• Title/Summary/Keyword: thermal factor

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The Effect of Analysis Variables on the Failure Probability of the Reactor Pressure Vessel by Pressurized Thermal Shock (가압열충격에 의한 원자로 압력용기의 파손확률에 미치는 해석변수의 영향)

  • Jang, Chang-Heui;Jhung, Myung-Jo;Kang, Suk-Chull;Choi, Young-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.6
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    • pp.693-700
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    • 2004
  • The probabilistic fracture mechanics(PFM) is a useful analytical tool to assess the integrity of reactor pressure vessel(RPV) at the event of pressurized thermal shock(PTS). In PFM, the probabilities of flaw initiation and propagation are estimated by comparing the applied stress intensity factor with the fracture toughness calculated by the simulation of various stochastic variables. It is known that the results of PFM analyses are dependent on the choice of the stochastic parameters and assumptions. Of the various variables and assumptions, we investigated the effects of the RT$_{NDT}$ shift equations, fracture toughness curves, and flaw distributions on the PFM results for the three PTS transients. The results showed that the combined effects of the RT$_{NDT}$ shift equations and fracture toughness curves are complicated and dependent on the characteristics of the transients, the chemistry of the materials, the fast neutron fluence, and so on.

Determination of hey Fuel Ratio According to Fuel Composition (IV) - Overall Estimation of Methods- (연료 조성에 따른 공연비 산정 (IV) - 공연비 계산방식의 평가-)

  • Park Chanjun;Ohm Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1155-1162
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    • 2004
  • This paper is the forth paper of several companion papers which compare the method of Air-Fuel ratio determination. In the previous work, various AFR calculations were performed for various fuels and the results were compared with each other. The comparison, however, were limited to numerical value and estimation of each equation or method was insufficient. In this paper, the overall estimation of the methods was attempted. Also, the method of trouble shooting of instrumentation was presented. Through the estimation of methods, it is concluded that the Eltinge method contains inherently the most perfect thermal dissociation model as far as the exhaust composition is concerned; therefore, this might be regarded as the most general equation of AFR determination among the existing ones. The others might be considered as approximate form. In addition, the mal-distribution factor in Eltinge method is qualitatively equivalent to thermal dissociation chemical equilibrium constant K. Lastly, it is illustrated that all instrumentation error, including the sampling line leakage, can be easily detected through the analyzing the exhaust component on the Eltinge chart.

Chemical Reaction of Pentacene Growth on Hybrid Type Insulator by Annealing Temperature (하이브리드 타입 절연막 위에서 열처리 온도에 따른 펜타센 생성과 관련된 화학반응)

  • Oh Teresa
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.2 s.344
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    • pp.13-17
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    • 2006
  • Pentacene channel for organic thin film transistor was deposited on the SiOC film by thermal evaporation. The growth of pentacene is related with the Diels-Alder reaction and the nucleophilic reaction by the thermal induction. The surface is an important factor to control the recursive Diels-Alder reaction for growing of pentacene on SiOC far The terminal C=C double bond of pentacene molecule was broken easily as a result of attack of the nucleophilic reagents on the surface of SiOC film. The nucleophilic reaction can be accelerated by increasing temperature on surface, and it maks pentacene to grow hardly on the SiOC film with a flow rate ratio of $O_2/(BTMSM+O_2)=0.5$ due to its inorganic property. The nucleophlic reaction mechanism is $SN_2(bimolecular nucleophilic substitution)$ type.

Synthesis of Copper Nanoparticle by Multiple Thermal Decomposition and Electroless Ag Plating (복합적 열분해법을 이용한 구리 나노분말의 합성 및 무전해 은도금에 관한 연구)

  • PARK, JEONGSOO;KIM, SANGHO;HAN, JEONGSEB
    • Journal of Hydrogen and New Energy
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    • v.28 no.1
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    • pp.70-76
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    • 2017
  • To synthesize copper nanoparticle a thermal decomposition was adopted. And to solve the problem of surface oxidation of the synthesized copper powder an electroless Ag plating method was used. The size and shape of synthesized Cu nanoparticle were affected by the size of copper oxalate used as a precursor, reaction solvent, reaction temperature and amount of reducing agent. Especially reaction solvent is dominant factor to control shape of Cu nano-particle which can have the shapes of sphere, polygon and rod. In case of glycerol, it produced spherical shape of about 500 nm in size. Poly ethylene produced uniform polygonal shape in about 700 nm and ethylene glycol produced both of polygon and rod having size range between 500 and 1500 nm. The silver coated copper powder showed a high electrical conductivity.

Emission Characteristics of HCNG Engine with Compression Ratio Change (압축비 변화에 따른 HCNG 엔진의 배기 특성)

  • Lee, Sungwon;Lim, Gihun;Park, Cheolwoong;Choi, Young;Kim, Changgi
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.4
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    • pp.106-112
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    • 2013
  • Compression ratio is an important factor affecting engine performance and emission characteristics since thermal efficiency of spark ignition engine can be theoretically improved by increasing compression ratio. In order to evaluate the effect of compression ratio change in HCNG engine, natural gas engine was employed using HCNG30 (CNG 70 vol%, hydrogen 30 vol%). Combustion and emission characteristics of CNG and HCNG fuel was analyzed with respect to the change of compression ratio at each operating condition. The results showed that thermal efficiency improved and $CH_4$, $CO_2$ emission decreased with the increase in compression ratio while $NO_x$ emissions were decreased at a certain excess air ratio condition. Higher thermal efficiency and further reduction of exhaust emissions can be achieved by the increase of compression ratio and the retard of spark timing.

Effect of Thermal Treatment Conditions on Shapes of Inkjet Printed Silver Patterns (열처리 조건이 잉크젯 인쇄된 실버 패턴의 형상에 미치는 영향)

  • Shin, Kwon-Yong;Kang, Kyung-Tae;Cho, Young-June;Lee, Sang-Ho
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1712-1713
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    • 2011
  • Inkjet technology have many merits in plenty of industrial applications. However, deposited droplet has a very critical issue that is coffee ring effect, for the application to an industrial manufacturing process. To remove the coffee ring effect, the effect of thermal treatment conditions on shapes of inkjet printed silver patterns were investigated in various surface condition. The surface changes were characterized by the contact angle measurement. Droplets from a 50 ${\mu}m$ nozzle were printed on the substrate after optimizing the ejection of individual droplets. Ink with a high boiling point of main solvent results in coffee ring effect. This result implies that the dominant factor that determines the shape of droplet is the drying conditions of main solvent of silver nanoparticle colloidal ink. As a results, selecting a proper thermal treatment conditions is very crucial for better shapes of inkjet printed silver nanoparticle colloidal patterns.

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Estimation of the Properties for a Charring Material Using the RPSO Algorithm (RPSO 알고리즘을 이용한 탄화 재료의 열분해 물성치 추정)

  • Chang, Hee-Chul;Park, Won-Hee;Yoon, Kyung-Beom;Kim, Tae-Kuk
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.1
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    • pp.34-41
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    • 2011
  • Fire characteristics can be analyzed more realistically by using more accurate properties related to the fire dynamics and one way to acquire these fire properties is to use one of the inverse property estimation techniques. In this study two optimization algorithms which are frequently applied for the inverse heat transfer problems are selected to demonstrate the procedure of obtaining pyrolysis properties of charring material with relatively simple thermal decomposition. Thermal decomposition is occurred at the surface of the charring material heated by receiving the radiative energy from external heat sources and in this process the heat transfer through the charring material is simplified by an unsteady 1-dimensional problem. The basic genetic algorithm(GA) and repulsive particle swarm optimization(RPSO) algorithm are used to find the eight properties of a charring material; thermal conductivity(virgin, char), specific heat(virgin, char), char density, heat of pyrolysis, pre-exponential factor and activation energy by using the surface temperature and mass loss rate history data which are obtained from the calculated experiments. Results show that the RPSO algorithm has better performance in estimating the eight pyrolysis properties than the basic GA for problems considered in this study.

The Electrical Properties of GaN Individual Nanorod Devices by Wet-etching of the Nanorod Surface and Annealing Treatment (표면 습식 식각 및 열처리에 따른 GaN 단일 나노로드 소자의 전기적 특성변화)

  • Ji, Hyun-Jin;Choi, Jae-Wan;Kim, Gyu-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.2
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    • pp.152-155
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    • 2011
  • Even though nano-scale materials were very advantageous for various applications, there are still problems to be solved such as the stabilization of surface state and realization of low contact resistances between a semiconducting nanowire and electrodes in nano-electronics. It is well known that the effects of contacts barrier between nano-channel and metal electrodes were dominant in carrier transportation in individual nano-electronics. In this report, it was investigated the electrical properties of GaN nanorod devices after chemical etching and rapid thermal annealing for making good contacts. After KOH wet-etching of the contact area the devices showed better electrical performance compared with non-treated GaN individual devices but still didn't have linear voltage-current characteristics. The shape of voltage-current properties of GaN devices were improved remarkably after rapid thermal annealing as showing Ohmic behaviors with further bigger conductivities. Even though chemical etching of the nanorod surfaces could cause scattering of carriers, in here it was shown that the most important and dominant factor in carrier transport of nano-electronics was realization of low contact barrier between nano-channel and metal electrodes surely.

Evaluation of Direct Normal Radiation Resources for Construction of Solar Thermal Power System in Korea (국내 태양열발전시스템 설치를 위한 법선면 직달일사량 분석)

  • Jo, Dok-Ki;Kang, Yong-Heack
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.653-657
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    • 2007
  • Since the direct normal insolation is a main factor for designing any solar thermal power system, it is necessary to evaluate its characteristics all over the country. We have begun collecting direct normal insolation data since December 1990 at 16 different locations and considerable effort has been made for constructing a standard value from measured data at each station. KIER(Korea Institute of Energy Research's new data will be extensively used by solar thermal concentrating system users or designers as well as by research institutes. From the results, we can conclude that 1) Yearly mean 5.41kWh/$m^2$/day of the direct normal insolation was evaluated for clear day all over 16 areas in Korea. 2) Clear day's direct normal insolation of spring and summer were 5.54kWh/$m^2$/day and 5.86kWh/$m^2$/day, and for fall and winter their values were 5.32kWh/$m^2$/day and 4.92kWh/$m^2$/day respectively. So, spring and summer were higher, and fall and winter were lower than the yearly mean value.

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Observation on the Ignition Delay Time of Cool and Thermal Flame of n-heptane/alcohol Blended Fuel at Low Temperature Combustion Regime (저온연소조건에서 n-heptane/alcohol 혼합연료의 냉염과 열염에 대한 착화지연 관찰)

  • Song, Jaehyeok;Kang, Kijoong;Ryu, Seunghyup;Choi, Gyungmin;Kim, Duckjool
    • Journal of the Korean Society of Combustion
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    • v.18 no.4
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    • pp.12-20
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    • 2013
  • The ignition delay time is an important factor to understand the combustion characteristics of internal combustion engine. In this study, ignition delay times of cool and thermal flame were observed separately in homogeneous charge compression ignition(HCCI) engine. This study presents numerical investigation of ignition delay time of n-heptane and alcohol(ethanol and n-butanol) binary fuel. The $O_2$ concentration in the mixture was set 9-10% to simulate high exhaust gas recirculation(EGR) rate condition. The numerical study on the ignition delay time was performed using CHEMKIN codes with various blending ratios and EGR rates. The results revealed that the ignition delay time increased with increasing the alcohol fraction in the mixture due to a decrease of oxidation of n-heptane at the low temperature. From the numerical analysis, ethanol needed more radical and higher temperature than n-butanol for oxidation. In addition, thermal ignition delay time is sharply increasing with decreasing $O_2$ fraction, but cool flame ignition delay time changes negligibly for both binary fuels. Also, in high temperature regime, the ignition delay time showed similar tendency with both blends regardless of blending ratio and EGR rate.