• Title/Summary/Keyword: thermal effects

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Effects of Crosslinking Agent and Flame Retardant on the Dielectric Properties of Poly(phenylene ether)-based Polymer Substrate Material (폴리페닐렌에테르계 고분자 기판 소재의 유전특성에 대한 가교제 및 난연제의 영향)

  • Kim, Dong-Kook;Park, Seong-Dae;Yoo, Myong-Jae;Lee, Woo-Sung;Kang, Nam-Kee;Lim, Jin-Kyu;Kyoung, Jin-Bum
    • Polymer(Korea)
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    • v.33 no.1
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    • pp.39-44
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    • 2009
  • Polymer substrates were fabricated by using poly (phenylene ether) as a base resin, N,N'-m-phenylenedimaleimide (PDMI) as a crosslinking agent and decabromodiphenylethane as a flame retardant. The effects of crosslinking agent and flame retardant on physical properties such as dielectric property of the substrate were investigated. Thermal curing feature of PDMI with or without an initiator was analyzed by DSC, and then, PPE-PDMI test compositions were designed based on this result. Composite sheets were cast by film coater, laminated under vacuum and pressure, and then, the changes of dielectric constant, dielectric loss, peel strength, solder heat resistance and inflammability according to increasing amount of PDMI and flame retardant were evaluated, Dielectric constant and dielectric loss showed increasing trend with increasing amount of PDMI and flame retardant, but solder heat resistance and inflammability were improved. Peel strength was obtained higher than 1 kN/m when PDMI above 10 wt% was added, but slightly decreased as the amount of flame retardant increased. From the measured gel contents, the reaction mechanism of PPE-PDMI system was deduced to the formation of network structure by crosslinking PDMI with PPE rather than the formation of semi-IPN structure. In conclusion, the polymer composite substrate materials with dielectric constant of 2.52$\sim$2.65 and dielectric loss below 0.002 at 1 GHz were obtained and they will be proper for high frequency applications.

A Numerical Study on the Extinguishing Effects of CO2 in Counterflow Diffusion Flames with the Concept of Local Application System (국소방출방식 개념의 대향류 확산화염에서 CO2 소화효과에 관한 수치해석 연구)

  • Mun, Sun-Yeo;Park, Chung-Hwa;Hwang, Cheol-Hong;Oh, Chang-Bo
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.55-62
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    • 2012
  • The suppression mechanisms of carbon dioxide ($CO_2$) as a representative fire suppression agent were revisited using a counterflow diffusion flame which could be applied the concept of a local application system. To end this, the low strain rate $CH_4$/air counterflow diffusions with $CO_2$ addition in either fuel or oxidizer stream were examined numerically using detailed-kinetic chemistry. Radiative heat loss due to radiating gas species including $CO_2$ added was considered by the optically thin model (OTM). As a result, the critical $CO_2$ volume fractions in the oxidizer stream required to extinguish the flame were in good agreement with the experimental data reported in the literature, while somewhat under-prediction was observed with $CO_2$ added in the fuel stream. The surrogate agents were adopted to estimate the quantitative contribution with changing in global strain rate ($a_g$) on the flame extinguishment among pure dilution effect, thermal effects including radiation heat loss and chemical effect due to the $CO_2$ fire suppression agent.

Potential Effects of Land-Use Change on the Local climete (토지이용 변화가 국지기후에 미치는 영향)

  • 이현영
    • Korean Journal of Remote Sensing
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    • v.11 no.3
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    • pp.83-100
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    • 1995
  • The land-use has changed rapidly during the last two decades in accordance with urbanization in the Seoul Metropolitan Region. As a result of these changes, the local climate has undergone changes as well. This study intends to define the land-use changes, and then to show how they have brought in significant changes in the local climates. Land-use changes in the study area so repidly that up-to date maps and documents are not available at present. Therefore, Landsat data for land-use classification and NOAA AVHRR thermal data for the temperature fields were analyzed. Additionary, to visualize the effect of the land-use on the local climate, computer-enhanced brightness temperatures, Green Belt and city boundaries were overlaid on land-use patterns obtained from satellite images using GIS techniques. The results of analysis demonstrate that Green Space in the Seoul Metropolitan Region decreased from 94% to 62% while urban land-use increased ten times, from 4% to 39% for the period of 1972-1992. The resulting disappearance of biomass caused by land-use changes may have implications for the local-and micro-climate. The results show that the local climate of the study area became drier and warmer. This study also suggests a need for further studies of man's effects on local climate to minimize adverse influences and hazardous pollution and efficacious ways for urban planning.

Effects of Mulching Practices on Soil Temperature and Soil Physical Properties (Mulching방법별(方法別) 토양온도(土壤溫度)와 토양물리성(土壤物理性) 변화(變化))

  • Jung, Pil-Kyun;Lee, Kwang-Seek;Ko, Mun-Hwan;Um, Ki-Tae;Ha, Ho-Seong
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.4
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    • pp.366-372
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    • 1985
  • Soil temperatures and soil physical properties were investigated in order to better understand the effects of mulchings in the red pepper field. The red pepper was planted in the lysimeter installed at the Yesan sandy loam with 20% slope and 10cm slope length. The results were summarized as follows: 1. Average soil temperatures at 10cm and 20cm depth in vinyl mulching plots were $1.6^{\circ}C$ and $1.1^{\circ}C$ higher than those of control, respectively. However, the average soil temperatures in rice straw mulching plots were relatively lower than those of control during the growing season. 2. The greatest diurnal fluctuation of soil temperature was found at the vinyl mulching plots and it was decreased with increasing soil depth. 3. The calculated thermal diffusivities were 0.011, 0.009 and $0.007cm^2/sec$ for the vinyl mulching, control and straw mulching, respectively. 4. Soil losses were 103kg/10a for the vinyl mulching and 36kg/10a for the straw mulching which were nearly negligible as compared to the control. 5. Soil physical properties such as bulk density, hardness and water content were significantly improved by the vinyl and straw mulchings.

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Effects of Shield Materials on the Growth and Yield Characteristics of Melon Grown inside a Plastic Greenhouse in Summer Season (고온기 멜론 시설재배 시 자재별 차광 효과)

  • Lee, Jae Han;Lee, Jung Sup;Kwon, Joon Kook;Yeo, Kyung Hwan;Bang, Ji Woong;Kim, Jin Hyun;Lee, Choung Keun;Park, Kyoung Sub;Myung, Dong Ju
    • Journal of Bio-Environment Control
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    • v.30 no.4
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    • pp.304-311
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    • 2021
  • This Experiment was conducted to determine the effects of light shield materials when melon grown inside a plastic greenhouse in summer season. The average temperatures were 36.6℃, 34.5℃ and 34.0℃ respectively for the control(non-shield), coating agent, and the white net. The light transmittances were 69% and 75%, respectively inside the greenhouse treated with the coating agent and white net immediately after applicants, compared with that inside the control greenhouse. At the 40 and 80 days after treatment, the light transmittances for the coating agent were 92% and 98%, respectively, indicating it was slowly decomposed and removed, but there was no change in the transmittance for the white net. While the leaf number did not differ among the treatments, the plant height was higher in the white net and shading agent than in control. The weight of the leaves, fresh-weight and dry-weight were no different from that of shading, but it became heavier in the later stages. The marketable fruit yield was increased by 6% for white nets and 5% for the coating agent compared to control, there was no statistical significance. Therefore, coating agent is considered as an effective method to lower temperature during high temperature period, but it is preferable to use it in consideration of cultivation period, because the coating agent is gradually removed.

Fabrication and Electrical Property Analysis of [(Ni0.3Mn0.7)1-xCux]3O4 Thin Films for Microbolometer Applications (마이크로볼로미터용 [(Ni0.3Mn0.7)1-xCux]3O4 박막의 제작 및 전기적 특성 분석)

  • Choi, Yong Ho;Jeong, Young Hun;Yun, Ji Sun;Paik, Jong Hoo;Hong, Youn Woo;Cho, Jeong Ho
    • Journal of Sensor Science and Technology
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    • v.28 no.1
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    • pp.41-46
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    • 2019
  • In order to develop novel thermal imaging materials for microbolometer applications, $[(Ni_{0.3}Mn_{0.7})_{1-x}Cu_x]_3O_4$ ($0.18{\leq}x{\leq}0.26$) thin films were fabricated using metal-organic decomposition. Effects of Cu content on the electrical properties of the annealed films were investigated. Spinel thin films with a thickness of approximately 100 nm were obtained from the $[(Ni_{0.3}Mn_{0.7})_{1-x}Cu_x]_3O_4$ films annealed at $380^{\circ}C$ for five hours. The resistivity (${\rho}$) of the annealed films was analyzed with respect to the small polaron hopping model. Based on the $Mn^{3+}/Mn^{4+}$ ratio values obtained through x-ray photoelectron spectroscopy analysis, the hopping mechanism between $Mn^{3+}$ and $Mn^{4+}$ cations discussed in the proposed study. The effects of $Cu^+$ and $Cu^{2+}$ cations on the hopping mechanism is also discussed. Obtained results indicate that $[(Ni_{0.3}Mn_{0.7})_{1-x}Cu_x]_3O_4$ thin films with low temperature annealing and superior electrical properties (${\rho}{\leq}54.83{\Omega}{\cdot}cm$, temperature coefficient of resistance > -2.62%/K) can be effectively employed in applications involving complementary metal-oxide semiconductor (CMOS) integrated microbolometer devices.

Effects of acute heat stress on salivary metabolites in growing pigs: an analysis using nuclear magnetic resonance-based metabolomics profiling

  • Kim, Byeonghyeon;Kim, Hye Ran;Kim, Ki Hyun;Ji, Sang Yun;Kim, Minji;Lee, Yookyung;Lee, Sung Dae;Jeong, Jin Young
    • Journal of Animal Science and Technology
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    • v.63 no.2
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    • pp.319-331
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    • 2021
  • Heat stress (HS) causes adverse impacts on pig production and health. A potential biomarker of HS is required to predict its occurrence and thereby better manage pigs under HS. Information about the saliva metabolome in heat-stressed pigs is limited. Therefore, this study was aimed to investigate the effects of acute HS on the saliva metabolome and identify metabolites that could be used as potential biomarkers. Growing pigs (n = 6, 3 boars, and 3 gilts) were raised in a thermal neutral (TN; 25℃) environment for a 5-d adaptation period (CON). After adaptation, the pigs were first exposed to HS (30℃; HS30) and then exposed to higher HS (33℃; HS33) for 24 h. Saliva was collected after adaptation, first HS, and second HS, respectively, for metabolomic analysis using 1H-nuclear magnetic resonance spectroscopy. Four metabolites had significantly variable importance in the projection (VIP > 1; p < 0.05) different levels in TN compared to HS groups from all genders (boars and gilts). However, sex-specific characteristics affected metabolites (glutamate and leucine) by showing the opposite results, indicating that HS was less severe in females than in males. A decrease in creatine levels in males and an increase in creatine phosphate levels in females would have contributed to a protective effect from protein degradation by muscle damage. The results showed that HS led to an alteration in metabolites related to energy and protein. Protection from muscle damage may be attributed to the alteration in protein-related metabolites. However, energy-related metabolites showed opposing results according to sex-specific characteristics, such as sex hormone levels and subcutaneous fat layer. This study had shown that saliva samples could be used as a noninvasive method to evaluate heat-stressed pigs. And the results in this study could be contributed to the development of a diagnostic tool as a noninvasive biomarker for managing heat-stressed pigs.

Measurements of Void Concentration Parameters in the Drift-Flux Model (상대유량 모델내의 기포분포계수 측정에 관한 연구)

  • Yun, B.J.;Park, G.C.;Chung, C.H.
    • Nuclear Engineering and Technology
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    • v.25 no.1
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    • pp.91-101
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    • 1993
  • To predict accurately the thermal hydraulic behavior of light water reactors during normal or abnormal operation, the accurate estimation of the void distribution is required. Up to date, many techniques for predicting void fraction of two-phase flow systems have been suggested. Among these techniques, the drift-flux model is widely used because of its exact calculation ability and simplicity. However, to get more accurate prediction of void fraction using drift-flux model, slip and flow regime effects must be considered more properly In the drift-flux method, these two effects are accounted for by two drift-flux parameters ; $C_{o}$ and (equation omitted). At earlier stage, $C_{o}$ is measured in a circular tube. In this study, $C_{o}$ is experimentally determined by measuring local void fraction and vapor velocity distribution in a rectangular subchannel having 4 heating rods which simulates nuclear subchannels. The measurements are peformed with two-electrical conductivity probes which are known to be adequate for measuring local parameters. The experiments are performed at low flow rate and the system pressure less than 3 atmo spheric pressure. In this experiment, (equation omitted), is not measured, but quoted from well-known empirical correlation to formulate $C_{o}$. Finally, $C_{o}$ is expressed as a function of channel averaged void fraction. fraction.

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Effect of Water Temperature and Photoperiod on the Oxygen Consumption of Four Different Strains of Red Seabream, Pagrus major

  • Oh, Sung-Yong;Choi, Hee Jung;Kim, Min-Suk;Park, Yong Joo;Myoung, Jung-Goo;Kwon, Joon Yeong;Choi, Cheol Young
    • Journal of Marine Life Science
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    • v.1 no.2
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    • pp.109-116
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    • 2016
  • We determined the effects of different water temperatures (15, 20, and 25℃) and photoperiod cycles (24L:0D, 12L:12D, and 0L:24D) on the oxygen consumption of the offspring of a cultured Japanese strain (JJ), a selected Korean strain (KK), and intraspecific hybrid strains (JK and KJ) of red seabream, Pagrus major, under starvation conditions. The different fish strains, water temperatures, and photoperiod cycles had effects on the mean oxygen consumption of fish. Oxygen consumption increased with increasing water temperatures for all photoperiod treatments (p<0.001). Fish held in continuous darkness (0L:24D) used consistently less oxygen than fish exposed to continuous light (p<0.05). The oxygen consumption of fish exposed to the light phase in a 12L:12D photoperiod was higher than that of fish in the dark phase of the 12L:12D cycle, and differences were significant in three of the strains: JJ (15℃), KK (15 and 20℃), and KJ (25℃). The oxygen consumption of the inbred (JJ and KK) and intraspecific hybrid (JK and KJ) strains varied with differing water temperatures and photoperiod cycles. The JK strain displayed significantly higher oxygen consumption than the other strains under all experimental conditions except 15℃ with a 0L:24D photoperiod. The JK and KJ strains usually showed the highest and lowest oxygen consumption values, respectively, whereas the inbred strains exhibited intermediate values. Oxygen consumption in the JJ and JK strains was usually higher than that of the KK and KJ strains. We propose that differences in the thermal sensitivity and photosensitization properties of the strains contribute to differences in their ability to adapt to changes in water temperature and photoperiod, thus resulting in differences in the amplitude of their metabolic rates.

The isobaric effect on the measurement of Gd isotopes by thermal ionization mass spectrometry (열이온화 질량분석기를 이용한 Gd 동위원소 측정에서 동중원소 영향)

  • Jeon, Young-Shin;Park, Jong-Ho;Joe, Kih-Soo;Han, Sun-Ho;Song, Kyuseok
    • Analytical Science and Technology
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    • v.22 no.5
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    • pp.415-421
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    • 2009
  • A study was performed to investigate the isobaric effects of impurities in isotope measurement of gadolinium by TIMS. Especially, the ratio of $^{155}Gd/^{158}Gd$ showed the higher value than that of natural gadolinium and also decreased as the measuring time increased. This phenomenon is considered to be due to the oxide form of La ($LaO^+$, m/z=155) causing to create a serious bias on the measurement of $^{155}Gd$ abundance by La as an impurity, and due to $LaO^+$ produced more than the $Gd^+$ in the early time which disappears as the time goes on because of lower melting point and ionization potential of La than Gd. Although isobaric effects from Ba($BaO^+$), Ce($CeO^+$), Sm($SmO^+$), La($LaO^+$), and $K_4{^+}$(m/z=156)-cluster were detected even when blank rhenium filaments were used, these could be avoided by preconditioning(baking out) the filament. And we found that the measurement of $GdO^+$ instead of $Gd^+$ is more suitable in avoiding the isobaric effect from impurities such as La, Ce and Ba in the measurement of Gd isotope only in case of absence or extremely low level of Yb, Sm, Dy, Er, Lu.