• Title/Summary/Keyword: ternary composite

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Phase Orientation of TiC-$TiB_2$-SiC Ternary Eutectic Composite Prepared by an FZ Method

  • Tu, Rong;Li, Wenjun;Goto, Takashi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.859-860
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    • 2006
  • TiC-$TiB_2$-SiC system was a ternary eutectic, whose eutectic composition was 34TiC-$22TiB_2$-44SiC (mol%). TiC-$TiB_2$-SiC ternary eutectic composite were synthesized by a floating zone method using TiC, $TiB_2$ and SiC powders as starting materials. The TiC-$TiB_2$-SiC eutectic composite showed a lamellar texture. TiC(022), $TiB_2(010)$ and SiC(111) of the eutectic composite were perpendicular to the growth direction. TiC-$TiB_2$-SiC ternary eutectic composite had specific relationship among the crystal planes: TiC[011]//$TiB_2[010]$//SiC[112], TiC(200)//$TiB_2$(001)//SiC(402) and $TiC(1\bar{1}1)$//$TiB_2(101)$//SiC(220).

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Flowing and Strength Properties of Ternary System Inorganic Composite According to the Change of W/B and Addition Ratio of Na2SiO3 (3성분계 무기결합재의 W/B 및 규산나트륨 첨가율 변화에 따른 유동 및 강도특성)

  • Bae, Sang-Woo;Moon, Ji-Hwan;Lee, Yun-Seong;Lee, Kang-Pil;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.49-50
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    • 2011
  • This study tried to utilize basic data for developing the cement substitute material through ternary system inorganic composite properties of flowing and strength. W/B and addition ratio of Na2SiO3 have been changed in ternary system inorganic composite combined blast furnace slag, red mud and fly ash. As to the experimental result inorganic composite, the flowing and intensity improvement effect was showed to be bigger than W/B according to the addition ratio change of the Na2SiO3. When particularly the Na2SiO3 addition ratio was 6%, the rapid flowing and strength improvement effect was confirmed.

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Molecular Composite of Cellulose Triacetate and Polyester (II) -Bulk Property- (셀룰로오즈 트리아세테이트와 폴리에스테르의 분자복합체 (II) -고체성질-)

  • Hong, Young Keun
    • Textile Coloration and Finishing
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    • v.4 no.1
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    • pp.26-29
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    • 1992
  • Ternary solutions that cellulose triacetate (CTA) and polyethylene terephthate (PET) were mixed in a solvent trifiuoroacetic acid (TFA)/methylene chloride (MC) (6/4 : v/v) showed phase separation and mesophase formation. The ternary systems which were mesomorphic were spun into a methanol both and relatively strong cellulosic fillaments were successfully produced. Analysis showed that CTA/PET fibers have fibrillar structure and high orientation parallel to the fiber axis. These fibers proved to be molecular composite and have relatively high strength and modulus as spun.

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Novel Synthesis of MnO2-SiC Fiber-TiO2 Ternary Composite and Effective Photocatalytic Degradation with Standard Dyes

  • Latiful Kabir;Yeon Woo Choi;Yun Seo Shin;Yeon Ji Shin;Geun Chan Kim;Jun Hyeok Choi;Jo Eun Kim;Young Jun Joo;Kwang Youn Cho;Hyuk Kim;Je-Woo Cha;Won-Chun Oh
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.275-282
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    • 2024
  • In this work, we investigated the photo-degradation performance of MnO2-SiC fiber-TiO2 (MnO2-SiC-TiO2) ternary nanocomposite according to visible light excitation utilizing methylene blue (MB) and methyl orange (MO) as standard dyes. The photocatalytic physicochemical characteristics of this ternary nanocomposite were described by X-ray diffraction (XRD), scanning electron microscopy (SEM), tunneling electron microscopy (TEM), ultraviolet-visible (UV-vis), diffuse reflectance spectroscopy (DRS), electrochemical impedance spectroscopy (EIS), photocurrent and cyclic voltammogram (CV) test. Photolysis studies of the synthesized MnO2-SiC-TiO2 composite were conducted using standard dyes of MB and MO under UV light irradiation. The experiments revealed that the MnO2-SiC-TiO2 exhibits the greatest photocatalytic dye degradation performance of around 20 % with MB, and of around 10 % with MO, respectively, within 120 min. Furthermore, MnO2-SiC-TiO2 showed good stability against photocatalytic degradation. The photocatalytic efficiency of the nanocomposite was indicated by the adequate photocatalytic reaction process. These research results show the practical application potential of SiC fibers and the performance of a photocatalyst composite that combines these fibers with metal oxides.

Flowing and Strength Properties of Ternary System Inorganic Composite Mortar according to the Change of Replacement Ratio of Recycled Sand (순환잔골재 치환율 변화에 따른 3성분계 무기결합재 모르타르의 유동 및 강도특성)

  • Bae, Sang-Woo;Park, Jong-Pil;Kim, Gyu-Yong;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.99-100
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    • 2012
  • This study tried to present the appropriate replacement ratio of the recycled sand through the properties of the ternary system inorganic composite mortar according to replacement ratio change of the recycled sand about the natural sand through test verification. The flowing and compressive strength was degraded as the replacement ratio of the experimental result recycled sand increased. The appropriate replacement ratio of the recycled sand according to it was shown up less than 15%.

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Facile Synthesis of Co3O4/Mildly Oxidized Multiwalled Carbon Nanotubes/Reduced Mildly Oxidized Graphene Oxide Ternary Composite as the Material for Supercapacitors

  • Lv, Mei-Yu;Liu, Kai-Yu;Li, Yan;Wei, Lai;Zhong, Jian-Jian;Su, Geng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1349-1355
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    • 2014
  • A three-dimensional (3D) $Co_3O_4$/mildly oxidized multiwalled carbon nanotubes (moCNTs)/reduced mildly oxidized graphene oxide (rmGO) ternary composite was prepared via a simple and green hydrolysishydrothermal approach by mixing $Co(Ac)_2{\cdot}4H_2O$ with moCNTs and mGO suspension in mixed ethanol/$H_2O$. As characterized by scanning electron microscopy and transmission electron microscopy, $Co_3O_4$ nanoparticles with size of 20-100 nm and moCNTs are effectively anchored in mGO. Cyclic voltammetry and galvanostatic charge-discharge measurements were adopted to investigate the electrochemical properties of $Co_3O_4$/moCNTs/rmGO ternary composite in 6 M KOH solution. In a potential window of 0-0.6 V vs. Hg/HgO, the composite delivers an initial specific capacitance of 492 $Fg^{-1}$ at 0.5 $Ag^{-1}$ and the capacitance remains 592 $Fg^{-1}$ after 2000 cycles, while the pure $Co_3O_4$ shows obviously capacitance fading, indicating that rmGO and moCNTs greatly enhance the electrochemical performance of $Co_3O_4$.

Research on New Nylon-6 Nanocomposites with Flame Retardancy

  • Qiao, Jinliang;Zhang, Xiaohong;Liu, Yiqun;Dong, Weifu;Wang, Qingguo;Gui, Hua;Gao, Jianming;Song, Zhihai;Lai, Jinmei;Huang, Fan
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.139-140
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    • 2006
  • Some of novel halogen-free, elastomeric flame retardants for nylon-6 have been developed. It is found that the S-ENP and clay have a synergistic flame retardant effect on nylon-6 resulted from the formation of two barriers on the nanocomposite residue surface at the end of combustion. A novel flame retardant ternary nanocomposite of nylon-6/ENP/nano-Magnesium hydroxide was also fabricated. The new ternary composite has better flame retardancy and thermal stability than the conventional one because nano-MH can disperse much more homogeneous in the new ternary composite than in the conventional one.

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Synergistic effect of clay and polypropylene short fibers in epoxy based ternary composite hybrids

  • Prabhu, T. Niranjana;Demappa, T.;Harish, V.;Prashantha, K.
    • Advances in materials Research
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    • v.4 no.2
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    • pp.97-111
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    • 2015
  • Polypropylene short fiber (PP)-clay particulate-epoxy ternary composites were prepared by reinforcing PP short fiber and clay particles in the range of 0.1 phr to 0.7 phr into epoxy resin. Prepared hybrid composites were characterized for their mechanical, thermal and flame retardant properties. The obtained results indicated an increase in impact resistance, tensile strength, flexural strength and Young's modulus to an extent (up to 0.5 phr clay and 0.5 phr PP short fiber) and then decreases as the reinforcing phases are further increased. The thermal stability of these materials are found to increase up to 0.2 phr clay and 0.2 phr PP addition, beyond which it is decreased. Addition of clay is found to have the negative effect on epoxy-PP short fiber composites, which is evident from the comparison of mechanical and thermal properties of epoxy-0.5 phr PP short fiber composite and epoxy-0.5 phr PP short fiber-0.5 phr clay composite hybrid. UL-94 tests conducted on the composite hybrids have showed a reduction in the burning rate. Morphological observations indicated a greater fiber pull with the addition of clay. The performed tests in the present study indicated that materials under investigation have promising applications in construction, agriculture and decorative purposes.

The influence of nano-silica on the wear and mechanical performance of vinyl-ester/glass fiber nanocomposites

  • Sokhandani, Navid;Setoodeh, AliReza;Zebarjad, Seyed Mojtaba;Nikbin, Kamran;Wheatley, Greg
    • Advances in nano research
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    • v.13 no.1
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    • pp.97-111
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    • 2022
  • In the present article, silica nanoparticles (SNPs) were exploited to improve the tribological and mechanical properties of vinyl ester/glass fiber composites. To the best of our knowledge, there hasn't been any prior study on the wear properties of glass fiber reinforced vinyl ester SiO2 nanocomposites. The wear resistance is a critical concern in many industries which needs to be managed effectively to reduce high costs. To examine the influence of SNPs on the mechanical properties, seven different weight percentages of vinyl ester/nano-silica composites were initially fabricated. Afterward, based on the tensile testing results of the silica nanocomposites, four wt% of SNPs were selected to fabricate a ternary composite composed of vinyl ester/glass fiber/nano-silica using vacuum-assisted resin transfer molding. At the next stage, the tensile, three-point flexural, Charpy impact, and pin-on-disk wear tests were performed on the ternary composites. The fractured surfaces were analyzed by scanning electron microscopy (SEM) images after conducting previous tests. The most important and interesting result of this study was the development of a nanocomposite that exhibited a 52.2% decrease in the mean coefficient of friction (COF) by augmenting the SNPs, which is beneficial for the fabrication/repair of composite/steel energy pipelines as well as hydraulic and pneumatic pipe systems conveying abrasive materials. Moreover, the weight loss due to wearing the ternary composite containing one wt% of SNPs was significantly reduced by 70%. Such enhanced property of the fabricated nanocomposite may also be an important design factor for marine structures, bridges, and transportation of wind turbine blades.

Preparation and capacitance properties of graphene based composite electrodes containing various inorganic metal oxides

  • Kim, Jeonghyun;Byun, Sang Chul;Chung, Sungwook;Kim, Seok
    • Carbon letters
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    • v.25
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    • pp.14-24
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    • 2018
  • Electrochemical properties and performance of composites performed by incorporating metal oxide or metal hydroxide on carbon materials based on graphene and carbon nanotube (CNT) were analyzed. From the surface analysis by field emission scanning electron microscopy and field emission transmission electron microscopy, it was confirmed that graphene, CNT and metal materials are well dispersed in the ternary composites. In addition, structural and elemental analyses of the composite were conducted. The electrochemical characteristics of the ternary composites were analyzed by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy in 6 M KOH, or $1M\;Na_2SO_4$ electrolyte solution. The highest specific capacitance was $1622F\;g^{-1}$ obtained for NiCo-containing graphene with NiCo ratio of 2 to 1 (GNiCo 2:1) and the GNS/single-walled carbon $nanotubes/Ni(OH)_2$ (20 wt%) composite had the maximum specific capacitance of $1149F\;g^{-1}$. The specific capacitance and rate-capability of the $CNT/MnO_2/reduced$ graphene oxide (RGO) composites were improved as compared to the $MnO_2/RGO$ composites without CNTs. The $MnO_2/RGO$ composite containing 20 wt% CNT with reference to RGO exhibited the best specific capacitance of $208.9F\;g^{-1}$ at a current density of $0.5A\;g^{-1}$ and 77.2% capacitance retention at a current density of $10A\;g^{-1}$.