• Title/Summary/Keyword: thermal aging

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The Study on Characteristics for Thermal Aging of the Layer Insulation in Transformers (변압기 층간 절연지의 열열화 특성 평가에 관한 연구)

  • 이병성;송일근;김동명;박동배;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.406-409
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    • 2002
  • The primary insulation system used in an oil-filled transformer is Kraft paper, wood, porcelain and, of course, oil. Modern transformers use paper that is chemically treated to improve its tensile strength properties and resistance to aging caused by immersion in oil. These insulation papers are mainly aged to thermal stress. Over the course of the insulation paper and oil's life it is exposed to high temperatures, oxygen and water. Its interaction with the steel of the tank and core plus the copper and aluminium of the windings will eventually cause the chemical properties of the oil to decay. High temperature have an effect on mechanical strength of cellulous paper using the layer insulation. We made two aging cell in which thermal aging tests of insulation papers and mineral oil are conducted. It is measured dielectric strength, number of acid, moisture, etc. of insulation paper and oil aged in the aging cells.

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Effect of long-term thermal aging on the microstructural and mechanical characteristics of nickel-based alloy weldment (니켈계 합금 용접부의 미세조직 및 기계적 특성에 대한 장기 열적 시효의 영향)

  • Yoo, Seung Chang;Ham, Junhyuk;Kim, Ji Hyun
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.12 no.1
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    • pp.41-48
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    • 2016
  • To investigate the effect of long-term thermal aging on the microstructural and mechanical characteristics of weldment made of nickel base alloy and its weld metal, an accelerated heat treatment was applied to simulate the process of long-term thermal aging in the operating condition of nuclear power plant. A representative nickel-based weldment with Alloy 600 and Alloy 182 was fabricated and heat-treated at $400^{\circ}C$ for 1,713 h and 3,427 h to simulate the thermal aging for the period equivalent to 15 and 30 years in operating pressurized water reactors, respectively. The microstructural and mechanical characteristics were analyzed by using optical microscopy, scanning electron microscopy and Vickers microhardness measurement. Changes were observed in precipitation behavior and microhardness of each specimen, and these changes were mainly attributed to the change in precipitated morphology and residual stress across the weld during the thermal aging process.

Effects of Accelerated Thermal Aging on Dynamic Properties of Laminated Rubber Bearings (적층고무받침의 가속 열 노화 동적특성 영향)

  • Oh, Ju;Jung, Hie-Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.5A
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    • pp.417-424
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    • 2010
  • The dynamic properties of laminated rubber bearings used as isolators in structures could be significantly deteriorated because of the change of microstructure in rubber caused by thermal aging. As a result, a catastrophic failure of bridges and buildings unexpectedly occurs when they are subjected to earthquake attack. Here, the dynamic properties of laminated rubber bearings before and after different of compression-shear loading and repeated cycles loadings, ultimated failure test with thermal aging were first measured and compared to each other. The experimental results, the effects of thermal aging on the shear stiffness, energy absorption, and equivalent damping coefficient of laminated rubber bearings are investigated. It is found that the deterioration of dynamic properties of laminated rubber bearings caused by thermal aging is significant and should be taken into account in designing rubber bearings.

Evaluation of Mechanical Properties with Thermal Aging in CF8M/SA508 Welds (CF8M과 SA508 용접재의 열화거동과 기계적특성 평가)

  • 우승완;최영환;권재도
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.12
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    • pp.1968-1973
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    • 2004
  • Structural degradations are often experienced on the components of nuclear power plants in reactor pressure vessels (RPV) and steam generators (SG) when these components are exposed to high temperature and high pressure for a long period of time. Such conditions result in the change of microstructures and of mechanical properties of materials, which requires an evaluation of the safeguards related to structural integrity. In a primary reactor cooling system (RCS), a dissimilar weld zone exists between cast stainless steel (CF8M) in a pipe and low-alloy steel (SA508 cl.3) in a nozzle. Thermal aging is observed in CF8M as the RCS is exposed for a long period of time under the operating temperature between 290 and 33$0^{\circ}C$. Under the same conditions, it is well known that degradation is not observed in low alloy steel. An investigation of the effect of thermal aging on the various mechanical properties of the dissimilar weld zone is required. The purpose of the present investigation is to find the effect of thermal aging on the dissimilar weld zone. The specimens are prepared by an artificially accelerated aging technique maintained for various times at 43$0^{\circ}C$, respectively. Then, The various mechanical test for the dissimilar welds are performed.

Studies on the aging behavior of coated paper(III) - The application of new coating binder for anti-thermal aging - (도공지 노화에 관한 연구(III) - 도공지 노화방지를 위한 새로운 도공용 바인더 적용 -)

  • Sin, U-Seul;Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.339-347
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    • 2011
  • This study was carried out in order to manufacture the high quality coated paper. High quality coated paper includes not only present state but also the state of the future. So in this study, acrylic-styrene emulsion which polymerized in laboratory was compared with SB(Styrene-butadiene) latex during thermal aging. The coated paper with three different formulations which controlled the dosage of acrylic-styrene emulsion were prepared. The coated paper were thermally aged at $105^{\circ}C$ for 18days and the optical properties were measured. Brightness, whiteness and CIE L value were higher during thermal aging with increasing amount of acrylic-styrene emulsion. CIE $a^*$ value was higher and CIE $b^*$ value decreased with increasing amount of acrylic-styrene emulsion. These results indicate that high quality coated paper which has anti -thermal aging property can be manufactured with acrylic-styrene emulsion.

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Influence of Aging of Lead Rubber Bearing on Seismic Performance of Bridges (납고무받침의 노화가 교량의 내진성능에 미치는 영향)

  • Park, Seong-Kyu;Oh, Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.2A
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    • pp.109-116
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    • 2012
  • The dynamic properties of lead rubber bearings, which are used as isolator, are dependent on the main rubber's dynamic behaviors and nonlinear qualities. Rubber materials tend to undergo an aging process under the influence of mechanical or environmental factors, so they can end up inevitably facing damage. A main cause of such aging is known to be oxidization, which occurs through the heat of reaction at high temperatures. Accordingly, in this study an accelerated thermal aging test was carried out in order to compare the characteristic values of the bearings with each other before and after thermal aging occurs. As a result of this experiment, it was found that a thermal aging phenomenon could have an effect on shear stiffness, energy absorption, and equivalent damping coefficients. Furthermore, a decline in the dynamic properties of the lead rubber bearings by means of the thermal aging process was applied to an actual bridge and the effects of such thermal aging on the seismic performance of the bridge were also compared and analyzed based on numerical analysis. As a result of this analysis, it was found that the changes in the basic properties of the lead rubber bearings have a minor effect on the seismic performance of bridges.

Study on the Thermal Degradation Behavior of FKM O-rings

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myoung Chan;Yoon, Yoo-Mi;Park, Sung Han;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.213-219
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    • 2018
  • The degradation mechanism and physical properties of an FKM O-ring were observed with thermal aging in this experiment. From X-ray photoelectron spectroscopy (XPS) analysis, we could observe carbon (285 eV), fluoro (688 eV), and oxygen (531 eV) peaks. Before thermal aging, the concentration of fluoro atoms was 51.23%, which decreased to 8.29% after thermal aging. The concentration of oxygen atoms increased from 3.16% to 20.39%. Under thermal aging, the FKM O-ring exhibited debonding of the fluoro-bond by oxidation. Analysis of the C1s, O1s, and F1s peaks revealed that the degradation reaction usually occurred at the C-F, C-F2, and C-F3 bonds, and generated a carboxyl group (-COOH) by oxidation. Due to the debonding reaction and decreasing mobility, the glass transition temperature of the FKM O-ring increased from $-15.91^{\circ}C$ to $-13.79^{\circ}C$. From the intermittent CSR test, the initial sealing force was 2,149.6 N, which decreased to 1,156.2 N after thermal aging. Thus, under thermal aging, the sealing force decreased to 46.2%, compared with its initial state. This phenomenon was caused by the debonding reaction and decreasing mobility of the FKM O-ring. The S-S curve exhibited a 50% increase in modulus, with break at a low strain and stress state. This was also attributed to the decreasing mobility due to thermal aging degradation.

Chlorine Effect on Thermal Aging Behaviors of BR and CR Composites

  • Choi, Sung-Seen;Kim, Jong-Chul
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2613-2617
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    • 2010
  • Chloroprene is a chlorine substituent of 1,3-butadiene. Butadiene rubber (BR) and chloroprene rubber (CR) composites were thermally aged at 60, 70, 80, and $90^{\circ}C$ for 2 - 185 days in a convection oven and changes of the crosslink densities by the accelerated thermal aging were investigated. The crosslink densities increased as the aging time elapsed and as the aging temperature became higher. Degrees of the crosslink density changes of the BR composite were on the whole larger than those of the CR one except the short-term thermal aging at 60 and $70^{\circ}C$. The crosslink densities abnormally increased after themal aging at high temperatures for a long time. Activation energies for the crosslink density changes of the rubber composites tended to increase with increase of the aging time and the variation showed a local minimum. The activation energies of the CR composite were lower than those of the BR one. The experimental results were explained with a role of ligand of chlorine atom of CR in a zinc complex, steric hindrance by chlorine atom of CR, and oxidation of rubber chain.

A comprehensive study of the effects of long-term thermal aging on the fracture resistance of cast austenitic stainless steels

  • Collins, David A.;Carter, Emily L.;Lach, Timothy G.;Byun, Thak Sang
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.709-731
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    • 2022
  • Loss of fracture resistance due to thermal aging degradation is a potential limiting factor affecting the long-term (80+ year) viability of nuclear reactors. To evaluate the effects of decades of aging in a practical time frame, accelerated aging must be employed prior to mechanical characterization. In this study, a variety of chemically and microstructurally diverse austenitic stainless steels were aged between 0 and 30,000 h at 290-400 ℃ to simulate 0-80+ years of operation. Over 600 static fracture tests were carried out between room temperature and 400 ℃. The results presented include selected J-R curves of each material as well as K0.2mm fracture toughness values mapped against aging condition and ferrite content in order to display any trends related to those variables. Results regarding differences in processing, optimal ferrite content under light aging, and the relationship between test temperature and Mo content were observed. Overall, it was found that both the ferrite volume fraction and molybdenum content had significant effects on thermal degradation susceptibility. It was determined that materials with >25 vol% ferrite are unlikely to be viable for 80 years, particularly if they have high Mo contents (>2 wt%), while materials less than 15 vol% ferrite are viable regardless of Mo content.

Accelerated Thermal Aging Measurement and Analysis of CSPE Cable for Condition Monitoring (CSPE 케이블의 상태감시를 위한 가속열화 측정 분석)

  • Park, Joung-Ho;Cha, Wang-Cheol;Lee, Jung-Hoon;Cho, Uk-Rae;Kim, Jae-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.3
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    • pp.88-95
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    • 2015
  • The accelerated thermal aging of CSPE(Chloro Sulfonate Polyethylene) was carried out for 40.41, 121.22, 202.04 days, 16.82, 50.45, 84.09 days and 7.32, 21.96, 36.59 days at 100, 110, and $120^{\circ}C$, respectively, which are equivalent to 20, 60, 100 years of aging at $50^{\circ}C$. The permittivities and the apparent densities of the accelerated thermally aged CSPE samples are increased with accelerated thermal aging year but EAB(Elongation at Break) is decreased with that. The dielectric strength and the electric breakdown of the non-accelerated and accelerated thermally aged CSPE samples do not depend on accelerated thermal aging year and applied voltage rising time. density and EAB measures.