• Title/Summary/Keyword: thermal stability enhancement

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Instability of Evaporation Fronts in the Interstellar Medium

  • Kim, Jeong-Gyu;Kim, Woong-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.46.2-46.2
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    • 2013
  • The neutral component of the interstellar medium (ISM) is segregated into the cold neutral medium (CNM) and warm neutral medium (WNM) as a result of thermal instability. It was found that the CNM--WNM evaporation interface, across which the CNM undergoes thermal expansion, is linearly unstable to corrugational disturbances, in complete analogy with the Darrieus-Landau instability (DLI) in terrestrial flames. To explore dynamical consequences of the DLI in the ISM, we perform a linear stability analysis of the DLI including the effect of thermal conduction as well as nonlinear hydrodynamic simulations. We find that the DLI is suppressed at short length scales via heat transport. The linear growth time of the fastest growing mode is proportional to the square of the evaporation flow speed of the CNM relative to the interface and is typically >10 Myr. In the nonlinear stage, perturbations grow into cusp-like structure protruding toward the WNM, and soon reach a steady state where the evaporation rate is increased by a factor of 2 compared to the initial state. We demonstrate that the amplitude of the interface distortion and enhancement in evaporation rate are determined primarily by the density ratio between the CNM and WNM. Given quite a long growth time and highly subsonic velocities at saturation, the DLI is unlikely to play an important role in the ISM dynamics.

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Synergistic Effect of Tocopherol, Citric Acid and Sodium Polyphosphate on the Thermal Oxidation of Blending Oil (혼합유(混合油)의 열산화(熱酸化)에 대(對)한 Tocopherol, 구연산 및 인산염(燐酸鹽)의 상승효과)

  • Chang, Hun-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.7 no.1
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    • pp.63-70
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    • 1990
  • Influence of mixing ratio of blending oil (rice bran oil : RBD palm olein = 1 : 1, 1 : 4 mixture: w/w) and natural tocopherol, citric acid, and sodium polyphosphate on enhancement of oxidation stability of blending oil under the condition of tap water infulx(1 ml/min/200g oil) were compared by AOM test after heating these system at l80$^{\circ}C$. In addition, the effects of tocopherol, and synergist on oxidition stability were also tested with potato chips fried with blending oil(1 : 4 mixture). The result obtained were as followes; 1. The test of RBD palm olein addition of 50% and 80% against rice bran oil on oxidation stability showed that the higher the palm olein contents in blending oil, the higher the oxidation stability. 2. The test of oxidation stability, adding l00ppm, 200ppm and 400ppm of natural tocopherol in two different types of blending oils, A(1 : 1 mixture) and B(1 : 4 mixture), disclosed that blending oil B was more positively effective, and this trend was superior at 200ppm level particularly, Furthermore, oxidation stability was enhanced remarkably upon addition of 100ppm of natural tocopherol, and 50ppm of citric acid together with 50ppm, 100ppm and 200ppm of sodium polyphosphate in general. Especially, 200ppm of sodium polyphosphate addition induced the most synergetic effect on oxidation stability showing as much as 3 times compare to control. 3. The results of oxidation stability obtained by peroxide value on potato chips fried with blending oil (1:4 mixture} added tocopherol, citric acid and sodium polyphosphate and preserved at $60^{\circ}C$ revealed that addition of tocopherol and 50ppm of citric acid together with 200ppm of sodium polyphosphate treatment was the most synergistic coinciding with AOM test results.

Effect of Inorganic Fillers on the Dimensional Stability of Poly(ethylene naphthalate) Film as a Flexible Substrate (무기 필러가 유연기판용 폴리에틸렌나프탈레이트 필름 치수안정성에 미치는 영향)

  • Kim, Jongwha;Kim, Hongsuk;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.733-738
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    • 2012
  • The effect of glass bead and glass fiber on the enhancement of dimensional stability in poly(ethylene naphthalate) (PEN) flexible substrate for photovoltaic devices has been studied. It was found that the coefficient of thermal expansion (CTE) and the optical transmittance decreased with increasing inorganic filler content. In addition to filler contents, the size and size distribution of fillers are the other important factors to improve CTE and optical transmittance of PEN film. Our results showed that the optimum filler content was found to be about 5 wt% to enhance the dimensional stability of PEN by more than 50% with maintaining the optical transmittance over 85% for the flexible substrate.

The effect of TiCrN coating on high temperature stability of Inconel 617 (TiCrN 코팅이 Inconel 617 합금의 고온안정성에 미치는 영향)

  • Lee, Byeong-Woo;Park, Jong-Cheon;Kim, Mi-Ru;Koo, Jin-Heui;Kim, Byeong-Ik;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.235-239
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    • 2011
  • TiCrN layers (Ti : Cr = 20 : 80 and 5 : 95 wt%) were deposited on Inconel 617 and the effect of TiCrN coating on the high temperature stability of Inconel 617 up to $1000^{\circ}C$ was examined. XRD analysis and microstructural observation showed that vigorous and inhomogenous Cr diffusion to the surface was suppressed by TiCrN layer compare to the uncoated Inconel 617. This led to a distinctive enhancement in thermal oxidation resistance of Inconel 617.

Investigation on nanoadhesive bonding of plasma modified titanium for aerospace application

  • Ahmed, Sabbir;Chakrabarty, Debabrata;Mukherjee, Subroto;Joseph, Alphonsa;Jhala, Ghanshyam;Bhowmik, Shantanu
    • Advances in aircraft and spacecraft science
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    • v.1 no.1
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    • pp.1-14
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    • 2014
  • Physico-chemical changes of the plasma modified titanium alloy [Ti-6Al-4V] surface were studied with respect to their crystallographic changes by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM).The plasma-treatment of surface was carried out to enhance adhesion of high performance nano reinforced epoxy adhesive, a phenomenon that was manifested in subsequent experimental results. The enhancement of adhesion as a consequence of improved spreading and wetting on metal surface was studied by contact angle (sessile drop method) and surface energy determination, which shows a distinct increase in polar component of surface energy. The synergism in bond strength was established by analyzing the lap-shear strength of titanium laminate. The extent of enhancement in thermal stability of the dispersed nanosilica particles reinforced epoxy adhesive was studied by Thermo Gravimetric Analysis (TGA), which shows an increase in onset of degradation and high amount of residuals at the high temperature range under study. The fractured surfaces of the joint were examined by Scanning electron microscope (SEM).

Thermal Stability Enhancement of Nickel Monosilicides by Addition of Pt and Ir (Pt와 Ir 첨가에 의한 니켈모노실리사이드의 고온 안정화)

  • Yoon, Ki-Jeong;Song, Oh-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.4
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    • pp.27-36
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    • 2006
  • We fabricated thermally evaporated 10 nm-Ni/(poly)Si, 10 nm-Ni/l nm-Ir/(poly)Si and 10 nm-Ni/l nm-Pt/(poly)Si films to investigate the thermal stability of nickel monosilicides at the elevated temperatures by rapid annealing them at the temperatures of $300{\sim}1200^{\circ}C$ for 40 seconds. Silicides of 50 nm-thick were formed on top of both the single crystal silicon actives and the polycrystalline silicon gates. A four-point tester was used to examine sheet resistance. A scanning electron microscope and field ion beam were employed for thickness and microstructure evolution characterization. An X-ray diffractometer and an Auger depth profiler were used for phase and composition analysis, respectively. Nickel silicides with platinum have no effect on widening the NiSi stabilization temperature region. Nickel silicides with iridium farmed on single crystal silicon showed a low resistance up to $1200^{\circ}C$ while the ones formed on polycrystalline silicon substrate showed low resistance up to $850^{\circ}C$. The grain boundary diffusion and agglomeration of silicides lowered the NiSi stable temperature with polycrystalline silicon substrates. Our result implies that our newly proposed Ir added NiSi process may widen the thermal process window for nano CMOS process.

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Structural and Physical Properties of Antheraea pernyi Silk Fibroin Fiber Treated with $I_2-KI$ Aqueous Solution

  • Khan Md. Majibur Rahman;Gotoh Yasuo;Morikawa Hideaki;Miura Mikihiko
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.333-338
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    • 2006
  • Silk fibroin (SF) fiber from the Antheraea pernyi silkworm was treated with a 1.23 N iodine-potassium iodide ($I_2-KI$) aqueous solution, and the structure and physical properties were investigated to clarify the effects of the iodine treatment. The noticeably high weight gain value of SF fiber, about 25 wt% was attributed to the absorption of polyiodide ions in the form of $I_3{^-}\;and\;I_5{^-}$. Fourier transform infrared spectroscopy and X-ray diffraction measurements suggested that polyiodide ions mainly entered the amorphous region. In addition, a new sharp reflection on the meridional direction, corresponding to a period of $7.0{\AA}$, was observed and indicated the possibility of the formation of mesophase structure of ${\beta}$-conformation chains. Dynamic viscoelastic measurements showed that the damping tan ${\delta}$ peak at $270^{\circ}C$ gradually shifted to lower temperature in the iodinated SF fibers, suggesting an enhancement of the molecular motion of the fibroin chains induced by the presence of polyiodide ions. With heating above $254^{\circ}C$, the iodine component introduced intermolecular cross-linking of SF, and the melt flow of the sample was inhibited. The thermal decomposition stability of fibroin molecules was greatly enhanced by iodine treatment.

Synthesis and Characterization of Upconversion Nanoparticles for Cancer Therapy

  • Choe, Seung-Yu;Kim, Bo-Bae;Kim, Eun-Bi;Lee, Seung-U;Jeon, Seon-A;Park, Tae-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.420.2-420.2
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    • 2016
  • Various fields have been paid attention to upconversion nanoparticles (UCNPs) because of its unique optical properties. Moreover, to use the UC luminescent techniques through cell images for identified apoptosis/necrosis of cancer cells have been performed. They have been studied for a versatile biomedical application such as a biosensing tool, or delivery of active forms of medicines inside living cells. UCNPs have distinctive characteristics such as photoluminescence, special emission, low background fluorescence signal and good colloidal stability, which have many advantages compared with the organic dyes and quantum dots. UCNPs have not only a great potential for imaging (UC luminescence) but also therapies (photo-thermal therapy, PTT and photo-dynamic therapy, PDT) in cancer diagnostics. Therefore, we report the enhancement of upconversion red emission in NaYF4:Yb3+,Er3+ nanoparticles, synthesized via solid-state method with the thermal decomposition of trifluoroacetate as precursors and organic solvent at a high boiling point. The UCNPs have an emission in the field of near infrared wavelength, cubic shape and nano-size in length. In this study, we will further investigate it for cancer therapy with NIR optical detection onto the solid substrate.

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Teflon coating of fabric filters for enhancement of high temperature durability (섬유상 여과필터의 고온 내구성 향상을 위한 테프론 코팅 연구)

  • Kim, Eun-Joo;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.232-239
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    • 2011
  • Fabric fibrous filter has been used in various industrial applications owing to the low cost and wide generality. However, the basic properties of fabric materials often limit the practical utilization including hot gas cleaning. This study attempts to find new coatings of porous fibrous filter media in order to overcome its insufficient thermal resistance and durability. Teflon was one of the plausible chemicals to supplement the vulnerability against frequent external thermal impacts. A foaming agent composed of Teflon and some organic additives was tentatively coated on the glass fiber mat. The present test Teflon foam coated filter was fount to be useful for hot gas cleaning, up to $250^{\circ}C$-$300^{\circ}C$. Close examination using XPS(X-ray Photoelectron Spectroscopy) and Contact angle proved the binding interactions between carbon and fluorine, which implies coating stability. The PTFE/Glass foam coated filter consisted of more than 95% (C-F)n bond, and showed super-hydrophobic with good-oleophobic characteristics. The contact angle of liquid droplets on the filter surface enabled to find the filter wet-ability against liquid water or oil.

Numerical Study on the Premixed Flame Instability and Nonlinear Behavior (예혼합화염의 불안정성 및 비선형적 거동에 관한 수치적 연구)

  • Kang, Sang-Hun;Baek, Seung-Wook;Im, Hong G.
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.281-286
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    • 2005
  • To understand fundamental characteristics of combustion in a small scale device, the effects of the momentum and heat loss on the stability of laminar premixed flames in a narrow channel are investigated by two-dimensional high-fidelity numerical simulation. A general finding is that momentum loss promotes the Saffman-Taylor (S-T) instability which is additive to the Darrieus-Landau (D-L) instabilities, while the heat loss effects result in an enhancement of the diffusive-thermal (D-T) instability. These effects are also valid in nonlinear behavior of the premixed flame. The simulations of multiple cell interactions are also conducted with heat and momentum loss effects.

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