• Title/Summary/Keyword: thermal diffusion

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Comparison of Degradation Behaviors for Titanium-based Hard Coatings by Pulsed Laser Thermal Shock

  • Jeon, Seol;Lee, Heesoo
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.523-527
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    • 2013
  • Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

Dependence on Dopant of Ni-silicide for Nano CMOS Device (Nano CMOS소자를 위한 Ni-silicide의 Dopant 의존성 분석)

  • 배미숙;지희환;이헌진;오순영;윤장근;황빈봉;왕진석;이희덕
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.11
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    • pp.1-8
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    • 2003
  • In this paper, the dependence of silicide properties such as sheet resistance and cross-sectional profile on the dopants for source/drain and gate has been characterized. There was little difference of sheet resistance among the dopants such as As, P, BF$_2$ and B$_{11}$ just a(ter formation of NiSi using RTP (Rapid Thermal Process). However, the silicide properties showed strong dependence on the dopants when thermal treatment was applied after silicidation. BF$_2$ implanted silicon showed the most stable property, while As implanted one showed the worst. The main reason of the excellent property of BF$_2$ sample is believed to be tile retardation of hi diffusion by the flourine. Therefore, retardation of Ni diffusion is highly desirable for high performance Ni-silicide technology.y.

Property Analysis of Solar Selective Coatings (태양 선택흡수막의 특성 분석)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.33 no.4
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    • pp.31-38
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    • 2013
  • The chemical composition of the black Cr solar selective coatings electrodeposited were investigated for property analysis by using a XPS(X-ray photoelectron spectroscopy) before and after annealing in air at $300^{\circ}C{\sim}500^{\circ}C$ for 120 hours. Black Cr selective coating exposed by solar radiation for 5 months was compared with annealed sample. In addition, The Cu solar selective coatings were prepared by thermal oxidation method for low temperature application. The samples obtained were characterized by using the optical reflectance measurements by using a spectrometer. Optical properties of oxidized Cu solar coatings were solar absorptance $({\alpha}){\simeq}0.62$ and thermal emittance $({\epsilon}){\simeq}0.41(100^{\circ}C)$. In the as-prepared Cr black selective coating, the surface of the coating was found to have Cr hydroxide and Cr. The Cr hydroxide of the major component was converted to $Cr_2O_3$ or $CrO_3$ form after annealing at $500^{\circ}C$ with the desorption of water molecules. The black Cr selective coating was degraded significantly at temperature of $500^{\circ}C$. The main optical degradation modes of this coating were diffusion of Cu substrate materials.

The high thermal stability induced by a synergistic effect of ZrC nanoparticles and Re solution in W matrix in hot rolled tungsten alloy

  • Zhang, T.;Du, W.Y.;Zhan, C.Y.;Wang, M.M.;Deng, H.W.;Xie, Z.M.;Li, H.
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2801-2808
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    • 2022
  • The synergistic effect of ZrC nanoparticle pining and Re solution in W matrix on the thermal stability of tungsten was studied by investigating the evolution of the microstructure, hardness and tensile properties after annealing in a temperature range of 1000-1700 ℃. The results of metallography, electron backscatter diffraction pattern and Vickers micro-hardness indicate that the rolled W-1wt%Re-0.5 wt% ZrC alloy has a higher recrystallization temperature (1600 ℃-1700 ℃) than that of the rolled pure W (1200 ℃), W-0.5 wt%ZrC (1300 ℃), W-0.5 wt%HfC (1400-1500 ℃) and W-K-3wt%Re alloy fabricated by the same technology. The molecular dynamics simulation results indicated that solution Re atoms in W matrix can slow down the self-diffusion of W atoms and form dragging effect to delay the growth of W grain, moreover, the diffusion coefficient decrease with increasing Re content. In addition, the ZrC nanoparticles can pin the grain boundaries and dislocations effectively, preventing the recrystallization. Therefore, synergistic effect of solid solution Re element and dispersed ZrC nanoparticles significantly increase recrystallization temperature.

Investigation of transport of radionuclide in a thermal stratification test facility using radiotracer technique

  • Pant, Harish Jagat;Goswami, Sunil;Chafle, Sunil B.;Sharma, Vijay Kumar;Kotak, Vimal;Shukla, Vikram;Mishra, Amitanshu;Gohel, Nilesh C.;Bhattacharya, Sujay
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1449-1455
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    • 2022
  • A radiotracer investigation was carried out in a Thermal Stratification Test Facility (TSTF) with objectives of investigating the dispersion and diffusion of radionuclide and effectiveness of the thermocline to minimize the radionuclide content in the hot water layer. Technetium-99m (99mTc) as sodium pertechnetate was used as a radiotracer in the investigation. Qualitative analysis showed that a thermocline is formed within the TSTF and is effective in preventing the transport of radionuclide from bottom section to the top section of the facility. It was found that the radiotracer injected at the bottom of the pool took about 17.4 h to disperse from bottom to the top of the facility. The results of the investigation helped in understanding the effectiveness of hot water layer and thus to minimize the pool top radiation levels.

Prediction of Thermal Conductivity of Spatially Reinforced Composites (다방향으로 입체 보강된 복합재의 열전도계수 예측)

  • 이상의;유재석;김천곤;홍창선;김광수
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.238-243
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    • 2001
  • This paper predicted the thermal conductivity of spatially reinforced composites(SRC) by applying the volume averaging method and the thermal resistance method. The former method employs existing micro-mechanical theories and conventional transformation rules to constitute relations for the unit cells of the composites and the latter one uses the analogy between the diffusion of heat and electrical charge. To verify the theoretical prediction, the thermal conductivity of 4-D(dimensional) SRC was examined experimentally. The comparison of the numerical results with those measured by the experiment showed good agreement.

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Detection of Thermal Effluent Discharged from Nuclear Power Plant Using Airborne MSS and Landsat ETM+

  • Han, Joung-Gyu;Chi, Kwang-Hoon;Yeon, Young-Kwang
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.323-329
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    • 2002
  • The thermal effluent discharged from nuclear power plants can affect the offshore ecosystem change. The ability of measuring sea surface temperature in high resolution with Airborne MSS thermal spectral band(8.5 $\mu$m ~ 12.5 $\mu$m) and Landsat ETM+(10.4$\mu$m ~ 12.5 $\mu$m) gives us an information of spread range of thermal effluent. This information can be used as one of major factors fur analyzing the impact of the fish farm damage around the nuclear power plants. Every season from November 1999, this research has been conducted to investigate the extent of diffusion of thermal effluent discharged from KoRi, UlJin and WolSung Nuclear Power Plant located at the coastline of the East Sea of Korea.

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The Thermal Diffusivity of Standard Pieces for Spark Test (불꽃試驗용 標準試片 의 熱擴散 係數)

  • 차경옥;이관수;이흥주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.3
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    • pp.319-327
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    • 1983
  • The thermal diffusivity one of the series of standard pieces for spark test are determined by the flash method. The standard pieces are composed with carbon steels, structural carbon steels, alloy steels and high speed tool steels. In order to compute the thermal conductivity of the standard pieces, their specific heats are measured by a differential scanning calorimeter. The thermal conductivities are calculated from the data of specific heat, density and thermal diffusivity. To increase the accuracy of data for the thermal diffusivity by data reduction excursion method in the flash method, the governing heat diffusion equation, which is closely described experimental conditions with the finite pulse and the heat loss from the sample surfaces, is solved. In this analysis an integral transform is used.

Analysis of Thermal Relaxation Time of Tissues Subject to Pulsed Laser Irradiation (초단파 레이저 조사시 티슈 열완화 시간 분석)

  • Kim, Kyung-Han;Lee, Jae-Hoon;Suh, Jeong
    • Laser Solutions
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    • v.12 no.2
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    • pp.17-25
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    • 2009
  • Two methodologies for predicting thermal relaxation time of tissue subjected to pulsed laser irradiation is introduced by the calculation the optical penetration depth and by the investigation of the temperature diffusion behavior. First approach is that both x-axial and y-axial thermal relaxation times are predicted and they are superposed to achieve the thermal relaxation time (${\tau}_1$) for two-dimensional square tissue model. Another approach to achieve thermal relaxation time (${\tau}_2$) is measuring the time required for local temperature drop until $e^{-1}$ of the maximum laser induced heating.

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Enhancement of light reflectance and thermal stability in Ag-Mg alloy contacts on p-type GaN

  • Song, Yang-Hui;Son, Jun-Ho;Kim, Beom-Jun;Jeong, Gwan-Ho;Lee, Jong-Ram
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.18-20
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    • 2010
  • The mechanism for suppression of Ag agglomeration in Ag-Mg alloy ohmic contact to p-GaN is investigated. The Ag-Mg alloy ohmic contact shows low contact resistivity of $6.3\;{\times}\;10^{-5}\;{\Omega}cm^2$, high reflectance of 85.5% at 460 nm wavelength after annealing at $400^{\circ}C$ and better thermal stability than Ag contact The formation of Ga vacancies increase the net hole concentration, lowering the contact resistivity. Moreover, the oxidation of Mg atoms in Ag film increase the work function of Ag-Mg alloy contact and prevents Ag oxidation. The inhibition of oxygen diffusion by Mg oxide suppresses the Ag agglomeration, leading to enhance light reflectance and thermal stability.

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