• Title/Summary/Keyword: tensile modulus

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Effects of UV Initiator on Properties of Polymer-Modified Asphalt (자외선 경화제가 고분자개질아스팔트의 물성에 미치는 영향에 관한 연구)

  • Kang, Hyun-Seung;Hong, Young-Keun
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.217-222
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    • 2010
  • Paved roads are suffered from the permanent plastic deformation in hot summer and cracks in cold winter, which are detrimental to safe driving. This leads to necessity of modification of asphalt to resist those deformation. In this study, two kinds of modifiers were examined; organic polymers and a photoinitiator which is activated by ultraviolet lay. The mechanical and rheololgical properties of modified asphalts were examined using UTM and rheometer. Results showed that the properties were varied depending on the types of polymer and irradiation time. UV irradiation increased the tensile strength and storage modulus of thermoplastic polymer-modified asphalt, however UV was not effective on thermoset polymer. According to long term ultraviolet curing test, properties of the polymer/photoinitiator-modified asphalt did not decrease, but rather increase for 20 years. This indicates that the useful life of the asphalt could be extended by addition of photoinitiator.

Thiazole Type Accelerator Effects on Silane/Silica Filled Natural Rubber Compound upon Vulcanization and Mechanical Properties (Thiazole계 가황촉진제가 실란/실리카 충전 천연고무 컴파운드의 가황 거동 및 기계적 물성에 미치는 영향)

  • Kim, Sung-Min;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.235-244
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    • 2012
  • A thiazole type accelerator MBT (2-mercapto benzothiazole) was added into silica filled natural rubber (NR) compound with various concentrations (0, 1, 2, 3, 4 phr). The effects of MBT on the cure rate, mechanical property, degree of rubber-filler interaction (${\alpha}_F$), crosslinking density, and viscoelastic property ($tan{\delta}$) were investigated. As accelerator concentration increased, the $t_{s2}$ and $t_{90}$ decreased and the crosslinking density and modulus at 300% elongation increased. The tensile strength and elongation increased up to 3 phr and no further increased at 4 phr. The $tan{\delta}$ value measured at room temperature was higher than that of the $70^{\circ}C$. The ${\alpha}_F$ value was not affected by the addition of MBT. The mechanisms for the vulcanization rate were reviewed.

Characterizations of Polypropylene/Functionalized Multiwalled Carbon Nanotube Films (폴리프로필렌/기능화된 다중벽 탄소나노튜브 나노복합체 필름의 특성 연구)

  • Ko, Jeong-Ho;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.333-341
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    • 2009
  • Polypropylene (PP)/functionalized multiwalled carbon nanotube (F-MWNT) nanocomposites were prepared by using solution intercalation method with different F-MWNT loads. The PP composite films, which contain dodecanol-MWNT (DDO-MWNT) or dodecylamine-MWNT (DDA-MWNT) as reinforcing additive, were evaluated by thermomechanical properties, morphology, electrical conductivity and gas permeability. The images from electron microscopy (SEM and TEM) showed that F-MWNTs were homogeneously dispersed in PP matrix, while they were agglomerated in some other part. The addition of F-MWNT could improve thermomechanical properties of the films. The maximum enhancement was observed at 2 wt% F-MWNT. DDO-MWNT was more effective than DDA-MWNT for both tensile modulus and optical transparency of the films.

Properties of SBR Nanocomposites Reinforced with Organoclay/Carbon Black Dual Phase Fillers (카본 블랙/유기화 클레이로 보강된 SBR 나노 복합재료: 모폴로지와 기계적 물성)

  • Kang, B.S.;Kim, W.
    • Elastomers and Composites
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    • v.42 no.1
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    • pp.9-19
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    • 2007
  • In this study, SBR (Styrene-butadiene rubber: solid content: 25 wt%) nanocomposites reinforced with carbon/organoclay(C18-MMT) were manufactured by a latex method. The SBR nanocomposites was made with the dual phase fillers. The mixing ratios, i.e. carbon black/C18-MMT, were 50/0, 49/1, 48/2, 47/3, 45/5, 44/6, 40/10. Total filler content of compounds was restricted to 50 phr. Cure characteristics and mechanical properties of SBR nanocomposites with carbon black and C18-MMT were evaluated. The SBR nanocomposites containing 49/1 ratio of carbon black/C18-MMT showed good dispersity and excellent values of ODR torque, tensile strength, modulus and tear energy. It was found that the improvement of the mechanical properties was mainly due to the reinforcing effect, i.e., the improvement of dispersion of silicates in the rubber matrix.

Influence of Hydrophobic Silica on Physical Properties of Epoxy Nanocomposites for Epoxy Molding Compounds (에폭시 몰딩 컴파운드를 위한 에폭시 나노복합재료의 소수성 실리카의 영향)

  • Kim, Ki-Seok;Oh, Sang-Yeob;Kim, Eun-Sung;Shin, Hun-Choong;Park, Soo-Jin
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.12-16
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    • 2010
  • In this work, the effect of hydrophobic treated silica on the water absorption, thermal stabilities, and mechanical properties of the epoxy nanocomposites were investigated as a function of the silica content. As filler, fumed silica treated by dimethyldichlorosilane was used. It was found that the silica was well dispersed in the epoxy resins by the melt-mixing method with the addition of a silane coupling agent. The water absorption of the nanocomposites decreased with an increase of the silica content due to the effect of hydrophobic treated silica. The thermal properties, such as thermal degradation temperature, glass transition temperature ($T_g$), and coefficient of thermal expansion (CTE), of the nanocomposites were improved by the addition of silica. Furthermore, the mechanical properties of the nanocomposites, that is, the tensile strength and modulus, were enhanced with increasing silica content. This was attributed to the physically strong interaction between silica and epoxy resins.

Quality Evaluation of Tangmyon Prepared from Sweet Potato and/or Corn Starches (원료 전분이 다른 당면의 품질 평가)

  • Ko, Chang-Heon;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.24 no.2
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    • pp.160-164
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    • 1992
  • Cooking, texture and sensory properties of sweet potato Tangmyon (starch noodle), common Tangmyon (50% sweet potato starch+50% corn starch) and corn Tangmyon were evaluated. The weight gain of Tangmyon showed a linear relationship with the square root of cooking time, in which the common Tangmyon showed the highest value. The solid loss during cooking was the highest in common Tangmyon followed by corn Tangmyon. The sweet potato Tangmyon showed the highest value for compression strength and stretching ratio, but lowest value for elongation elastic modulus. At the same compression strength, corn Tangmyon had the highest tensile strength and sweet potato Tangmyon the lowest value. Sweet potato Tangmyon showed the highest sensory scores of gloss, clarity, adhesiveness, gumminess, extensibility and overall desirability, and corn Tangmyon the lowest scores. Except adhesiveness (by appearance) and the gumminess of common and corn Tangmyon, significant differences (p<0.05) were observed for other sensory properties among samples.

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A Study on the Optimum Mix Proportion of the Mass Concrete Designed as Massive and Deep Structure

  • Kwon Yeong-Ho;Lee Hwa-Jin
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.293-302
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    • 2005
  • This study describes data from determination of the optimum mix proportion and site application of the mass concrete placed in bottom slab and side wall having a large depth and section as main structures of LNG in-ground tank. This concrete requires low heat hydration, excellent balance between workability and consistency because concreting work of LNG in-ground tank is usually classified by under-pumping, adaptation of longer vertical and horizontal pumping line than ordinary pumping condition. For this purpose, low heat Portland cement and lime stone powder as cementitious materials are selected and design factors including unit cement and water content, water-binder ratio, fine aggregate ratio and adiabatic temperature rising are tested in the laboratory and batch plant. As experimental results, the optimum unit cement and water content are selected under $270kg/m^3$ and $l55{\~}l60 kg/m^3$ separately to control adiabatic temperature rising below $30^{\circ}C$ and to improve properties of the fresh and hardened concrete. Also, considering test results of the confined water ratio($\beta$p) and deformable coefficient(Ep), $30\%$ of lime stone powder by cement weight is selected as the optimum replacement ratio. After mix proportions of 5cases are tested and compared the adiabatic temperature rising($Q^{\infty}$, r), tensile and compressive strength, modulus of elasticity, teases satisfied with the required performances are chosen as the optimum mix design proportions of the side wall and bottom slab concrete. $Q^{\infty}$ and r are proved smaller than those of another project. Before application in the site, properties of the fresh concrete and actual mixing time by its ampere load are checked in the batch plant. Based on the results of this study, the optimum mix proportions of the massive concrete are applied successfully to the bottom slab and side wall in LNG in-ground tank.

Mechanical performances of concrete beams with hybrid usage of steel and FRP tension reinforcement

  • Bui, Linh V.H.;Stitmannaithum, Boonchai;Ueda, Tamon
    • Computers and Concrete
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    • v.20 no.4
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    • pp.391-407
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    • 2017
  • Fiber reinforced polymer (FRP) bars have been recently used to reinforce concrete members in flexure due to their high tensile strength and especially in corrosive environments to improve the durability of concrete structures. However, FRPs have a low modulus of elasticity and a linear elastic behavior up to rupture, thus reinforced concrete (RC) components with such materials would exhibit a less ductility in comparison with steel reinforcement at the similar members. There were several studies showed the behavior of concrete beams with the hybrid combination of steel and FRP longitudinal reinforcement by adopting the experimental and numerical programs. The current study presents a numerical and analytical investigation based on the data of previous researches. Three-dimensional (3D) finite element (FE) models of beams by using ANSYS are built and investigated. In addition, this study also discusses on the design methods for hybrid FRP-steel beams in terms of ultimate moment capacity, load-deflection response, crack width, and ductility. The effects of the reinforcement ratio, concrete compressive strength, arrangement of reinforcement, and the length of FRP bars on the mechanical performance of hybrid beams are considered as a parametric study by means of FE method. The results obtained from this study are compared and verified with the experimental and numerical data of the literature. This study provides insight into the mechanical performances of hybrid FRP-steel RC beams, builds the reliable FE models which can be used to predict the structural behavior of hybrid RC beams, offers a rational design method together with an useful database to evaluate the ductility for concrete beams with the combination of FRP and steel reinforcement, and motivates the further development in the future research by applying parametric study.

Effect of Solar Radiation Aging on the Properties of Epoxy Polymers (에폭시 폴리머의 물성에 미치는 태양광 복사 노화의 영향)

  • Lee, Dong-Geon;Lee, Sang-Bong;Kim, Myung-June;Park, Jung-Sun;Lee, Soo-Yong;Kang, Tae-Yeob
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.9
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    • pp.769-774
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    • 2016
  • Epoxy polymer exposed to solar radiation on long-term is required to a long-term environmental test in order to ensure the reliability of operation performance. In this paper, the solar aging experiment is performed for 7, 14, 28, 56, and 84 cycles, using solar simulator designed according to MIL-STD-810. After the aging experiment, measuring RGB values and using the CIE1976 color space, each RGB decreasing rates and total color shift are calculated. In addition, using a universal testing machine, mechnical properties according to ASTM-D638 are measured. As a result, by increasing solar aging period, total color shift is increased, and the tensile strength and elongation are decreased, but the elastic modulus and the poisson's ratio are slightly changed.

Preparation and Thermo-Mechanical Properties of 4-Component Polyimide Films (4성분계 폴리이미드 필름 제조 및 열적-기계적 특성)

  • Seo, Kwan-Sik;Sul, Kyung-Il;Kim, Yong-Seok;Suh, Dong-Hack;Choi, Kil-Young;Won, Jong-Chan
    • Polymer(Korea)
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    • v.31 no.2
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    • pp.130-135
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    • 2007
  • To enhance the thermo-mechanical properties of polyimide films which have potential application for the FCCL, we have synthesized the poly (amic acid) s composed of 4-components PMDA/BTDA and PDA/ODA as monomer system, u4 then they were effectively converted into 4-component polyimide films by thermal imidization process. It has been found that CTE values in the range of $100\sim200^{\circ}C$ decreased with the amount of PDA, which also caused 36% and 59% increases in tensile modulus and strength respectively. And also, peel test results on 3-layered copper clad laminate using 4-component polyimide films showed excellent adhesion strength above 1.8 kgf/cm. On the basis of obtained results it can be concluded that 4-component polyimide films may be applied for the high performance FCCL base films.