• Title/Summary/Keyword: thermal factor

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Distribution Characteristics of Dioxins in Marine Sediment from Busan Port in Korea

  • Jeong, Tae-Uk;Seo, Dong-Cheol;Jeong, Seung-Ryul;Song, Bok-Joo;Cho, Jeong-Gu;Yoo, Pyung-Jong;Kim, Gi-Gon;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.107-111
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    • 2012
  • Eight marine sediments from Busan port in Korea were annually analyzed to examine the concentration distribution of dioxins from 2006 to 2010. Yearly mean concentration of dioxins ranged from 186.3 to $383.3pg\;g^{-1}$ in real values and 5.087 to 8.541 pg-TEQ (Toxicity equivalency) based on dry weight of samples. The dioxin concentration at the site near fishing market was the highest concentration among all sampling sites. Also the dioxin concentration at the sites with various pollutant sources such as large ships, sewage influx and thermal power station as well as fishing market was higher than that of the sites without specific pollutant sources. Another main factor that affects the dioxin concentration is topography characteristics of the bay. The bay has relatively high dioxin concentration because of the lack of the pollutant diffusion. This study demonstrated that the dioxin concentration in the site with pollutant sources and the lack of the pollutant diffusion was relatively high as compared with the other sites. As a result of contribution ratio of dioxin congeners, OCDD (Octachlorodibenzodioxin) in all sites was major contributor in real value, in contrast, dioxin congeners in TEQ values were dominated by 2,3,4,7,8-PeCDF.

Effects of Wet Oxidation on the Nitride with and without Annealing (열처리 전후의 질화막에 대한 습식산화의 효과)

  • Yun, Byeong-Mu;Choe, Deok-Gyun
    • Korean Journal of Materials Research
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    • v.3 no.4
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    • pp.352-360
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    • 1993
  • A nitride layer was df'posited on the thermal oxide layer by LPCVD process. ONO(oxidenitricle oxide) capacitors with various thickness of component layer wore fabricated by wet reoxidation of the nitride with and without anrwalmg treatment and their properties were investigated. As a result of observation on the refrative index and etching behavior of the ONO fIlms, the nitride layer OF 40 A thick ness was not so dense that the bottom oxide during the reoxidation process and the capability of securing the capacitance decreased. The conduction current in the ONO multl-Iayer dielctric film was reduced as the bottom(or top) oxide layer became thicker. However, in the case of oxide with thickness more than 50A, it merely plays a factor of reduction in capacitance, and the effect of barrier for hole injection was not so much increased. Annealing of the nitride laypr bpfore reoxidation did not show a grpat effects on the refractive index and capacitance of the film, however, the annealing process increased the breakdown voltage by 2${\cdot}$V.

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Wear Resistance of c-BN Surface Modified 316L Austenitic Stainless Steel by R.F. Sputtering (R.F. sputtering 방법에 의해 c-BN 표면처리된 316L 오스테나이트계 스테인리스 강의 내마모특성 향상)

  • Lee, Kwang-Min;Jeong, Se-Hoon;Park, Sung-Tae
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.194-198
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    • 2010
  • Cubic boron nitride (c-BN) is a promising material for use in many potential applications because of its outstanding physical properties such as high thermal stability, high abrasive wear resistance, and super hardness. Even though 316L austenitic stainless steel (STS) has poor wear resistance causing it to be toxic in the body due to wear and material chips, 316L STS has been used for implant biomaterials in orthopedics due to its good corrosion resistance and mechanical properties. Therefore, in the present study, c-BN films with a $B_4C$ layer were applied to a 316L STS specimen in order to improve its wear resistance. The deposition of the c-BN films was performed using an r.f. (13.56 MHz) magnetron sputtering system with a $B_4C$ target. The coating layers were characterized using XPS and SEM, and the mechanical properties were investigated using a nanoindenter. The friction coefficient of the c-BN coated 316L STS steel was obtained using a pin-on-disk according to the ASTM G163-99. The thickness of the obtained c-BN and $B_4C$ were about 220 nm and 630 nm, respectively. The high resolution XPS spectra analysis of B1s and N1s revealed that the c-BN film was mainly composed of $sp^3$ BN bonds. The hardness and elastic modulus of the c-BN measured by the nanoindenter were 46.8 GPa and 345.7 GPa, respectively. The friction coefficient of the c-BN coated 316L STS was decreased from 3.5 to 1.6. The wear property of the c-BN coated 316L STS was enhanced by a factor of two.

Study on the Environmental Factor Analysis of Interior Material using Hanji (한지 소재 내장재의 친환경적 요소 분석 연구)

  • Kim, Ji-Soo;Lee, Yu-Ra;Lim, Hyun-A
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.63-71
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    • 2011
  • Hanji has known for its high qualities for more than thousand years. Hanji is stronger, and has better durability, air permeability, flexibility, thermal insulation, soundproofs and UV absorbability. Therefore, developing industrial interior finishing materials using Hanji is replaced with the PVC (Poly-Vinyl Chloride) materials instead, it will be a new environment-friendly material and positively represents Korean brand marketing. The industrial inter-construction material is discomposed by heat or light because of material characteristics. As a result, it emits a lot of noxious substances. Hanji is essentially a neutral paper since it does not rely on any acidic chemicals of artificial bleaching methods. Hanji is also known as the living paper because of its close relation to nature. Therefore, I would like to suggest that Hanji made from alternative material as a chicken fiber. It will be a non-polluting interior finishing materials by making use of Hanji to a taste of Korean culture in the green industry around the world. Rather than PVC used commonly in construction material, kitchen and office furniture, interior materials in the subway, trains, or other vessels, credit cards, and ID cards, I created an interior construction material by using patented Hanji. This will be increased the value of usefulness in the environment-friendly green industry instead of PVC.

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Study on Temperature Variation by Greenhouse Soil Warming System Using Solar Thermal Energy (2) - Required Energy per Unit Area for Soil Warming - (태양열을 이용한 시설재배 지중변온가온의 토양 온도특성 연구(2) - 지중변온가온의 단위면적당 소요에너지 -)

  • Kim, Jin-Hyun;Kim, Tae-Wook;Nah, Kyu-Dong;Kim, Tae-Soo;Kim, Eun-Tae;Chung, Suk-Hyun
    • Journal of Biosystems Engineering
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    • v.35 no.1
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    • pp.46-52
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    • 2010
  • The temperature of root zone was known as an important factor for the growth of crops and reduction of energy in greenhouse. The purpose of this study was to design the apposite inflow of calories per the unit area by comparison of temperature in the warmed and non-warmed soil. The energy needed for soil warming about pipe length showed the change of temperature on inflow and outflow as $2^{\circ}C{\sim}3^{\circ}C$(average $2.5^{\circ}C$). Therefore, the inflow per the unit hour was 3,450, 57,5 kcal/$h{\cdot}m^2$ on soil heating respectively. The non-warmed soil temperature in greenhouse made a difference by depth and it was partially affected inner temperature under 15 cm, but it was not above 15 cm. The soil temperature would be raised over $5^{\circ}C$ than non-warmed soil to increase effect of soil warming. Therefore, the inflow per the unit area that should be provided was about 100 kcal/$h{\cdot}m^2$.

Distribution Characteristics and Background Air Classification of PM2.5 OC and EC in Summer Monsoon Season at the Anmyeondo Global Atmosphere Watch (GAW) Regional Station (안면도 기후변화감시소의 여름철 PM2.5 OC와 EC 분포 특성 및 배경대기 구분)

  • Ham, Jeeyoung;Lee, Meehye;Ryoo, Sang-Boom;Lee, Young-Gon
    • Atmosphere
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    • v.29 no.4
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    • pp.429-438
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    • 2019
  • Organic carbon (OC) and elemental carbon (EC) in PM2.5 were measured with Sunset Laboratory Model-5 Semi-Continuous OC/EC Field Analyzer by NIOSH/TOT method at Anmyeondo Global Atmosphere Watch (GAW) Regional Station (37°32'N, 127°19'E) in July and August, 2017. The mean values of OC and EC were 3.7 ㎍ m-3 and 0.7 ㎍ m-3, respectively. During the study period, the concentrations of reactive gases and aerosol compositions were evidently lower than those of other seasons. It is mostly due to meteorological setting of the northeast Asia, where the influence of continental outflow is at its minimum during this season under southwesterly wind. While the diurnal variation of OC and EC were not clear, the concentrations of O3, CO, NOx, EC, and OC were evidently enhanced under easterly wind at night from 20:00 to 8:00. However, the high concentration of EC was observed concurrently with CO and NOx under northerly wind during 20:00~24:00. It indicates the influence of thermal power plant and industrial facilities, which was recognized as a major emission source during KORUS-AQ campaign. The diurnal variations of pollutants clearly showed the influence of land-sea breeze, in which OC showed good correlation between EC and O3 in seabreeze. It is estimated to be the recirculation of pollutants in land-sea breeze cycle. This study suggests that in general, Anmyeondo station serves well as a background monitoring station. However, the variation in meteorological condition is so dynamic that it is primary factor to determine the concentrations of secondary species as well as primary pollutants at Anmyeondo station.

Thermo-physiological Responses by Presence of Vents and Difference in Clothing Length for Construction Site Working Clothes (통기구 유무와 옷 길이 차이에 따른 건설현장 작업복의 온열생리반응)

  • Kim, Seong-Suk;Kim, Hee-Eun
    • Fashion & Textile Research Journal
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    • v.20 no.2
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    • pp.202-209
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    • 2018
  • This study examined thermo-physiological responses according to the design change of construction site working clothes (control (C) working clothes; prototype (P) working clothes). We measured rectal temperature, skin temperature, micro-climate within the clothes and sweat rate. In the evaluation of physiological functionality, based on pattern improvement in working clothes, P working clothes showed significantly lower rectal temperatures, trunk and thigh skin temperatures than C working clothes. It is preferable that rectal temperature should be kept low during work that is not favorable to an increase in body temperature. P working clothes were more physiologically functional than C working clothes. In addition, P working clothes showed significantly lower temperatures in the trunk and thigh parts in a micro climate temperature. We could explain that the side seam zipper on the pants and the gusset on armpit parts create an air permeability effect of lowering the temperature of micro-climate. Aggressive ventilation through the slit of the garment is an important factor for the restoration of the physiological function of the worker at rest between work. Sweat rate showed a higher level in C working clothes than P working clothes. When working in a hot environment, workwear needs to be designed so that the worker is not exposed to thermal stress. Therefore, it was evaluated that the P work clothes used in this study alleviated the physiological burdens of heat.

Numerical Analysis of Thermal and Flow affected by the variation of rib interval and Pressure drop Characteristics (리브 간격 변화에 따른 열.유동 수치해석 및 압력 저하 특성)

  • Chung, Han-Shik;Lee, Gyeong-Wan;Shin, Yong-Han;Choi, Soon-Ho;Jeong, Hyo-Min
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.616-624
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    • 2011
  • The flow characteristics and heat transfer augment on the periodically arranged semi-circular ribs in a rectangular channel for turbulent flow has been investigated numerically. The aspect ratio of the rectangular channel was AR=5, the rib height to hydraulic diameter ratio were 0.07 and rib height to channel height ratio was set as e/H=0.117 for various PR(rib pitch-to-rib height rate) between 8~14, respectively. The SST k-${\omega}$ turbulence model and v2-f turbulence model were used to find out the heat transfer and the flow characteristics of near the wall which are suited to obtain realistic phenomena. The numerical analysis results show turbulent flow characteristics, heat transfer enhancement and friction factor as observed experimentally. The results predict that turbulent kinetic energy(k) is closely relative to the diffusion of recirculation flow. and v2-f turbulence model simulation results have a good agreement with experimental values.

Investigation of Ni/Cu Contact for Crystalline Silicon Solar Cells (결정질 실리콘 태양전지에 적용하기 위한 도금법으로 형성환 Ni/Cu 전극에 관한 연구)

  • Kim, Bum-Ho;Choi, Jun-Young;Lee, Eun-Joo;Lee, Soo-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.250-253
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    • 2007
  • An evaporated Ti/Pd/Ag contact system is most widely used to make high-efficiency silicon solar cells, however, the system is not cost effective due to expensive materials and vacuum techniques. Commercial solar cells with screen-printed contacts formed by using Ag paste suffer from a low fill factor and a high shading loss because of high contact resistance and low aspect ratio. Low-cost Ni and Cu metal contacts have been formed by using electroless plating and electroplating techniques to replace the Ti/Pd/Ag and screen-printed Ag contacts. Ni/Cu alloy is plated on a silicon substrate by electro-deposition of the alloy from an acetate electrolyte solution, and nickel-silicide formation at the interface between the silicon and the nickel enhances stability and reduces the contact resistance. It was, therefore, found that nickel-silicide was suitable for high-efficiency solar cell applications. The Ni contact was formed on the front grid pattern by electroless plating followed by anneal ing at $380{\sim}400^{\circ}C$ for $15{\sim}30$ min at $N_{2}$ gas to allow formation of a nickel-silicide in a tube furnace or a rapid thermal processing(RTP) chamber because nickel is transformed to NiSi at $380{\sim}400^{\circ}C$. The Ni plating solution is composed of a mixture of $NiCl_{2}$ as a main nickel source. Cu was electroplated on the Ni layer by using a light induced plating method. The Cu electroplating solution was made up of a commercially available acid sulfate bath and additives to reduce the stress of the copper layer. The Ni/Cu contact was found to be well suited for high-efficiency solar cells and was successfully formed by using electroless plating and electroplating, which are more cost effective than vacuum evaporation. In this paper, we investigated low-cost Ni/Cu contact formation by electroless and electroplating for crystalline silicon solar cells.

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Electrical Properties and Preparation of 6FDA/4-4'DDE Polyimide Thin films by Bapor Deposition Polymerization method (진공증착중합법을 이용한 6FDA/4-4'DDE 폴리이미드 박막의 제조와 전기적 특성)

  • 이붕주;김형권;이덕출
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.229-236
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    • 1998
  • In this paper, thin films of Polyimide (PI) were fabricated by vapor deposition polymerization method (VDPM) of dry processes. The film's properties with curing temperature and electrical properties were studies. The synthesis of hexafluoroisopropyliden-2,2-bis[phthalic anhydride](6FDA) and 4, 4'-diamino diphenyl ether (DDE) was carried out by vapor deposition polymerization(VDP) with the same deposition rate. The evaporation temperature of 6FDA and DDE were $214^{\circ}C$ and $137^{\circ}C$, respectively, so as to preserve balance of stoichiometry. The polymic acid (PAA) made by VDPM were changed to PI by thermal curing. The uniformity and density of PI thin films were increased according to increasing curing temperature. The relative permittivity and dissipation loss factor were 3.7 and 0.008 at the frequency of 100Hz~200KHz, respectively, for the fabricated in the curing temperature of $300^{\circ}C$. Also, the resistivity was about 1.05$\times$$ 10^{15}$$\Omega$cm at $30^{\circ}C$.

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