• 제목/요약/키워드: thermal oxidation

검색결과 1,006건 처리시간 0.028초

VOC Emissions from Automotive Painting and Their Control: A Review

  • Kim, Byung-R.
    • Environmental Engineering Research
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    • 제16권1호
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    • pp.1-9
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    • 2011
  • During automotive painting, volatile organic compounds (VOCs) associated with the paint solvents are emitted to the atmosphere. Most VOC emissions come from spraying operations via the use of solvent-based paints, as the spraybooth air picks up gaseous solvent compounds and overspray paint materials. The VOCs consist of aromatic and aliphatic hydrocarbons, ketones, esters, alcohols, and glycolethers. Most VOCs (some hydrophilic VOCs are captured and retained in the water.) are captured by an adsorption system and thermally oxidized. In this paper, the processes involved in automotive painting and in VOC control are reviewed. The topics include: painting operations (briefly), the nature of VOCs, VOC-control processes (adsorption, absorption, biological removal, and thermal oxidation) and energy recovery from VOCs using a fuel reformer and a fuel cell, and the beneficial use of paint sludge.

폴리올 에스테르 유도체에 대한 합성 윤활유의 제조 및 그의 특성 (Synthesis and Characteristics of Synthetic Lubricants for the Polyol ester derivatives)

  • 이재덕;정노희
    • 한국응용과학기술학회지
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    • 제26권2호
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    • pp.213-223
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    • 2009
  • Conventional additives were added to a newly synthesized base oil to create synthetic lubricants. Commercial polyol ester prepared in this laboratory were obtained as esterification of 1,1,1-trimethylol propane and respectively. This newly synthesized base oil had a variable chemical structure that could achieved the following properties; oxidation or thermal stability, low temperature fluidity, and higher flash points. When compared with commercial mineral lubricants, the synthetic lubricants show superior thermal and oxidation stability, and anti-wear properties.

Alumina Filler가 충진된 에폭시 경화물(硬化物)의 변색(變色)이 전기적(電氣的) 특성(特性)에 미치는 영향(影響) (The Effect of Discoloration on the Electrical Properties of Alumina Filled Epoxy)

  • 한기만;김동욱;오무원;권혁삼;김영성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
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    • pp.59-62
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    • 1993
  • This Paper studies on thermal oxidation of alumina filled epoxy network polymer used in Extra-High voltage application. The thermal oxidation of surface has investigated by yellow index variation and various electrical properties which are surface resistivity, tracking resistance and AC dielectric strength are estimated by yellow index.

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Black Chrome 태양광 선택흡수막의 표면분석 (Surface Analysis of Black Chrome Solar Selective Coatings)

  • 이길동;최영희;오정무
    • 태양에너지
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    • 제9권2호
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    • pp.69-77
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    • 1989
  • The thermal degradation of electroplated black chrome coating on Ni substrates has been investigated by using Auger electron spectroscopy technique. The sample was prepared by electroplating at $20^{\circ}C$ for 20 seconds with the current density at $0.4A/cm^2$. Its surface oxidation process was investigated with 1 hour annealed sample for a temperature range of $300-550^{\circ}C$. While its optical solar absorption was dominated by fine metallic Cr particles, thermal degradation was occurred primarily by oxidation of metallic Cr particles as increasing the annealing temperature.

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회전 아크를 이용한 메탄 개질 반응에서 플라즈마 모드에 따른 개질 특성 (Characteristics of $CH_4$ Reforming by Rotating Arc)

  • 김동현;이대훈;김관태;송영훈
    • 한국연소학회지
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    • 제11권2호
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    • pp.15-21
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    • 2006
  • Characteristics of a plasma reactor for partial oxidation of methane, especially focused on the role and effectiveness of plasma chemistry, are investigated. Partial oxidation of methane is investigated using a rotating arc which is a three dimensional version of a typical gliding arc. Three different modes of operation were found. Each mode shows different reforming performance. The reason for the difference is due to the difference in relative role of thermal and plasma chemistry in overall process. A mode with high temperature results higher methane conversion and hydrogen selectivity in contrast to the mode with lower temperature where poor methane conversion and higher selectivity of $C_2$ species are observed. In this way, we can confirm that by controlling characteristic of process or controlling relative strength of plasma chemistry and thermal chemistry, it is possible to map an optimal condition of reforming process by rotating arc.

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Ti-6Al-4V 고강도 볼트의 성형성에 미치는 표면산화효과 (Effect of Thermal Oxidation Coating on the Hot Forging Process of High Strength Ti-6Al-4V Bolt)

  • 김정한;이채훈;홍재근;김재호;염종택
    • 소성∙가공
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    • 제18권3호
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    • pp.251-255
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    • 2009
  • Since fastener bolt for airplane require high specific strength and corrosion resistance, Ti-6Al-4V alloy is widely used. However, the Ti-6Al-4V bolt is generally manufactured by cutting and rolling because of their poor workability. The aim of present work is to develop hot forming technology for high strength Ti-6Al-4V. Various heat-treatments were applied to specimen in order to increase hot-workability and prevent galling with die. Multiple forging were simulated with FE code to determine optimum process parameters including specimen temperature, strain rate, local strain, and thermal shrinkage. Forged samples were heat-treated again to increase their mechanical properties.

급속 열처리 장치를 이용한 실리콘 산화막의 Annealing 효과 (Effects of Annealing on Silicon Dioxide using Rapid Thermal Process System)

  • 박현우;장현룡;황호정
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
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    • pp.383-386
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    • 1988
  • In MOS integrated circuits, annealing after oxidation process is necessary to improve physical properties of silicon dioxide. With subsequent annealing in inert gases such as nitrogen or argon, and excess silicon bond is allowed time to complete the oxidation and surface charge density is reduced. In this paper, we will present effects of the rapid thermal annealing on silicon dioxide. In order to evaluate characteristics of silicon dioxide, we analyzed C-V curve dependent on annealing time and temperature, and presented variation of fixed oxide charge.

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MgO와 Al의 테르밋 반응생성물이 첨가된 MgO-C계 내화재료의 용손 기구 (Wear Mechanism of MgO-C Refractory with Thermite Reaction Products of MgO and Al)

  • 최태현;전병세
    • 한국세라믹학회지
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    • 제33권7호
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    • pp.832-838
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    • 1996
  • Thermite reaction products of MgO and Al were added to MgO-C refractory to improve the properties of corrosion against the attack of slag, oxidation and mechanical spalling. Corrosion rate of MgO-C-MgAl2O4 spinel refractory at the ratio of 3.3(CaO/SiO2) slag was smaller than that of MgO-C and MgO-C-Al refractory. The excellent corrosion resistance of the MgO-C-MgAl2O4 spinel refractory against the slag attack was appeared by Al and MgAl2O4 spinel with high melting point and corrosion resistance and the high thermal conductivity and low thermal expansion of AIN. Hot M.O.R at 140$0^{\circ}C$ and the resistance of oxidation weight loss at 90$0^{\circ}C$ were 210kg/cm2 and -12% respectively.

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Temperature-Dependent Thermal and Chemical Stabilities as well as Mechanical Properties of Electrodeposited Nanocrystalline Ni

  • Zheng, Liangfu;Peng, Xiao
    • Metals and materials international
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    • 제24권6호
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    • pp.1293-1302
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    • 2018
  • Nanocrystalline (NC) Ni electrodeposits (EDs) with a mean grain size of $34{\pm}12nm$ has been investigated, from room temperature to $800^{\circ}C$ under a purge gas of argon, by both non-isothermal and isothermal differential scanning calorimetry measurements, in combination with characterization of temperature-dependent microstructural evolution. A significant exothermic peak resulting from superimposition of recrystallization and surface oxidation occurs between 340 and $745^{\circ}C$ at a heating rate of $10^{\circ}C/min$ for the NC Ni EDs. The temperatures for recrystallization and oxidation increase with increasing the heating rate. In addition, recrystallization leads to a profound brittle-ductile transition of the Ni EDs in a narrow range around the peak temperature for the recrystallization.

A study of thermolysis of irradiated diamide-containing extraction systems with nitric acid

  • Srvortsov, I.V.;Belova, E.V.;Sokolov, I.P.;Rodin, A.V.;Stefanovsky, S.V.;Mysoedov, B.F.
    • Nuclear Engineering and Technology
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    • 제50권8호
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    • pp.1421-1425
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    • 2018
  • The dynamics of gas release at thermal oxidation of extraction systems on the basis of diamides of dicarbonic acids in fluorinated sulphones with 14 mol/L $HNO_3$ was investigated. The effect of preirradiation of the mixtures with accelerated electrons on the kinetics of their thermolysis was determined. The mixtures were heated in an autoclave at temperatures of 170 and $200^{\circ}C$ and irradiated using an electron accelerator to absorbed doses of 0.1, 0.5, and 1.0 MGy. It has been shown that no conditions for autocatalytic oxidation at thermolysis of extraction mixtures irradiated up to a dose of 1 MGy were developed.