• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.9
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• pp.769-774
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• 2016

Epoxy polymer exposed to solar radiation on long-term is required to a long-term environmental test in order to ensure the reliability of operation performance. In this paper, the solar aging experiment is performed for 7, 14, 28, 56, and 84 cycles, using solar simulator designed according to MIL-STD-810. After the aging experiment, measuring RGB values and using the CIE1976 color space, each RGB decreasing rates and total color shift are calculated. In addition, using a universal testing machine, mechnical properties according to ASTM-D638 are measured. As a result, by increasing solar aging period, total color shift is increased, and the tensile strength and elongation are decreased, but the elastic modulus and the poisson's ratio are slightly changed.

• Polymer(Korea)
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• v.31 no.2
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• pp.130-135
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• 2007

To enhance the thermo-mechanical properties of polyimide films which have potential application for the FCCL, we have synthesized the poly (amic acid) s composed of 4-components PMDA/BTDA and PDA/ODA as monomer system, u4 then they were effectively converted into 4-component polyimide films by thermal imidization process. It has been found that CTE values in the range of $100\sim200^{\circ}C$ decreased with the amount of PDA, which also caused 36% and 59% increases in tensile modulus and strength respectively. And also, peel test results on 3-layered copper clad laminate using 4-component polyimide films showed excellent adhesion strength above 1.8 kgf/cm. On the basis of obtained results it can be concluded that 4-component polyimide films may be applied for the high performance FCCL base films.

• Polymer(Korea)
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• v.32 no.6
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• pp.580-586
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• 2008

Copolyimides were synthesized from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 1,3-bis(3-aminophenoxy)benzene (BAPB) with different mole ratios of 2,2-bis[4-(4-aminophenoxy)pheny1]hexafluoropropane (BAPP). The solution cast film of poly(amic acid) (PAA) was heat treated at different temperatures to create copolyimide films. The PI copolymer films were found to exhibit good optical transparencies. The thermomechanical properties, morphology, and optical transparency of PI films were examined using fourier transform infrared spectroscopy (FT-IR), wide-angle X-ray diffraction (XRD), scanning electron microscopes (SEM), differential scanning calorimeter(DSC), thermo-gravimetric analyzer (TGA), universal tensile machine (UTM), and IN - Vis. spectrometer. The glass transition temperature ($T_g$), ultimate strength, and initial modulus linearly increased with increasing BAPP mole fraction. However, thermal stability($T_D{^i}$) of the copolyimide remains constant regardless of BAPP loadings. It was found, however, that the optical transparency decreases slightly upon increasing the BAPP content because of the formation of the charge transfer complexes.

• Polymer(Korea)
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• v.32 no.6
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• pp.598-602
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• 2008

In this study we prepared crosslinked separators with the improved thermal stability by irradiating a commercial polyethylene (PE) separator for lithium secondary battery with an electron beam, and the thermal and mechanical properties of the prepared separators were evaluated as a function of the absorption dose. The thermal shrinkage of electron beam irradiated separator was decreased with increasing absorption dose. As a result of the shutdown behavior using an AC impedance, it was observed that the irradiated separator had the better shutdown function than the unirradiated separator. The modulus of the irradiated separator was enhanced as the absorption dose was increased, while the tensile strength and the break elongation of the irradiated separator were decreased.

• Polymer(Korea)
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• v.37 no.6
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• pp.764-769
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• 2013

Starch was grafted by poly(methyl methacrylate) through the emulsion polymerization method. Modified starch/(acrylonitrile-butadiene rubber) (NBR) compounds were prepared by a latex blend method. The morphology, thermal properties and mechanical properties of the modified starch/carbon black/NBR composites were investigated with the change of starch concentration. The mechanical properties of the composites were improved by the addition of modified starch. But, when the concentration of modified starch was higher than 40 phr, the mechanical properties were deteriorated due to the poor dispersion of modified starch. At the same ratio of starch to carbon black, the composite showed a synergistic reinforcing effect by the good dispersion and high cross-linking density. In addition, the tensile strength, storage modulus, hardness, swelling and other properties were the best.

• Tunnel and Underground Space
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• v.22 no.4
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• pp.284-295
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• 2012

Abrasiveness of rock plays an important role on the wear of rock cutting tools. In this study, Cerchar abrasiveness tests were carried out to assess the abrasiveness of 19 different Korean rocks. Cerchar abrasiveness test is widely used to assess the abrasiveness of rock because of its simplicity and inexpensive cost. This study examines the relationship between Cerchar Abrasiveness Index (CAI) and mechanical properties (uniaxial compressive strength, Brazilian tensile strength, Young's modulus, Poisson's ratio, porosity, shore hardness of rock), and the effect of quartz content, equivalent quartz content, which was obtained from XRD analysis. As a result of test, CAI was more influenced by petrographical properties than by the bonding strength of the matrix material of rock. CAI prediction model which consisted of UCS and EQC was proposed. CAI decreased linearly with the hardness of the steel pin. Numerical analysis was performed using Autodyn-3D for simulating the Cerchar abrasiveness test. In the simulations, most of pin wear occurred during the initial scratching distance, and CAI increased with the increase of normal loading.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.202-209
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• 2019

The objective of this study is to examine the reproducibility for compressive strength development and mechanical properties of lightweight concrete made using bottom ash aggregates and foam(LWC-BF). Based on the mix proportions conducted by Ji et al., six identical mixes were prepared with different actual foam volume ratios from 0% to 25% and water-to-binder ratios from 25% to 30%. The presently measured properties, including initial slump, slurry density, compressive strength gains at different ages, splitting tensile strength, and modulus of rupture, were very close to those determined in the previous tests by Ji et al. Thus, the developed LWC-BF has a good potential in obtaining a reproducibility for compressive strength development and mechanical properties even though the troubles of mixing control owing to the addition of preformed foam.

• Corrosion Science and Technology
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• v.20 no.1
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• pp.26-36
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• 2021

Pipes operating in the seawater environment faces cavitation degradation and corrosion of the metallic component, as well as a negative synergistic effect. Cavitation degradation shows the mechanism by which materials deteriorate by causing rapid change of pressure or high-frequency vibration in the solution, and introducing the formation and explosion of bubbles. In order to rate the cavitation resistance of materials, constant conditions have been used. However, while a dynamic cavitation condition can be generated in a real system, there has been little reported on the effect of ultrasonic amplitude on the cavitation resistance and mechanism of composites. In this work, 3 kinds of epoxy coatings were used, and the cavitation resistance of the epoxy coatings was evaluated in 3.5% NaCl at 15 ℃ using an indirect ultrasonic cavitation method. Eleven kinds of mechanical properties were obtained, namely compressive strength, flexural strength and modulus, tensile strength and elongation, Shore D hardness, water absorptivity, impact test, wear test for coating only and pull-off strength for epoxy coating/carbon steel or epoxy coating/rubber/carbon steel. The cavitation erosion mechanism of epoxy coatings was discussed on the basis of the mechanical properties and the effect of ultrasonic amplitude on the degradation of coatings.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.1
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• pp.17-23
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• 2021

The membrane-type Liquefied Natural Gas (LNG) cargo tank is equipped with a double barrier to seal the LNG, of which the secondary barrier serves to prevent LNG leakage and mainly uses fiber-reinforced composite materials. However, the composite materials have thermal expansion anisotropy, which deteriorates shape distortion and mechanical performance due to repeated thermal loads caused by temperature changes between cryogenic and ambient during the unloading of LNG. Therefore, in this study, the longitudinal thermal expansion characteristics of the composite materials were obtained using a vertical thermo-mechanical analyzer, and the elastic modulus was obtained through the tensile test for each temperature to perform thermal load analysis for each direction. This is considered that it is useful to secure reliability from the viewpoint of the design of materials for a LNG cargo hold.

• Advances in concrete construction
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• v.11 no.4
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• pp.335-345
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• 2021

It is known from the literature that there are relatively few studies on the engineering properties of ultra-high performance concrete (UHPC) in early age. In fact, in order to ensure the safety of UHPC during construction and sufficient durability and long-term performance, it is necessary to explore the early behavior of UHPC. The test parameters (test control factors) investigated included the percentage of cement replaced by silica fume (SF), the percentage of cement replaced by ultra-fine silica powder (SFP), the amount of steel fiber (volume percent), and the amount of polypropylene fiber (volume percentage). The engineering properties of UHPC in the fresh mixing stage and at the age of 7 days were investigated. These properties include freshly mixed properties (slump, slump flow, and unit weight) and hardened mechanical properties (compressive strength, elastic modulus, flexural strength, and splitting tensile strength). Moreover, the effects of the experimental factors on the performance of the tested UHPC were evaluated by range analysis and variance analysis. The experiment results showed that the compressive strength of the C8 mix at the age of 7 days was highest of 111.5 MPa, and the compressive strength of the C1 mix at the age of 28 days was the highest of 128.1 MPa. In addition, the 28-day compressive strength in each experimental group increased by 13%-34% compared to the 7-day compressive strength. In terms of hardened mechanical properties, the performance of each experimental group was superior to that of the control group (without fiber and without additional binder materials), with considerable improvement, and the experimental group did not produce explosive or brittle damage after the test. Further, the flexural test process found that all test specimens exhibited deflection-hardening behavior, resulting in continued to increase carrying capacity after the first crack.