• Applied Chemistry for Engineering
• /
• v.17 no.4
• /
• pp.414-419
• /
• 2006

Effects of water vapor, hydrocarbons, and CO, which are inevitably included in exhaust gases of combustion, on a combined $De-NO_{x}$ process of non-thermal plasma and $NH_{3}$ SCR (Selective Catalytic Reduction) have been investigated. Test results showed that fast SCR reaction enhanced $De-NO_{x}$ rate under the low temperature conditions, $150{\sim}200^{\circ}C$ The present test, however, showed that the role of the fast SCR reaction can be significantly suppressed by addition of hydrocarbons in a non-thermal plasma reactor. Detailed investigation verified that such suppressed role of the fast SCR reaction could be caused by the $NO_{2}/NO_{x}$ ratio modified by aldehydes produced from hydrocarbons in a non-thermal plasma reactor. In addition, the present study was confirmed that the effects of water vapor and CO were not noticeable compared with the hydrocarbon effects.

• Journal of Korean Society of Water and Wastewater
• /
• v.24 no.1
• /
• pp.85-92
• /
• 2010

In this study, odorous compounds emitted from various wastewater treatment were treated with using the non-thermal plasma reaction, and the effluent gas from the plasma reactor was introduced to a waste sludge reactor to achieve simultaneous sludge reduction. Hydrogen sulfide, the model odorous compound, was removed at 70% using the plasma reaction, and greater than 99% removal efficiency was observed when treated by the sludge reactor. In addition, the sludge reactor showed a high efficiency of ozone removal. As ozone reacted with sludge, oxidation with organic matters took place, and total COD decreased by 50~60% and soluble COD increased gradually. As a result, the integrated process consisting of the non-thermal plasma and the sludge reactor can be successfully applied for the simultaneous treatment of malodorous gas and waste sludge.

• JSTS:Journal of Semiconductor Technology and Science
• /
• v.5 no.3
• /
• pp.149-158
• /
• 2005

This paper describes design, fabrication, and application of the silicon based temperature controllable micro reactor. In order to achieve fast temperature variation and low energy consumption, reaction chamber of the micro reactor was thermally isolated by etching the highly conductive silicon around the reaction chamber. Compared with the model not having thermally isolated structure, the thermally isolated micro reactor showed enhanced thermal performances such as fast temperature variation and low energy consumption. The performance enhancements of the micro reactor due to etched holes were verified by thermal experiment and numerical analysis. Regarding to 42 percents reduction of the thermal mass achieved by the etched holes, approximately 4 times faster thermal variation and 5 times smaller energy consumption were acquired. The total size of the fabricated micro reactor was $37{\times}30{\times}1mm^{3}$. Microchannel and reaction chamber were formed on the silicon substrate. The openings of channel and chamber were covered by the glass substrate. The Pt electrodes for heater and sensor are fabricated on the backside of silicon substrate below the reaction chamber. The dimension of channel cross section was $200{\times}100{\mu}m^{2}$. The volume of reaction chamber was $4{\mu}l$. The temperature of the micro reactor was controlled and measured simultaneously with NI DAQ PCI-MIO-16E-l board and LabVIEW program. Finally, the fabricated micro reactor and the temperature control system were applied to the thermal denaturation and the trypsin digestion of protein. BSA(bovine serum albumin) was chosen for the test sample. It was successfully shown that BSA was successfully denatured at $75^{\circ}C$ for 1 min and digested by trypsin at $37^{\circ}C$ for 10 min.

• Nuclear Engineering and Technology
• /
• v.55 no.7
• /
• pp.2534-2546
• /
• 2023

Gas-cooled space reactor, which adopts He-Xe gas mixture as working fluid, is a better choice for megawatt power generation. In this paper, thermal-hydraulic characteristics of He-Xe gas mixture in 2×2 rod bundle wrapped with helical wires is numerically investigated. The velocity, pressure and temperature distribution of the coolant are obtained and analyzed. The results show that the existence of helical wires forms the vortexes and changes the velocity and temperature distribution. Hot spots are found at the contact corners between helical wires and fuel rods. The highest temperature of the hot spots reach 1600K, while the mainstream temperature is less than 400K. The helical wire structure increases the friction pressure drop by 20%-50%. The effect extent varies with the pitch and the number of helical wires. The helical wire structure leads to the reduction of Nusselt number. Comparing thermal-hydraulic performance ratios (THPR) of different structures, the THPR values are all less than 1. It means that gas-cooled space reactor adopting helical wires could not strengthen the core heat removal performance. This work provides the thermal-hydraulic design basis for He-Xe gas cooled space nuclear reactor.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2002.05a
• /
• pp.287.1-287
• /
• 2002

• Proceedings of the KSME Conference
• /
• 2001.06e
• /
• pp.213-218
• /
• 2001

The characteristics of the fluid flow and mass transfer in a vertical atmospheric pressure chemical vapor deposition (APCVD) are numerically studied. In order to get the optimal process parameters for the uniformity of deposition on a substrate, Navier-Stokes and energy equations have been solved for the pressure, mass-flow rate and temperature distribution in a CVD reactor. Results show that the thermal boundary condition at the reactor wall has an important effect in the formation of buoyancy-driven secondary cell when radiation effect is considered. Results also show that reduction of the buoyancy effect on the heated reactor improves the uniformity of deposition.

• Journal of the Korean Society of Safety
• /
• v.37 no.4
• /
• pp.129-138
• /
• 2022

A new method for injecting cooling water into the Korean research reactor (KRR) in the event of beam tube rupture is proposed in this paper. Moreover, the research evaluates the risk to the reactor core in terms of core damage frequency (CDF). The proposed method maintains the cooling water in the chimney at a certain level in the tank to prevent nuclear fuel damage solely by gravitational coolant feeding from the emergency water supply system (EWSS). This technique does not require sump recirculation operations described in the current procedure for resolving beam tube accidents. The reduction in the risk to the core in the event of beam tube rupture that can be achieved by the proposed change in the cooling water injection design is quantified as follows. 1) The total CDF of the KRR for the proposed design change is approximately 4.17E-06/yr, which is 8.4% lower than the CDF of the current design (4.55E-06/yr). 2) The CDF for beam tube rupture is 7.10E-08/yr, which represents an 84.1% decrease compared with that of the current design (4.49E-07/yr). In addition to this quantitative reduction in risk, the modified cooling water injection design maintains a supply of pure coolant to the EWSS tank. This means that the reactor does not require decontamination after an accident. Thermal hydraulic analysis proves that the water level in the reactor pool does not cause damage to the nuclear fuel cladding after beam tube rupture. This is because the amount of water in the chimney can be regulated by the EWSS function. The EWSS supplies emergency water to the reactor core to compensate for the evaporation of coolant in the core, thus allowing water to cover the fuel assemblies in the reactor core over a sufficient amount of time.

• Journal of Korean Society on Water Environment
• /
• v.30 no.5
• /
• pp.559-567
• /
• 2014

Since the ocean dumping of organic wastes is prohibited under the London Convention, the need for land treatment of food waste leachate (FWL) has significantly been growing in recent years. This study was conducted to use thermal solubilization to turn FWL into a form that can easily be degraded during the anaerobic digestion process, thereby reducing the percentage of solids and increasing the production of methane. To derive the optimal operating conditions of thermal solubilization, a laboratory-scale reactor was built and operated. The optimal reaction temperature and time turned out to be $190^{\circ}C$ and 90 min, respectively. The BMP test showed a methane production of 465 mL $CH_4/g$ $COD_{Cr}$ and a biodegradation rate of 90.1%. The production of methane rose by about 15%, compared with no the application of thermal solubilization. To reduce the solid content of FWL and improve the methane production, therefore, it may be helpful to apply thermal solubilization to pre-treatment facilities for anaerobic digestion.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.07b
• /
• pp.922-926
• /
• 2002

In this paper, in order to investigate the catalytic effect of the sludge exhausted from waterworks as heating temperature for NOx removal, we measure NO, $NO_2$ concentration as increasing temperature of sludge pellets and applying high voltage to sludge pellets in a quartz-glass reactor at the same time. NO initial concentration is 100ppm balanced with air gas in a mixing chamber. The gas flow is 5[l/min] and the heating temperature of sludge pellets in a quartz-glass reactor is adjusted from $200[^{\circ}C]$ $400[^{\circ}C]$ to investigate the effect of sludge pellets for removal NOx$(NO+NO_2)$ as increasing temperature. $BaTiO_3$ pellets is filled in a packed-bed reactor for corona discharge to measure how much NOx$(NO+NO_2)$ is removed after generating $NO_2$ from the packed-bed reactor. AC[60Hz] voltage is supplied to the reactor for discharge. In the result, $NO_2$ concentration is decreased by sludge pellets without heating temperature for sludge pellets in case of sludge pellets done heat treatment, however NO concentration is almost the same to be compared NO initial concentration. As increasing heating temperature for sludge pellets, $NO_2$ adsorbed on the sludge surface done heat treatment is converted to NO by the thermal energy, so NO concentration is extremely increased by reduction decomposition of $NO_2$. Finally, We think the sludge is possible to use for reduction catalysts, however we need to study more about the possibility and endurance of sludge as catalysts for NOx removal.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.21 no.7
• /
• pp.1042-1049
• /
• 1997

LMFBR(Liquid Metal Fast Breeder Reactor) vessel is operated under the high temperatures of 500-550.deg. C. Thus, transient thermal loads were severe enough to cause inelastic deformation due to creep-fatigue and plasticity. For reduction of such inelastic deformations, Y-piece structure in the form of a thermal sleeve is used in LMFBR vessel under repeated start-up, service and shut-down conditions. Therefore, a systematic method for inelastic analysis is needed for design of the Y-piece structure subjected to such loading conditions. In the present investigation, finite element analysis of heat transfer and inelastic thermal stress were carried out for the Y-piece structure in LMFBR vessel under service conditions. For such analysis, ABAQUS program was employed based on the elasto-plastic and Chaboche viscoplastic constitutive equations. Based on numerical data obtained from the analysis, creep-fatigue damage estimation according to ASME Code Case N-47 was made and compared to each other. Finally, it was found out that the numerical predictio of damage level due to creep based on Chaboche unified viscoplastic constitutive equation was relatively better compared to elasto-plastic constitutive formulation.