• 제목/요약/키워드: thermal-degradation

Search Result 1,125, Processing Time 0.032 seconds

Epoxidized Polybutadiene as a Thermal Stabilizer for Poly(3-hydroxybutyrate). 1. Effect of Epoxidation on the Thermal Properties of Polybutadiene

  • Park, Ju-Yol;Lee, Jong-Keun;Park, Won-Ho
    • Fibers and Polymers
    • /
    • v.3 no.3
    • /
    • pp.109-112
    • /
    • 2002
  • Polybutadiene(PB) was epoxidized to various extents with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. The thermal properties of the epoxidized PBs were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). As a result of epoxidation the glass transition temperature (Tg) of PB increased by approximately $0.8^{\circ}$ for each 1 mol% of epoxidation. The thermal decomposition of the epoxidised PBs occurred in two-step process, while that of PB exhibited apparent one-step degradation process.

A Study on the Properties of FRP Insulation Materials by Thermal-Accelerated Degradation (고온 가속열화에 의한 FRP 절연재료의 특성변화에 관한 연구)

  • Lee, B.S.;Chung, U.N.;Han, S.O.;Park, C.S.;Kang, D.H.;Na, D.G.;Lee, D.C.
    • Proceedings of the KIEE Conference
    • /
    • 1997.07d
    • /
    • pp.1543-1545
    • /
    • 1997
  • In this work, properties of FRP insulation materials by thermal-accelerated degradation were investigated. Usually, most degradations cause the hydrophilic to decrease the contact angle and surface properties. But, in this work on thermal-degradated FRP, we can confirm the introduction of hydrophobic properties by cross-linking and the ablation of small-molecules rather than chain scission and oxidation. Hydrophobic introduction in thermal-degradated FRP caused the increase of electrical insulation on treated FRP surface. But, Tensile strength decreased steeply on FRP being exposed higher temperature.

  • PDF

Analysis of thermal characteristics of the ZnO arrester block (산화아연 피뢰기 소자의 열적 특성 분석)

  • Lee, Bok-Hee;Lee, Su-Bong;Lee, Seung-Ju;Jeon, Byung-Wook;Kim, Dong-Sung;Jung, Dong-Cheol
    • Proceedings of the KIEE Conference
    • /
    • 2007.07a
    • /
    • pp.1393-1394
    • /
    • 2007
  • This paper presents the thermal characteristics of ZnO arrester blocks under the AC voltage. The leakage currents of ZnO arrester blocks were measured as a function of time. The temperature distribution of ZnO arrester blocks were observed by the forward looking infrared camera. The degradation and thermal runaway of ZnO arrester blocks were related to the temperature of ZnO arrster blocks which depended on heat generation and dissipation. As a result, the degradation and thermal runaway of ZnO arrester blocks are associated with the temperature and leakage current of ZnO arrester blocks.

  • PDF

Temperature Distribution Monitoring of Transformer (변압기 온도 변화특성 모니터링)

  • Lee, Woo-Sun;Jung, Chan-Moon;Son, Dong-Min;Seo, Young-Jin;Lim, Jang-Sub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.08a
    • /
    • pp.69-72
    • /
    • 2002
  • The conventional thermal insulator and power transformer testing is widely used in surface aging measurement of outside insulator because those testing can carry out very short time in Lab testing. Also thermal testing is able to offer the standard judgement of relative degradation level of outside HV machine. There it is very useful method compare to previous conventional thermal testing method and effective Lab testing method. But surface discharges(SD) have very complex characteristics of discharge pattern so it is required estimation research to development of precise analysis method. In recent, the study of IRR-camera is carrying out discover of temperature of power equipment through condition diagnosis and system development of degradation diagnosis. In this study, thermal testing of power transformer is measured with partial temperature distribution in real time.

  • PDF

Thermal Fatigue Behavior of 3D-Woven SiC/SiC Composite with Porous Matrix for Transpiration Cooling Passages

  • Hayashi, Toshimitsu;Wakayama, Shuichi
    • Advanced Composite Materials
    • /
    • v.18 no.1
    • /
    • pp.61-75
    • /
    • 2009
  • The effect of porous matrix on thermal fatigue behavior of 3D-orthogonally woven SiC/SiC composite was evaluated in comparison with that having relatively dense matrix. The porous matrix yields open air passages through its thickness which can be utilized for transpiration cooling. On the other hand, the latter matrix is so dense that the air passages are sealed. A quantity of the matrix was varied by changing the number of repetition cycles of the polymer impregnation pyrolysis (PIP). Strength degradation of composites under thermal cycling conditions was evaluated by the $1200^{\circ}C$/RT thermal cycles with a combination of burner heating and air cooling for 200 cycles. It was found that the SiC/SiC composite with the porous matrix revealed little degradation in strength during the thermal cycles, while the other sample showed a 25% decrease in strength. Finally it was demonstrated that the porous structure in 3D-SiC/SiC composite improved the thermal fatigue durability.

Effect of enzyme treatment on the DSC and TGA behavior of silkworm powder

  • Jo, You-Young;Bae, Sung Min;Kim, HyunBok;Lee, Kwang Gill;Kweon, HaeYong
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • v.37 no.1
    • /
    • pp.29-32
    • /
    • 2018
  • Silkworm powder's thermal property is an important factor for its storage and marketing. This study examined the effect of edible enzyme on the thermal property of silkworm powder using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Results of the TGA showed that regardless of the enzyme treatment, the weight loss patterns of silkworm powders exhibited 3 step thermal property deterioration at approximately $80^{\circ}C$, $280^{\circ}C$, and $480^{\circ}C$ due to water evaporation and thermal degradation. This is similar with the DSC which also resulted in all samples two endothermic peaks attributed also to water evaporation and thermal degradation. These results indicated that the use of enzyme such as protease and cellulase might not affect significantly the thermal properties of silkworm powder.

Degradation Characteristics of Perfluoropolyether Lubricant for Computer Hard Disk (컴퓨터 하드디스크 윤활제로 사용되는 Perfluoropolyether의 분해거동)

  • Lee, Ji-Hye;Chun, Sang-Wook;Kang, Ho-Jong
    • Polymer(Korea)
    • /
    • v.31 no.4
    • /
    • pp.278-282
    • /
    • 2007
  • The degradation characteristics of perfluoropolyether (PFPE) for computer hard disk drive have been investigated. Thermal degradation in PFPE started at $170\;^{\circ}C$ and it was completed at $450\;^{\circ}C$. If PFPE was contacted with wear fragment from slider made by $Al_2O_3{\cdot}TiC$, the thermal degradation was accelerated by the catalytic Lewis acid degradation. The Lewis acid degradation mainly took placed in methylene oride(fluoride) chain scission as well as methylene(fluoride) and hydroxy end chain. As a result, the degradation reaction accomplished as early as at $300\;^{\circ}C$. The photo oxidation due to UV exposure on PFPE caused the chain scission in methylene(fluoride), and end chain in PFPE without chain scission in methylene oxide(fluoride) and then the molecular weight of PFPE increased by expected secondary reactions between formed radicals in the photo oxidation.

The performance analysis of photovoltaic module accounting for solar cell degradation and series resistance (태양전지 셀의 열화와 직렬저항의 변화에 따른 태양전지 모듈의 특성 해석)

  • Park, Chi-Hong;Kang, Gi-Hwan;Waithiru, L.;Ahn, Hyung-Keun;Yu, Gwon-Jong;Han, Deuk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2006.06a
    • /
    • pp.28-29
    • /
    • 2006
  • When photovoltaic module is used for a long time, its performance decreases due to several reasons. In this paper, we focus on the possibilities mainly contributing to the degraded efficiency of the polycrystalline silicon photovoltaic modules. The analysis is based on the modules that have been used for 15 years. These are two main reasons that cause the efficiency degradation, the corrosion and thermal decomposition. The former phenomenon of electrode is mainly due to the moisture from damaged back sheet in some module. However the other reason of the degraded efficiency comes from the thermal decomposition, which can not be observed from the outside but only by experiment. In this study, the comparison between the efficiency of normal modules and degradation modules is presented. Module having degraded cell was seen to cause increase of series resistance by about 80%, in comparison to normal samples efficiency which reduce by about 20%. This study shows that the effects of series resistances on module performance are critical. These effects must be understood and taken into consideration when analyzing performance degradation.

  • PDF

Evaluation of the Thermal Degradation in Co-based Superalloy using High frequency Transducer of Scanning Acoustic Microscope (초음파현미경의 고주파 초음파 탐촉자를 이용한 코발트기 초내열합금강의 열화평가)

  • Park, Ik-Keun;Cho, Dong-Su;Kim, Yong-Kwon;Lim, Jae-Seang;Kim, Chung-Seok
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.24 no.5
    • /
    • pp.518-524
    • /
    • 2004
  • The feasibility of Y(z) curve method of scanning acoustic microscope using high frequency transducer was experimentally studied for assessment of the thermal degradation in Co-based superalloy. Thermal degradation was performed to simulate the microstructural changes in Co-based superalloy arising from long term exposure at high temperature. Longitudinal wave velocity measured by pulse echo method using 10MHz transducer and leaky surface acoustic wave (LSAW) velocity measured by V(z) curve method using 200MHE transducer were measured to investigate the effect on thermal degradation. Ultrasonic velocity decreased as the aging time increased in both ultrasonic waves. Moreover, the low frequency longitudinal wave velocity decreased a little. Otherwise, the high frequency LSAW velocity drastically decreased up to a maximum of 4.7% at the aging time of 4,000hours. A good correlation was found between LSAW and Vickers hardness. Consequently, V(z) curve method of SAM using high frequency transducer could be a potential tool for assessing thermal degradation.

Input Signal Selection Circuits Development of Electronic Cards for Thermal Degradation in Nuclear Power Plant (원전 열화 전자카드의 입력신호 선택회로 개발)

  • Kim, Jong-ho;Che, Gyu-shik
    • Journal of Advanced Navigation Technology
    • /
    • v.23 no.6
    • /
    • pp.554-560
    • /
    • 2019
  • Excore Nuclear Flux Monitoring System in Nuclear Power Plant monitors continuous reactor power up to maximum 200%. The monitoring method, however, has to be different depending on the reactor power level. Because the logarithmic pulse signals must be counted and processed exactly due to large uncertainty if their levels are low, on the other hand, they must be processed through statistical methodolgies if theirs are high to get exact monitoring values, in point of thermal degradation view. Therefore, we developed thermal degradation input signal selection circuit to transfer low level reactor power monitoring circuit to high level reactor power circuit at rated value in this paper. We proved their validities through testing them using real data used in nuclear power plant and analyzed their results. And, These methods will be used to measure the neutron level of excore nuclear flux monitoring system in nuclear power plant.