• Title/Summary/Keyword: the thermal treatment time

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Structural and Electrical Properties of $CuInSe_2$ Ternary Compound Thin Film ($CuInSe_2$ 3원 화합물 박막의 전기적 구조적 특성)

  • Kim, Young-Jun;Yang, Hyeon-Hun;Park, Joung-Yun;Jeong, Woon-Jo;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.258-259
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    • 2005
  • [ $CuInSe_2$ ] thin films were fabricated at various fabrication conditions (substrate temperature, sputtering pressure, BC/RF power, vapor deposition, heat treatment). And structural and electrical properties were measured in order to certify optimum conditions for growth of the ternary compound semiconductor $CuInSe_2$ thin films with stoichiometric composition. $CuInSe_2$ thin film was well made at the heat treatment of 500[$^{\circ}C$] of SLG/Cu/In/Se stacked elemental layer which was prepared by sputter and thermal evaporator, and chemical composition of the thin film was analyzed nearly as the proportion of 1 : 1 : 2. At the same time, carrier concentration, hall mobility and resistivity of the thin films was $1.27\sim9.88\times10^{17}[cm^{-3}]$, $49.95\sim185[cm^2/V{\cdot}s]$ and $10^{-1}\sim10^{-2}[\Omega{\cdot}cm]$, respectively

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Fabrication and Applications of Carbon Nanotube Fibers

  • Choo, Hungo;Jung, Yeonsu;Jeong, Youngjin;Kim, Hwan Chul;Ku, Bon-Cheol
    • Carbon letters
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    • v.13 no.4
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    • pp.191-204
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    • 2012
  • Carbon nanotubes (CNTs) have exceptional mechanical, electrical, and thermal properties compared with those of commercialized high-performance fibers. For use in the form of fabrics that can maintain such properties, individual CNTs should be held together in fibers or made into yarns twisted out of the fibers. Typical methods that are used for such purposes include (a) surfactant-based coagulation spinning, which injects a polymeric binder between CNTs to form fibers; (b) liquid-crystalline spinning, which uses the nature of CNTs to form liquid crystals under certain conditions; (c) direct spinning, which can produce CNT fibers or yarns at the same time as synthesis by introducing a carbon source into a vertical furnace; and (d) forest spinning, which draws and twists CNTs grown vertically on a substrate. However, it is difficult for those CNT fibers to express the excellent properties of individual CNTs as they are. As solutions to this problem, post-treatment processes are under development for improving the production process of CNT fibers or enhancing their properties. This paper discusses the recent methods of fabricating CNT fibers and examines some post-treatment processes for property enhancement and their applications.

Mechanical properties of CaO-MgO-Al2O3-SiO2-based glass-ceramic glaze for ceramic tiles fabricated by controlled heat-treatment

  • Jeong-U Eom;Seunggu Kang;Kangduk Kim;Jin-Ho Kim
    • Journal of Ceramic Processing Research
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    • v.22 no.5
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    • pp.568-575
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    • 2021
  • Glass-ceramic glazes were prepared using a CaO-MgO-Al2O3-SiO2 system and were used to fabricate low-temperature firing,high-hardness glazes in ceramic tiles. Additives (B2O3) and a nucleating agent (TiO2) were added to the glaze, and crystallineglazes were obtained by sintering at 1000 ~ 1100 oC for 30 or 60 min. X-ray diffraction analysis of the glazes suggested thatcordierite (Mg2Al4Si5O18) and anorthite (CaAl2Si2O8) crystal phases were present, and the peak intensity of the cordieritecrystal phase increased with increasing sintering temperature. All samples showed high crystallinities of 70% or more,irrespective of sintering temperature or time. The glaze density increased with increasing sintering temperature and decreasedat 1100 oC. The Vickers hardness test results of the glazes indicated high hardness values of 6.79 and 6.77 GPa after 30 minheat treatment at 1000 oC and 60 min at 1050 oC, respectively. Glass-ceramic glaze with high hardness at low temperature wasfabricated through crystallization of glaze for tiles.

The Study of Waste Treatment using Advanced Oxygen Enriched Combustion System (산소부하 연소 시스템을 이용한 폐기물 열처리에 관한 연구)

  • Lee, Keon-Joo
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.231-239
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    • 2003
  • In this study, the waste of landfill was treated using advanced enriched oxygen combustion system. The oxygen concentration of this study was 21%, 25%, 30% and 40% and the operating capacity was 200 g/min and the residence time was 10 minutes. As increased the oxygen concentration of combustion air. temperature of the incinerator was increased and the temperature was increased rapidly when the oxygen concentration was 30%. As increased the oxygen concentration, the NOx (ppm) of flue gas increase d for thermal NOx, however the CO (ppm) of flue gas decreased according to the increase of combustion efficiency . The optimum operation condition of incineration was obtained when the oxygen concentration is 30%${\sim}$40%. The unburned carbon of ash decreased from 10% to 4% when the oxygen concentration was increased from 21% to 30%, therefore the high combustion efficiency can be obtained if used the oxygen enriched combustion system.

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A Study on the Improvement of Physical and Dyeing Properties of Silk Fabrics (견직물의 물성과 염색성 개선에 관한 연구)

  • 장병호;박성윤
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.122-130
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    • 1992
  • To improve the physical properties and the dyeing properties of silk, the silk fabric was treated with urea resin and reactive dyeing. The effects of urea resin concentration, pH of padding bath and curing condition were investigated in order to find optimum condition and the following results are obtained The optimum condition for the crease recovery of silk fabric was urea resin concentration of 80 g/ι, pH of 7, the curings temperature of about 135$^{\circ}C$, and the curing time of 3 minutes. The crease recovery and the thermal insulation ratio of silk fabric were increased by the above treatment. K/S increased as the adding amount of Na$_2$SO$_4$ increased, K/S, however was not affected by the adding amount of Na$_2$CO$_3$. Co1or fastness of the dyed fabrics treated with urea resin were improved slightly compared with untreated ones.

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The effect of plamsa treatment on superconformal copper gap-fill

  • Mun, Hak-Gi;Kim, Seon-Il;Park, Yeong-Rok;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.249-249
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    • 2010
  • The effect of forming a passivation layer was investigated in superconformal Cu gap-filling of the nano-scale trench with atomic-layer deposited (ALD)-Ru glue layer. It was discovered that the nucleation and growth of Cu during metal-organic chemical vapor deposition (MOCVD) were affected by hydrogen plasma treatments. Specifically, as the plasma pretreatment time increased, Cu nucleation was suppressed proportionally. XPS and Thermal Desorption Spectroscopy indicated that hydrogen atoms passivate the Ru surface, which leads to suppression of Cu nucleation owing to prevention of adsorption of Cu precursor molecules. For gap-fill property, sub 60-nm ALD Ru trenches without the plasma pretreatment was blocked by overgrown Cu after the Cu deposition. With the plasma pretreatment, superconformal gap filling of the nano-scale trenches was achieved due to the suppression of Cu nucleation near the entrances of the trenches. Even the plasma pretreatment with bottom bias leads to the superconformal gap-filling.

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LANDFILL STABILIZATION WITH LANDFILL MINING AND THERMAL TREATMENT PROCESS

  • Gust, Micheal A.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1996.12a
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    • pp.97-101
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    • 1996
  • Municipal and sanitary landfills can pose environmental problems due to leachate, landfill gas md unstable geotechnical properties. Most governmental bodies delay the correction of landfill problems or landfill replacement until a crises stage is reached. The replacement of a landfill is often made difficult due to costly regulatory controls, public opposition to siting and the high cost of closure for the previous landfill unit. Solutions to extending landfill life and capacity Involve waste minimization by recycling, refuse compaction and waste-to-energy incineration. Incineration can reduce the volume of refuse by 50-95%. The largest installed bases of municipal waste Incinerators are located in Japan and the U.S. The volume of waste contained in a landfill can be estimated by load count tabulations, weight-and-volume measurements or a material balance analysis based on the trash profile of user categories. for an existing landfill, core samples may be collected and analyzed for use in a material balance analysis. Newly generated refuse contains approximately 50% of the heating value of coal. However, landfill properties vary significantly due to the waste profile of the contributors and biodegradation due to time and weathering. The volume of the Nanji-do landfill

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Synthesis and Characterization of CNT/TiO2 Composites Thermally Derived from MWCNT and Titanium(IV) n-Butoxide

  • Oh, Won-Chun;Chen, Ming-Liang
    • Bulletin of the Korean Chemical Society
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    • v.29 no.1
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    • pp.159-164
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    • 2008
  • Two kinds of CNT/TiO2 composite photocatalysts were synthesized with multi-walled carbon nanotubes (MWCNTs) and titanium(IV) n-butoxide (TNB) by a MCPBA oxidation method. Since MWCNTs had charge transfer and semiconducting, the CNT/TiO2 composite shows a good photo-degradation activity. The XRD patterns reveal that only anatase phase can be identified for MCT composite, but the HMCT composite synthesized with HCl treatment was observed the mixed phase of anatase and rutile. The EDX spectra were shown the presence as major elements of Ti with strong peaks. From the SEM results, the sample MCT and HMCT synthesized by the thermal decomposition with TNB show a homogenous sample with only individual MWCNTs covered with TiO2 without any jam-like aggregates between CNTs and TiO2. From the photocatalytic results, we could be suggested that the excellent activity of the CNT/TiO2 composites for organic dye and UV irradiation time could be attributed to combination effects between TiO2 and MWCNTs with plausible photodegradation mechanism.

Evaporative Heat Transfer Characteristics of Droplet on Oxi-nitriding Surface (산질화 표면에서 액적의 증발열전달 특성)

  • Kim, Dae Yun;Lee, Seong Hyuk
    • Journal of ILASS-Korea
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    • v.21 no.1
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    • pp.53-57
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    • 2016
  • The present study aims to experimentally investigate the evaporative heat transfer characteristics of Oxi-nitriding SPCC surface. Moreover, the heat transfer coefficient was examined with respect to surface temperature during droplet evaporation. In fact, the nitriding surface showed significant enhancement for anticorrosion performance compared to bare SPCC surface but the thermal resistance also increased due to the formation of compound layer. From the experimental results, the evaporative behavior of sessile droplet on nitriding surface showed similar tendency with the bare surface. Total evaporation time of sessile droplet on the nitriding surface was delayed less than 5%. The difference in heat transfer coefficient increased with the surface temperature, and the maximum difference was estimated to be around 11% at $80^{\circ}C$ surface. Thus, this nitriding surface treatment method could be useful for seawater heat exchanger industries.

Characteristics of Aging of Ni-Ti Alloy Used for Implant Fabrications(I) (생체주입용 Ni-Ti 합금의 시효특성(I))

  • Cho, Hyung-June;Lee, Jun-Hee;Park, Ki-Ryoung
    • Journal of Biomedical Engineering Research
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    • v.10 no.3
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    • pp.261-268
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    • 1989
  • The characteristics of aging of near-equiatomic Ni-Ti alloy has been studied by the three point bend test and the measurement of Differential Scanning Calorimetry(DSC). The DSC is used to measure precise transformation temperatures and the amount of thermal energy required for the corresponding phase transformation. The effort of hardness on aging treatment in saline solution of $37^{\circ}C$ was higher for the annealed than solution treated specimens. As the testing temperature inc- rease from under $M_f$ to above $A_f$ temperature, the elastic stiffness increased. Almost full recovery can be achieved after bending below Belo outer fiber strain. Total bend recovery decreased gradually as aging time and bend angle is increased.

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