• Title/Summary/Keyword: the dots

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Advances in Nanomaterials-Based Color Conversion Layer (나노물질 기반의 광변환층 개발 동향)

  • Kim, Dongryong;Choi, Moon Kee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.6
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    • pp.547-555
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    • 2022
  • Color conversion layer refers to a layer that converts the blue light emitted from the backlight into the red and green light. Heavy metal-free quantum dots and perovskite nanocrystals have attracted great attention as base materials for color conversion layers due to their outstanding optical characteristics. Here, we review recent advances in the development of color conversion layers based on quantum dots. First, we overview the representative optical characteristics of quantum dots and perovskite nanocrystals, and then introduce printing techniques for color converting layers including photolithography, inkjet printing, and nanoimprinting. Finally, we conclude this review with a brief perspective.

Bandgap Tuning and Quenching Effects of In(Zn)P@ZnSe@ZnS Quantum Dots

  • Sang Yeon Lee;Su Hyun Park;Gyungsu Byun;Chang-Yeoul Kim
    • Journal of Powder Materials
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    • v.31 no.3
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    • pp.226-235
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    • 2024
  • InP quantum dots (QDs) have attracted researchers' interest due to their applicability in quantum dot light-emitting displays (QLED) or biomarkers for detecting cancers or viruses. The surface or interface control of InP QD core/ shell has substantially increased quantum efficiency, with a quantum yield of 100% reached by introducing HF to inhibit oxide generation. In this study, we focused on the control of bandgap energy of quantum dots by changing the Zn/(In+Zn) ratio in the In(Zn)P core. Zinc incorporation can change the photoluminescent light colors of green, yellow, orange, and red. Diluting a solution of as-synthesized QDs by more than 100 times did not show any quenching effects by the Förster resonance energy transfer phenomenon between neighboring QDs.

Aqueous synthesis of quantum dots using functionalized ionic liquid (이온성 액체를 이용한 수계 양자 점 합성)

  • Choi, Suk-Young;Kim, Tae-Young;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.254-254
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    • 2010
  • We report aqueous synthesis of cadmium telluride (CdTe) quantum dots(QDs) using imidazolium-based ionic liquids with various functional groups. The functinalized ionic liquids were designed to have thiol groups, and then phase transfer with aqueous or organic solvents can be adjusted by changing side chain lengths of the cation and the choice of anion. The quantum yield was obtained IL-functionalized CdTe QDs reached up to 40% by post-treatment method.

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White Light -Emitting Diodes with Multi-Shell Quantum Dots

  • Kim, Kyung-Nam;Han, Chang-Soo;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.92-92
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    • 2010
  • Replacing the existing illumination with solid-state lighting devices, such as light-emitting diodes (LEDs) are expected to reduce energy consumption and environmental pollution as they provide better efficiency and longer lifetimes. Currently, white light emitting diodes are composed of UV or blue LED with down-converting materials such as highly luminescent phosphors White light-emitting diodes (LED) were fabricated with multi-shell nanocrystal quantum dots for enhanced luminance and improved stability over time. Multi-shell quantum dots (QDs) were synthesized through one pot process by using the Successive Ionic Layer Adsorption and Reaction (SILAR) method. As prepared, the multi-shell QD has cubic lattice of zinc-blend structure with semi-spherical shape with quantum yield of higher than 60 % in solution. Further, highly fluorescent multi-shell QD was deposited on the blue LED, which resulted in QD-based white LED with high luminance with excellent color rendering properties.

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Detection of Al3+ by fluorescent turn-on nitrogen/sulphur-binary doped carbon dots

  • Siti Raudhatul Kamali;Chang-Nan Chen;Tai-Huei Wei
    • Analytical Science and Technology
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    • v.36 no.4
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    • pp.161-169
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    • 2023
  • In this study, a straightforward and precise nitrogen/sulphur-codoped carbon dots (N/S-CD) was produced using a microwave irradiation approach. The N/S-CD was formulated from succinic acid (SA), bis-(3-aminopropyl)-amine (BAPA), and sodium thiosulphate (STS) as sources of carbon, nitrogen, and sulphur, respectively. The synthesized N/S-CD established a valuable quantum yield (QY) of 70 % and was sensitive to aluminium ion (Al3+) with a detection limit of 0.21 µM and a linear concentration range of 0-100 µM. When detecting Al3+ in real water samples, the N/S-CD resulted in a satisfactory recovery in the range of 91.14 %-103.37 %. Thus, the proposed study is very promising for Al3+ detection in environmental water samples.

A Study on Electrical and Optical Characteristics of InAs/GaAs Self-organized Quantum Dots (InAs/GaAs Self-organized Quantum Dots의 전기.광학적 특성 연구)

  • 김기홍;박종도;배인호;손정식;문병연;이주인
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.99-103
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    • 2001
  • We present a detailed of the interband transitions of InAs/GaAs self-organized quantum dots(QDs) based on surface photovoltage(SPV), photoreflactance(PR) and photoluminescence(PL) spectroscopies. At room temperature, interband absorption transitions of QDs have been observed by using SPV spectrum, which clearly exhibits three well-resolved absorption transitions of QDs have been observed by using SPV spectrum, which clearly exhibits three well-resolved absorption peaks. The absorption line shape is Gaussian-like. Furthermore, the corresponding interband transitions are also observed in PR and PL experiments at 77K.

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The Synthesis of a High Yield PbSe Quantum Dots by Hot Solution Method

  • Baek, In-Chan;Seok, Sang-Il;Chung, Yong-Chae
    • Bulletin of the Korean Chemical Society
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    • v.29 no.9
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    • pp.1729-1731
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    • 2008
  • Colloidal solutions of crystalline PbSe nanoparticles have been synthesized by hot solution chemical process using PbO in oleic acid and tributylphosphine (TBP) bonded selenium. The use of TBP as a capping agent along with oleic acid gives a very good yield (around 10% at 180 ${^{\circ}C}$) with an average diameter of particle of about < 6.6 nm. The effects of temperature on size and production yield of PbSe quantum dots are studied. Xray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and UV/VIS/NIR absorption spectroscopy were used to characterize the samples.

Pt Coating on Flame-Generated Carbon Particles (화염법을 이용한 Pt/C 촉매 제조)

  • Choi, In-Dae;Lee, Dong-Geun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.2
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    • pp.116-123
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    • 2009
  • Carbon black, activated carbon and carbon nanotube have been used as supporting materials for precious metal catalysts used in fuel cell electrodes. One-step flame synthesis method is used to coat 2-5nm Pt dots on flame-generated carbon particles. By adjusting flame temperature, gas flow rates and resident time of particles in flame, we can obtain Pt/C nano catalyst-support composite particles. Additional injection of hydrogen gas facilitates pyrolysis of Pt precursor in flame. The size of as-incepted Pt dots increases along the flame due to longer resident time and sintering in high temperature flame. Surface coverage and dispersion of the Pt dots is varied at different sampling heights and confirmed by Transmission electron microscopy (TEM), Energy-dispersive spectra (EDS) and X-ray diffraction (XRD). Crystalinity and surface bonding groups of carbon are investigated through X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy.

Interband Transition and Confinement of Charge Carriers in CdS and CdS/CdSe Quantum Dots

  • Man, Minh Tan;Lee, Hong Seok
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.167-171
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    • 2015
  • Quantum-confined nanostructures open up additional perspectives in engineering materials with different electronic and optical properties. We have fabricated unique cation-exchanged CdS and CdS/CdSe quantum dots and measured their first four exciton transitions. We demonstrate that the relationship between electronic transitions and charge-carrier distributions is generalized for a broad range of core-shell nanostructures. These nanostructures can be used to further improve the performance in the fields of bio-imaging, light-emitting devices, photovoltaics, and quantum computing.

One-dimensional Array of Inks Quantum Dots on Grown V-grooves (V 홈 바닥에 형성된 일차원 InAs 양자점)

  • Son, Chang-Sik;Choi, In-Hoon;Park, Young-Ju
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.708-710
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    • 2003
  • One-dimensional array of InAs quantum dots (QDs) have been grown on V-grooved GaAs substrates by low-pressure metalorganic chemical vapor deposition. Atomic force microscope images show that InAs QDs are aligned in one-dimensional rows along the [011]oriented bottom of V-grooves and no QDs are formed on the sidewalls and the surface of mesa top. Capability to grow one-dimensional InAs QDs array would feasible for the single electron tunneling devices and other novel quantum-confined devices.