duration of gas-phase temperature above 600℃ (t600). The repair effectiveness in terms of recovered performance of concrete structural members compared to the initial undamaged performance has been summarized and compared regarding the repairing techniques and fire intensity levels. The complied results have shown that recovering the ultimate strength is achievable but the stiffness recovery is difficult. Moreover, the current fire loading scenarios adopted in the post-fire repair research are mostly idealized as constant heating rates or standard fire curves, which may have produced unrealistic fire damage patterns and the associated repairing techniques may be not practical. For future studies, the realistic fire impact and the system-level structural damage investigation are necessary.

유기 리간드 제어를 통한 고분산 팔라듐 나노 촉매의 합성 및 음이온교환막 연료전지를 위한 산소 환원 반응 특성 분석 (Synthesis of Highly Dispersed Pd Nanocatalysts Through Control of Organic Ligands and Their Electrochemical Properties for Oxygen Reduction Reaction in Anion Exchange Membrane Fuel Cells)

  • 성후광;;장정희;정남기
    • 한국재료학회지
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    • 제28권11호
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    • pp.633-639
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    • 2018
  • In anion exchange membrane fuel cells, Pd nanoparticles are extensively studied as promising non-Pt catalysts due to their electronic structure similar to Pt. In this study, to fabricate Pd nanoparticles well dispersed on carbon support materials, we propose a synthetic strategy using mixed organic ligands with different chemical structures and functions. Simultaneously to control the Pd particle size and dispersion, a ligand mixture composed of oleylamine(OA) and trioctylphosphine(TOP) is utilized during thermal decomposition of Pd precursors. In the ligand mixture, OA serves mainly as a reducing agent rather than a stabilizer since TOP, which has a bulky structure, more strongly interacts with the Pd metal surface as a stabilizer compared to OA. The specific roles of OA and TOP in the Pd nanoparticle synthesis are studied according to the mixture composition, and the oxygen reduction reaction(ORR) activity and durability of highly-dispersed Pd nanocatalysts with different particles sizes are investigated. The results of this study confirm that the Pd nanocatalyst with large particles has high durability compared to the nanocatalyst with small Pd nanoparticles during the accelerated degradation tests although they initially indicated similar ORR performance.

Anti-Fogging, Photocatalytic and Self-Cleaning Properties of TiO2-Transparent Coating

  • ;김정식
    • 한국재료학회지
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    • 제31권1호
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    • pp.8-15
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    • 2021
  • Transparent, photocatalytic, and self-cleaning TiO2 thin film is developed by TiO2 sol-gel coating on glass and polycarbonate (PC) substrates. Acetyl acetone (AcAc) suppresses the precipitation of TiO2 by forming a yellowish (complex) transparent sol-gel. XPS analysis confirms the presence of Ti2p and O1s in the thin films on glass and PC substrates. The TiO2-sol is prepared by stabilizing titanium (IV) isopropoxide (TTIP) with diethylamine and methyl alcohol. The addition of AcAcsilane coupling solution to the TiO2-sol instantaneously turns to yellowish color owing to the complexing of titanium with AcAc. The AcAc solution substantially improves the photocatalytic property of the TiO2 coating layer in MB solutions. The coated TiO2 film exhibits super hydrophilicity without and with light irradiation. The TiO2 thin film stabilized by adding 8.7 wt% AcAc shows the highest photo-degradation for methylene blue (MB) solution under UV light irradiation. Also, the optimum photocatalytic activity is obtained for the 8.7 wt% AcAc-stabilized TiO2 coating layer calcined at 450 ℃. The thin-films on glass exhibit fast self-cleaning from oleic acid contamination within 45 min of UV-light irradiation. The appropriate curing time at 140 ℃ improves the anti-fogging and thermal stability of the TiO2 film coated on PC substrate. The watermark-free PC substrate is particularly beneficial to combat fogging problems of transparent substrates.

저주파수대의 원자로 출력신호 점검을 위한 대수 카운트레이트 회로 (Log Count Rate Circuits for Checking Electronic Cards in Low Frequency Band Reactor Power Monitoring)

  • 김종호;최규식
    • 한국항행학회논문지
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    • 제24권6호
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    • pp.557-565
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    • 2020
  • 원자로의 출력신호를 감시하는 노외중성자속감시계통의 열화상태를 점검하기 위해서는 원자로에서 방출되는 중성자 펄스를 감지하여 처리하는 전자카드에서 주파수형태로 감지하여 전압으로 변환한 후 대수 형태의 직류전압 값을 얻는 방법을 이용한다. 실제로 원전에서 적용하는 방법으로서는 주파수 카운터와 flip-flop 조합으로 이 과정을 수행하거나, 또는 다이오드펌프와 캐패시터의 조합을 이용하는 방법을 쓰며, 아직도 이 방법이 일반적으로 쓰이고 있다. 이 방법들은 높은 주파수에서는 신뢰성이 높으나 낮은 주파수에는 오차가 크고 측정시간도 오래 걸린다는 문제점이 있다. 따라서 본 연구에서는 고출력대의 고주파수 범위뿐만 아니라 중위출력 범위 주파수대, 그리고 극히 저출력 범위에 속해 있는 취약주파수대인 0.21 Hz~2 kHz 범위의 낮은 주파수대에 이르는 광범위한 주파수를 대수직류전압으로 신뢰성 높게 변환시킬 수 있는 장치를 개발하였다. 개발된 선택회로의 신뢰성을 확인하기 위하여 원전에서 사용되는 실제의 데이터값을 적용하여 테스트하였으며, 그 결과를 분석하여 선택회로의 정당성을 입증하였다.

Micro Shell을 이용한 철기 문화재 복원용 충전제의 사용성 연구 (A Study of Usability of Micro Shell as a Filler for Restoration of Iron Objects)

  • 이현지;위광철
    • 박물관보존과학
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    • 제27권
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    • pp.91-102
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    • 2022
  • 철기 문화재 복원에 사용되고 있는 실리카 계열의 무기질 충전제는 열팽창률감소, 흐름성 개선 등의 기능성 부여를 목적으로 사용되고 있다. 그러나 충전제의 양이 많을 수록 복원재의 물성저하 및 황변 현상 촉진의 원인이되며, 결과적으로 재처리로 이어져 유물의 피로도를 상승시키는 결과를 초래한다. 따라서 복원제와 충전제의 혼합 정량화 및 황변성 연구 필요성이 강조될 수 밖에 없다. 이를 보완하기 위해 실리카계 경량 충전제인 Micro Shell을 비교군으로 물성연구를 진행하였다. 실험 결과 기존에 사용하던 충전제에 비해 Micro Shell이 황변도 발생 수치가 최대 34% 낮았으며, 충전제의 배합양에 따라서 공통적으로 접착력과 비중의 물성 수치값이 좋은 것을 확인하였다. 본 연구 결과 Micro Shell의 사용 가능성에 대해 확인하였다.

Effect of degumming conditions on the fluorescence intensity of fluorescent silk cocoons: A combined experimental and molecular dynamics study

  • Chan Yeong, Yu;Ezekiel Edward, Nettey-Oppong;Elijah, Effah;Su Min, Han;Seong-Wan, Kim;Seung Ho, Choi
    • International Journal of Industrial Entomology and Biomaterials
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    • 제45권2호
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    • pp.56-69
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    • 2022
  • Silk is a unique natural biopolymer with outstanding biocompatibility, high mechanical strength, and superior optical transparency. Due to its excellent properties, silk has been widely reported as an ideal biomaterial for several biomedical applications. Recently, fluorescent silk protein, a variant of native silk, has been reported as a biophotonic material with the potential for bioimaging and biosensing. Despite the realization of fluorescent silk, the traditional degumming process of fluorescence silk is crude and often results in fluorescence loss. The loss of fluorescent properties is attributed to the sensitivity of silk fibroin to temperature and solvent concentration during degumming. However, there is no comprehensive information on the influence of these processing parameters on fluorescence evolution and decay during fluorescent silk processing. Therefore, we conducted a spectroscopic study on fluorescence decay as a function of temperature, concentration, and duration for fluorescent silk cocoon degumming. Sodium carbonate solution was tested for degumming the fluorescent silk cocoons with different concentrations and temperatures; also, sodium carbonate solution is combined with Alcalase enzyme and triton x-100 to find optimal degumming conditions. Additionally, we conducted a molecular dynamics study to investigate the fundamental effect of temperature on the stability of the fluorescent protein. We observed degumming temperature as the prime source of fluorescent intensity reduction. From the MD study, fluorescence degradation originated from the thermal agitation of fluorescent protein Cα atoms and fluctuations of amino acid residues located in the chromophore region. Overall, degumming fluorescent silk with sodium carbonate and Alcalase enzyme solution at 25 ℃ preserved fluorescence.

Researched and Analyzed Variables for Pollution Waters around the "Kosova B" Thermal Power Plant

  • Musliu, Adem;Musliu, Arber;Baftiu, Naim
    • International Journal of Computer Science & Network Security
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    • 제22권9호
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    • pp.109-116
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    • 2022
  • The energy corporation of Kosovo continuously monitors and analyzes the impact of its own activities on the environment. Regarding the environmental situation, energy corporation of Kosovo- ECK regularly informs and reports objectively to the competent state institutions, local municipal institutions and interested parties. ECK, through numerous contacts with the competent authorities, firstly with different ministers, harmonizes the positions regarding environmental issues in the direction of achieving certain environmental standards or legal requirements in order to gradually be in accordance with them, based on the real possibilities, especially the financial ones. From this point of view, the environmental issue is very sensitive, quite complex and represents one of the biggest challenges of society currently and in the future. The researched variables show a continuous increase in the need for electricity production in Kosovo and this increase in production conditions a wide range of environmental impacts both at the local, regional and global levels. The aim of the work is to reduce the emission of pollutants through the main variables without inhibiting the economic development of the country, i.e. to bring the pollution as a result of the activities of the ECK operation into compliance with the permitted environmental norms. As a result of ECK's operational activities, the following follows: Air pollution mainly as a result of emissions from TCs in the air, transport, etc. Water pollution - as a result of technological water discharges, Land degradation - as a result of surface mining activities of the entire mining area. The purpose of the paper is to research and analyze the main water variables in the area of the Kosova B power plant, which is to determine the degree of their pollution from the activities of the power plants, as well as to assess the real state of surface water quality and control the degree of pollution of these waters. Methodology of the work: The analyzes of the water samples were done in the company Institute "INKOS" JSC by simultaneous methods using different reagents.

중수로 원전 가상의 mSGTR과 SBO 다중 사건에 대한 MARS-KS 코드 분석 (Analysis on Hypothetical Multiple Events of mSGTR and SBO at CANDU-6 Plants Using MARS-KS Code)

  • 유선오;이경원;백경록;김만웅
    • 한국압력기기공학회 논문집
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    • 제17권1호
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    • pp.18-27
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    • 2021
  • This study aims to develop an improved evaluation technology for assessing CANDU-6 safety. For this purpose, the multiple steam generator tube rupture (mSGTR) followed by an unmitigated station blackout (SBO) in a CANDU-6 plant was selected as a hypothetical event scenario and the analysis model to evaluate the plant responses was envisioned into the MARS-KS input model. The model includes logic models for controlling the pressure and inventory of the primary heat transport system (PHTS) decreasing due to the u-tubes' rupture, as well as the main features of PHTS with a simplified model for the horizontal fuel channels, the secondary heat transport system including the shell side of steam generators, feedwater and main steam line, and moderator system. A steady state condition was successfully achieved to confirm the stable convergence of the key parameters. Until the turbine trip, the fuel channels were adequately cooled by forced circulation of coolant and supply of main feedwater. However, due to the continuous reduction of PHTS pressure and inventory, the reactor and turbine were shut down and the thermal-hydraulic behaviors between intact and broken loops got asymmetric. Furthermore, as the conditions of low-flow coolant and high void fraction in the broken loop persisted, leading to degradation of decay heat removal, it was evaluated that the peak cladding temperature (PCT) exceeded the limit criteria for ensuring nuclear fuel integrity. This study is expected to provide the technical bases to the accident management strategy for transient conditions with multiple events.

Interaction study of molten uranium with multilayer SiC/Y2O3 and Mo/Y2O3 coated graphite

  • S.K. Sharma;M.T. Saify;Sanjib Majumdar;Palash K. Mollick
    • Nuclear Engineering and Technology
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    • 제55권5호
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    • pp.1855-1862
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    • 2023
  • Graphite crucibles are used for melting uranium and its alloys in VIM furnace. Various coating materials namely Al2O3, ZrO2, MgO etc. are applied on the inner surface of the crucibles using paint brush or thermal spray technique to mitigate U-C interaction. These leads to significant amount of carbon pick-up in uranium. In this study, the attempts are made to develop multilayer coatings comprising of SiC/Y2O3 and Mo/Y2O3 on graphite to study the feasibility of minimizing U-C interaction. The parameters are optimized to prepare SiC coating of about 70㎛ thickness using CVD technique on graphite coupons and subsequently Y2O3 coating of about 250㎛ thickness using plasma spray technique. Molybdenum and Y2O3 layers were deposited using plasma spray technique with 70㎛ and 250㎛ thickness, respectively. Interaction studies of the coated graphite with molten uranium at 1450℃ for 20 min revealed that Y2O3 coating with SiC interlayer provides physical barrier for uranium-graphite interaction, however, this led to the physical separation of coating layer. Y2O3 coating with Mo interlayer provided superior barrier effect showing no degradation and the coatings remained intact after interaction tests. Therefore, the Mo/Y2O3 coating was found to be a promising solution for minimizing carbon pick-up during uranium/uranium alloy melting.