• Title/Summary/Keyword: temperature sensitive material

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A research of thermoplastic elastomer PP(Poly Propylene)/SEBS(Styrene Ethylene Butylene Styrene) blends (열가소성 탄성중합체인 PP/SEBS 혼합 연구)

  • Han, Hyun Kak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.562-570
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    • 2018
  • New physical properties of polymer materials were obtained by blending two or three different type of polymers. TPE is used widely in the display, automotive and electronics industries. Consumers have sought emotionally more sensitive and advanced interior automotive parts. A polymer with high foamibility (Ed note: Please check this.) and flowability would be more plausible. TPE composed of foam is a good polymer material to satisfy these trends. In this research, two different TPE were tested, focusing on foamibility and flowability. Two type of TPE were prepared. The first was blended Homo-PP, oil and SEBS. The second was Co-PP, oil and SEBS. The blending temperatures were $180^{\circ}C$, $190^{\circ}C$, and $260^{\circ}C$(second one). The blending speed was 50rpm and blending time was 5 min. The MI of the blended material was affected by the MI of PP and not affected by the blending temperature. The hardness and tensile elasticity were less affected by the MI of PP and blending temperature. The hardness and tensile elasticity were lower at a higher SEBS/Oil content ratio. The soft touch feel was higher with high SEBS/Oil contents. The IPN (Interpenentration polymer network) structure was observed by dissolving the SEBS/Oil layer in xylene. Strain-hardening phenomena also was observed. TPE behaves in a rubber and foamed closed-cell improved its stability.

Comparison of Growth and Herbicidal Response Characteristics between Water Foxtail(Alopecurus aequalis var. amuriensis) and Blackgrass(Alopecurus myosuroides) for Herbicide Screening (제초제 스크리닝을 위한 뚝새풀과 서양뚝새풀간의 생육력 및 제초반응 비교연구)

  • Kim, J.S.;Kim, T.J.;Shin, W.K.;Kim, K.J.;Cho, K.Y.
    • Korean Journal of Weed Science
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    • v.15 no.3
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    • pp.188-196
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    • 1995
  • Blackgrass and water foxtail are troublesome weeds in a cultivation area of cereals. To know whether water foxtail could substitute for blackgrass as a plant material of screening for the discovery and development of new cereal herbicides, they were compared in a greenhouse and a growth chamber with respect to initial growth characteristics and responses to various herbicides. Blackgrass had a higher germination rate at lower temperature and a higher growth rate at higher temperature as compared to water foxtail. In addition, blackgrass was less sensitive to long day than water foxtail. These results suggest that blackgrass grows better in a cultivation area in spring than water foxtail. As compared to water foxtail, blackgrass showed shightly susceptible responses to herbicides when they were applied to soil surface at one day after seeding. However, the responses to the herbicides of blackgrass and water foxtail were similar with a foliar application of the herbicides at 3 or 4 leaf stage of the plant. Since there were no considerable differences in the herbicidal responses of the two plant species, water foxtail could substitute for blackgrass as a plant material for a primary herbicide screening. When water foxtail was used in a post-emergence screening test, seeding amount of 0.1g/$350cm^2$ and postemergence application of herbicides at 3 to 5 leaf stage were found to be appropriate on the view of alleviating screening efforts in a greenhouse.

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A Study on the Thermo-Mechanical Stress of MEMS Device Packages (마이크로 머신(MEMS) 소자 패키지의 열응력에 대한 연구)

  • Jeon, U-Seok;Baek, Gyeong-Uk
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.744-750
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    • 1998
  • Unlike common device, MEMS(micro-electro-mechanical system) device consists of very small mechanical structures which determine the performance of the device. Because of its small mechanical structure inside. MEMS device is very sensitive to thermal stress caused by CTE(coefficient of thermal expansion) mismatch between its components. Therefore, its characteristics are affected by material properties. process temperature. and dimensions of each layer such as chip, adhesive and substrate. In this study. we investigated the change of the thermal stress in the chip attached to a substrate. With computer-aided finite element method (FEM), the computer simulation of the thermal stress was conducted on variables such as bonding material, process temperature, bonding layer thickness and die size. The commercial simulation program, ABAQUS ver5.6, was used. Subsequently 3-layer test samples were fabricated, and their degree of bending were measured by 3-D coordinate measuring machine. The experimental results were in good agreement with the simulation results. This study shows that the bonding layer could be the source of stress or act as the buffer layer for stress according to its elastic modulus and CTE. Solder adhesive layer was the source of stress due to its high elastic modulus, therefore high compressive stress was developed in the chip. And the maximum tensile stress was developed in the adhesive layer. On the other hand, polymer adhesive layer with low elastic modulus acted as buffer layer, and resulted in lower compressive stress. The maximum tensile stress was developed in the substrate.

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A Study on the Measurement of Ultrasound Velocity to Evaluate Degradation of Low Voltage Cables for Nuclear Power Plants (원전 저압케이블 열화도 평가를 위한 초음파 음속계측에 관한 연구)

  • Kim, Kyung-Cho;Kang, Suk-Chull;Goo, Charles;Kim, Jin-Ho;Park, Jae-Seok;Joo, Geum-Jong;Park, Chi-Seung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.4
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    • pp.325-330
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    • 2004
  • Several kinds of low voltage cables have been used in nuclear power plants for the supply of electric power, supervision, and the propagation of control signals. These low voltage tables must be inspected for safe and stable operation of nuclear power plants. In particular, the degradation diagnosis to estimate the integrity of low voltage rabies has recently been emphasized according to the long use of nuclear power plants. In order to evaluate their degradation, the surrounding temperature, hardness of insulation material, elongation at breaking point (EAB), etc. have been used. However, the measurement of temperature or hardness is not useful because of the absence of quantitative criteria; the inspection of a sample requires turning off of the power plant power; and, the electrical inspection method is not sufficiently sensitive from the initial through the middle stage of degradation. In this research, based on the theory that the ultrasonic velocity changes with relation to the degradation of the material, we measured the ultrasonic velocity as low voltage cables were degraded. To this end, an ultrasonic degradation diagnosis device was developed and used to measure the ultrasonic velocity with the clothing on the cable, and it was confirmed that the ultrasonic velocity changes according to the degradation of low voltage cables. The low voltage cables used in nuclear power plants were degraded at an accelerated rate, and EAB was measured in a tensile test conducted after the measurement of ultrasonic velocity. With the increasing degradation degree, the ultrasonic velocity decreased, whose potential as a useful parameter for the quantitative degradation evaluation was thus confirmed.

The Influence of Insulation Wraps on the Temperature Change of Kiwifruit Trunk Surface During Winter (월동 피복재 종류에 따른 참다래 주간부 표면 온도변화)

  • Kwack, Yong-Bum;Kim, Hong Lim;Kim, Seong-Cheol;Kim, Mok-Jong;Lee, Yong-Bok
    • Korean Journal of Environmental Agriculture
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    • v.33 no.4
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    • pp.403-408
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    • 2014
  • BACKGROUND: Kiwifruit is a warm-temperate, deciduous fruit tree. It is sensitive to frost or freeze damage during winter. Therefore, the farmers cover kiwifruit trunk with rice straw to preclude freeze injury. This study was conducted to evaluate trunk wraps for protection of freeze injury of kiwifruit (Actinidia deliciosa) vines. METHODS AND RESULTS: The experimental orchard was located in Sacheon (lat. $34^{\circ}56'N$, long. $128^{\circ}03'E$) of Gyeongsangnam-do, South Korea. The vines were 5-6-year-old 'Hayward'. Two wrap materials, rice straw and silver-cushioned mat (reflective foil-coated, plastic-foamed mat, Ganan Industry, Rep. of Korea) were evaluated for their heat-retaining ability. The trunks of kiwifruit vines were wrapped in late December, and the wraps were removed in mid-April the following year (2012/13 and 2013/14). Temperature inner wraps were recorded from January to March in 2013 and 2014 by WatchDog 2450 (Spectrum Technologies, Inc., USA). In 2013, the lowest ambient temperature of January and February was $-10.2^{\circ}C$, $-10.9^{\circ}C$, respectively. The lowest temperature of inner-wrap of silver -cushioned mat was $-6.3^{\circ}C$, $-2.6^{\circ}C$ in January and February, respectively. However, rice straw showed $-9.8^{\circ}C$ and $-9.9^{\circ}C$ in its lowest value of January and February. And also silver cushioned mat appeared to be superior to rice straw in its ability of heat-retaining during night time.

Physicochemical Characteristics of Fe3O4 Magnetic Nanocomposites Based on Poly(N-isopropylacrylamide) for Anti-cancer Drug Delivery

  • Davaran, Soodabeh;Alimirzalu, Samira;Nejati-Koshki, Kazem;Nasrabadi, Hamid Tayefi;Akbarzadeh, Abolfazl;Khandaghi, Amir Ahmad;Abbasian, Mojtaba;Alimohammadi, Somayeh
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.1
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    • pp.49-54
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    • 2014
  • Background: Hydrogels are a class of polymers that can absorb water or biological fluids and swell to several times their dry volume, dependent on changes in the external environment. In recent years, hydrogels and hydrogel nanocomposites have found a variety of biomedical applications, including drug delivery and cancer treatment. The incorporation of nanoparticulates into a hydrogel matrix can result in unique material characteristics such as enhanced mechanical properties, swelling response, and capability of remote controlled actuation. Materials and Methods: In this work, synthesis of hydrogel nanocomposites containing magnetic nanoparticles are studied. At first, magnetic nanoparticles ($Fe_3O_4$) with an average size 10 nm were prepared. At second approach, thermo and pH-sensitive poly (N-isopropylacrylamide -co-methacrylic acid-co-vinyl pyrrolidone) (NIPAAm-MAA-VP) were prepared. Swelling behavior of co-polymer was studied in buffer solutions with different pH values (pH=5.8, pH=7.4) at $37^{\circ}C$. Magnetic iron oxide nanoparticles ($Fe_3O_4$) and doxorubicin were incorporated into copolymer and drug loading was studied. The release of drug, carried out at different pH and temperatures. Finally, chemical composition, magnetic properties and morphology of doxorubicin-loaded magnetic hydrogel nanocomposites were analyzed by FT- IR, vibrating sample magnetometry (VSM), scanning electron microscopy (SEM). Results: The results indicated that drug loading efficiency was increased by increasing the drug ratio to polymer. Doxorubicin was released more at $40^{\circ}C$ and in acidic pH compared to that $37^{\circ}C$ and basic pH. Conclusions: This study suggested that the poly (NIPAAm-MAA-VP) magnetic hydrogel nanocomposite could be an effective carrier for targeting drug delivery systems of anti-cancer drugs due to its temperature sensitive properties.

Effect of Temperature on Growth of Tin Oxide Nanostructures (산화주석 나노구조물의 성장에서 기판 온도의 효과)

  • Kim, Mee-Ree;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.497-502
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    • 2019
  • Metal oxide nanostructures are promising materials for advanced applications, such as high sensitive gas sensors, and high capacitance lithium-ion batteries. In this study, tin oxide (SnO) nanostructures were grown on a Si wafer substrate using a two-zone horizontal furnace system for a various substrate temperatures. The raw material of tin dioxide ($SnO_2$) powder was vaporized at $1070^{\circ}C$ in an alumina crucible. High purity Ar gas, as a carrier gas, was flown with a flow rate of 1000 standard cubic centimeters per minute. The SnO nanostructures were grown on a Si substrate at $350{\sim}450^{\circ}C$ under 545 Pa for 30 minutes. The surface morphology of the as-grown SnO nanostructures on Si substrate was characterized by field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Raman spectroscopy was used to confirm the phase of the as-grown SnO nanostructures. As the results, the as-grown tin oxide nanostructures exhibited a pure tin monoxide phase. As the substrate temperature was increased from $350^{\circ}C$ to $424^{\circ}C$, the thickness and grain size of the SnO nanostructures were increased. The SnO nanostructures grown at $450^{\circ}C$ exhibited complex polycrystalline structures, whereas the SnO nanostructures grown at $350^{\circ}C$ to $424^{\circ}C$ exhibited simple grain structures parallel to the substrate.

Semiconductor type micro gas sensor for $H_2$ detection using a $SnO_2-Ag_2O-PtO_x$ system by screen printing technique (스크린 프린팅 기법을 이용한 $SnO_2-Ag_2O-PtO_x$계 반도체식 마이크로 수소 가스센서에 관한 연구)

  • Kim, Il-Jin;Han, Sang-Do;Lee, Hi-Deok;Wang, Jin-Suk
    • Journal of Hydrogen and New Energy
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    • v.17 no.1
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    • pp.69-74
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    • 2006
  • Thick film $H_2$ sensors were fabricated using $SnO_2$ loaded with $Ag_2O$ and $PtO_x$. The composition that gave the highest sensitivity for $H_2$ was in the weight% ratio of $SnO_2 : PtO_x : Ag_2O$ as 93 : 1 : 6. The nano-crystalline powders of $SnO_2$ synthesized by sol-gel method were screen printed with $Ag_2O$ and $PtO_x$ on alumina substrates. The fabricated sensors were tested against gases like $H_2$, $CH_4$, $C_3H_8$, $C_2H_5OH$ and $SO_2$. The composite material was found sensitive against $H_2$ at the working temperature $130^{\circ}C$, with minor interference of other gases. The $H_2$ gas as low as 100 ppm can be detected by the present fabricated sensors. It was found that the sensors based on $SnO_2-Ag_2O-PtO_x$ system exhibited the high performance, high selectivity and very short response time to $H_2$ at ppm level. These characteristics make the sensor to be a promising candidate for detecting low concentrations of $H_2$.

Characterization of Double-layer Optical Sensing Membranes for Dual Sensing of Dissolved Oxygen Concentrations and pH and Their Application to the On-line Monitoring of Fermentation Processes (용존산소농도와 pH의 동시 검출용 이중층 광학 센서막의 특성 및 발효공정의 온라인 모니터링에의 응용)

  • Kim, Chun-Kwang;Lee, Jong-Il
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.370-374
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    • 2009
  • A double-layer optical sensing membrane has been fabricated to measure the concentration of dissolved oxygen (DO) and pH value simultaneously. (tris(4,7-diphenyl-1,10-phenanthroline (Rudpp) ruthenium(II)) as a DO sensitive dye has been mixed in the methyl trimethoxy silane (MTMS) sol-gel solution and coated onto one well in a 24-well microtiter plate. On the DO-sensing layer the GA (3-glycidoxypropyl trimethoxy silane (GPTMS), 3-aminopropyl trimethoxy silane (APTMS)) sol-gel solution mixed with 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (HPTS) has been coated and used to measure pH values. The double-layer sensing membrane was affected by ionic strength and temperature. The double-layer sensing membrane for DO and pH has been applied to online monitor in microorganism cultivation processes and showed a good performance.

Evaluation of Indoor Air Quality Improvement by Formaldehyde Emission Rate in School Indoor Environment Using Mass Balance (물질수지를 이용한 학교 실내환경의 포름알데히드(HCHO) 배출량 산정에 의한 실내공기질 개선 평가)

  • Yang, Won-Ho;Son, Bu-Soon;Kim, Dae-Won;Kim, Young-Hee;Byeon, Jae-Cheol;Jung, Soon-won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.15 no.3
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    • pp.160-165
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    • 2005
  • Schools have significant and serious indoor environmental health problem, of which indoor air quality (IAQ) in school building may affect the health of the students and indirectly affect learning performance. Schools are of special concern when regarding indoor exposure to air pollutants, because students are particularly sensitive to pollutants and spend a significant amount of time in that environment. Therefore researches for improvement of indoor air quality have been developed such as installation of air cleaning device, ventilation system, titanium dioxide(TiO2) coating and so on. However, it is difficult to evaluate the magnitude of improvement of indoor air quality in field study because indoor air quality can be affected by source generation, outdoor air level, ventilation, decay by reaction, temperature, humidity, mixing condition and so on. In this study, evaluation of reduction of formaldehyde emission rate in school indoor environments by far-Infrared ray coating material was carried out using mass balance model in indoor environment. we proposed the evaluation method of magnitude of improvement in indoor air quality, considering outdoor level and ventilation. Since simple indoor concentration measurements could not properly evaluate the indoor air quality, outdoor level and ventilation should be considered when evaluate the indoor air quality.