• Title/Summary/Keyword: temperature cycles

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Ferroelectric and Leakage current Properteis of SBT Capacitor with post-annealing Temperature (후속 열처리에 따른 SBT 캐패시터의 강유전 특성과 누설전류 특성)

  • 오용철;조춘남;김진사;신철기;박건호;최운식;김충혁;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.668-671
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    • 2001
  • The Sr$\_$0.8/Si$\_$2.4/Ta$_2$O$\_$9/(SBT) thin films are deposited on Pt-coated electrode(Pt/TiO$_2$/SiO$_2$/Si) using RF magnetron sputtering method. With increasing post-annealing temperature from 600[$^{\circ}C$] to 850[$^{\circ}C$], Bi-layered perovskite phase was crystallized above 650[$^{\circ}C$]. The maximum remanent polarization and the coercive electric field is 11.60[${\mu}$C/$\textrm{cm}^2$], 48[kV/cm] respectively. The leakage current density of SBT capacitor at post-annealing temperature of 750[$^{\circ}C$] is 1.01${\times}$10$\^$-8/ A/$\textrm{cm}^2$ at 100[kV/cm]. The fatigue characteristics of SBT thin films did not change up to 10$\^$10/ switching cycles.

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Anode-supported Solid Oxide Fuel Cells Prepared by Spin-coating (Spin-coating 공정에 의해 제조된 음극 지지형 고체산화물 연료전지)

  • Yu, Ji-Haeng;Lee, Hee-Lak;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.733-739
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    • 2007
  • NiO-YSZ anode-supported single cell was prepared by spin-coating YSZ and LSM slurries as electrolyte and cathode, respectively. Dense YSZ electrolyte film was successfully prepared on the porous NiO-YSZ anode substrate by tuning pre-sintering temperature of NiO-YSZ and co-firing temperature. The thickness of YSZ film was controlled by the solid content of slurry and coating cycles. The experimental conditions affecting on the thickness of YSZ film was discussed. Single cells with the active electrode area ${\sim}0.8\;cm^2$ were prepared by spin-coating the cathode layers of LSM-YSZ mixture and LSM consequently as well. The effects of the pre-sintering temperature and thus the microstructure of NiO-YSZ substrate on the current-voltage characteristics of co-fired cell were investigated.

Evaluation of Creep Fatigue Crack Growth Behavior of 9Cr Steel Employing Creep Reversal Parameter (크리프 역전 변수 도입에 의한 9Cr강의 크리프 피로 균열성장 거동의 평가)

  • Ma, Young-Wha;Baek, Un-Bong;Yoon, Kee-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1453-1460
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    • 2002
  • Creep-fatigue crack growth models have been proposed employing $(C_t)_{avg}$ as a crack tip parameter characterizing the time-dependent crack growth. The basic assumptions made in these previous models were ideal creep reversal conditions such as no creep reversal and complete creep reversal condition. Due to this assumption, the applicability of the models was limited since they did not consider partial creep reversal condition which is usually observed in many engineering metals at high temperature. In this paper the creep reversal parameter, Temperature;$C_R$, which was defined by Grover, is critically evaluated to quantity the extent of partial creep reversal at the crack tip. This approach does not rely on any simplifying assumptions regarding the extent of the amount of creep reversal during the unloading part of a trapezoidal fatigue cycles. It is shown that the $(C_t)_{avg}$ value calculated for 9Cr steel agrees well with the experimentally measured one. It is argued that the extent of improvement is not significant when the result is compared with that of the conventional model which has an assumption of full creep reversal behavior.

Thermocompression Anisothropic Conductive Films(ACFs) bonding for Flat Panel Displays(FPDs) Application (평판디스플레이를 위한 열압착법을 이용한 이방성 도전성 필름 접합)

  • Pak, Jin-Suk;Jo, Il-Jea;Shin, Young-Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.199-204
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    • 2009
  • The effect of temperature on ACF thermocompression bonding for FPD assembly was investigated, It was found that Au bumps on driver IC's were not bonded to the glass substrate when the bonding temperature was below $140^{\circ}C$ so bonds were made at temperatures of $163^{\circ}C$, $178^{\circ}C$ and $199^{\circ}C$ for further testing. The bonding time and pressure were constant to 3 sec and 3.038 MPa. To test bond reliability, FPD assemblies were subjected to thermal shock storage tests ($-30^{\circ}C$, $1\;Hr\;{\leftrightarrow}80^{\circ}C$, 1 Hr, 10 Cycles) and func! tionality was verified by driver testing. It was found all of FPDs were functional after the thermal cycling. Additionally, Au bumps were bonded using ACF's with higher conductive particle densities at bonding temperatures above $163^{\circ}C$. From the experimental results, when the bonding temperature was increased from $163^{\circ}C$ to $199^{\circ}C$, the curing time could be reduced and more conductive particles were retained at the bonding interface between the Au bump and glass substrate.

Standardization of Surface Replication Procedures for Life Assessment of High Temperature Facilities (고온설비 수명평가를 위한 표면복제 절차의 표준화)

  • Park, Jong-Seo;Lee, Hae-Mu;Baek, Un-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.9 s.180
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    • pp.2381-2386
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    • 2000
  • Surface replication is playing an important role in the assessment of creep damage and remaining life of high temperature components. As the replication procedures, however, have not been standardized in domestic industry, its standardization is proposed in this study. For this purpose, the 2.25Cr-IMo steel was heat treated(5 min at 1,300 0C and oil quenched) to produce a simulated HAZ microstructure, and crept in air at 575 0C and under 120 MPa to produce artificial cavities. Then, the effect of surface preparation procedures on the quality of replicas was investigated using this sample. As a result, it was demonstrated that the presence of cavities may be observed readily or missed depending on the surface preparation procedures followed. Therefore it is essential to repeat three polishing/etching cycles at least in order to reveal cavitation damage accurately, even though it may be tedious or time-consuming.

Thermo-Mechancal Fatigue of the Nickel Base Superalloy IN738LC for Gas Turbine Blades (가스터빈 블레이드용 IN738LC의 열기계피로수명에 관한 연구)

  • Fleury, E.;Ha, J.S.;Hyun, J.S.;Jang, S.W.;Jung, H.
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.188-193
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    • 2000
  • A more accurate life prediction for gas turbine blade takes into account the material behavior under the complex thermo-mechanical fatigue(TMF) cycles normally encountered in turbine operation. An experimental program has been carried out to address the thermo-mechanical fatigue life of the IN738LC nickel-base superalloy. In the first phase of the study, out-of-phase and in-phase TMF experiments have been performed on uncoated and coated materials. In the temperature range investigated. the deposition of NiCrAlY air plasma sprayed coating did not affect the fatigue resistance. In the second phase of the study, a physically-base life prediction model that takes into account of the contribution of different damage mechanisms has been applied. This model was able to reflect the temperature and strain rate dependences of isothermal cycling fatigue lives, and the strain-temperature history effect on the thermo-mechanical fatigue lives.

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Electrical Properties of 50% Pb-excess PZT Thin Films Deposited on the Glass Substrates (유리기판위에 증착한 50% Pb-excess PZT박막의 전기적특성)

  • Jeong, Kyu-Won;Park, Young;Ju, Pil-Yeon;Park, Ki-Yup;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.370-375
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    • 2001
  • PZT thin films (3500${\AA}$) ahve been prepared onto Pt/Ti/corning glass (1737) substrates with a RF magnetron sputtering system using Pb$\sub$1.50/(Zr$\sub$0.52/,Ti$\sub$0.48)O$_3$ ceramic target. We used two-step annealing techniques, PZT thin films were grown at a 300$^{\circ}C$ substrate temperature and then subjected to an RTA treatment. In case of 500$^{\circ}C$ RTA temperature show pyrochlore phase. The formation of Perovskite phase started above 600$^{\circ}C$ and PZT thin films generated (101) preferred orientation. As the RTA time and temperature increased, crystallization of PZT films were enhanced. The PZT capacitors fabricated at 650$^{\circ}C$ for 10 minutes RTA treatment showed remanent polarization 30 ${\mu}$C/$\textrm{cm}^2$, saturation polarization 42${\mu}$C/$\textrm{cm}^2$, coercive field 110kV/cm, leakage current density 2.83x10$\^$-7/A/$\textrm{cm}^2$, remanent polarization were decreased by 30% after 10$\^$9/ cycles.

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An Investigation on Flow and Structural Characteristics of Heat Exchanger in Rankine Steam Cycle for Co-generation System (기관 폐열 회수를 위한 열교환기의 Baffle 길이 변경에 따른 성능 예측에 관한 수치 해석적 연구)

  • Ryu, Kyuhyenn;Kim, Kusung;Lee, Younghum;Kang, Seokho;Park, Gibeom
    • New & Renewable Energy
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    • v.9 no.4
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    • pp.32-39
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    • 2013
  • A 2-loop waste heat recovery system with Rankine steam cycles for the improvement of fuel efficiency of gasoline vehicles has been investigated. A high temperature loop is used to recover waste heat from exhaust gas and a low temperature loop is used to recover waste heat from cold engine coolant. This paper has dealt with a layout of low temperature loop system, the review of the velocity contours through numerical analysis. According to the result of analysis, the designed heat exchanger. And comparing with flow analysis results, LT Boiler is safe to operation.

Studies on Absorption and Desorption Wood - Difference of Absorption and Desorption Behavior of Wood - (목재의 흡방습에 관한 연구 - 수종에 의한 흡방습성의 차이 -)

  • Lee, Weon-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.19 no.4
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    • pp.52-61
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    • 1991
  • In this paper, the difference of the property of absorption and desorption for five species in semi-steady state are studied. The species used are listed in Table 1 and the dimension of specimen was $8\times8{\times}T$(Tangential direction)cm and tested in various conditions. A change of average moisture content with time were measured in each cycles. The results obtained are summarized as follows. When the relative humidity in air was maximum or minimum, the distribution of moisture In wood of all specimens were illustrated by exponential curves of decrease or increased from lace 10 center of wood. From the consideration of coefficient of decrease(C), the amount of moisture change of spruce was larger than the others. The pheonomenon was considered no relation to the specific gravity in air dry, but the wood structures. The velocity of the absorption and desorption for species decreased in the order spruce(Picea sitchensis) neodobam(Fagus crenata), solsong(Tsuga heterophylla), meranti(Shorea sp.) and kaesoo(Cercidiphyllum japoicum). In case of constant temperature and water vapor pressure is changed. the amount of absorbed moisture was larger than that of constant water vapor pressure and temperature vaned. In this fact, it is considered that the property of sorption of wood is strongly influenced by vapor pressure gradient than temperature gradient.

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Cycling Behavior of Binder-Free Graphite-Lithium Intercalation Anode In AICI3-EMIC-LiCI-SOCI2 Room-Temperature Molten Salt

  • Koura, Nobuyuki;Minami, Takuto;Etoh, Keiko;Idemoto, Yasushi;Matsumoto, Futoshi
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.178-182
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    • 2002
  • The electrochemical behavior of binder-free carbon anode, comprising of only artificial and natural graphite (AG and NG) particles, for intercalation and deintercalation of lithium ion $(Li^+)$ in aluminum chloride (AICI_3)-I-ethyl­3-methylimidazolium chloride (EMIC)-lithium chloride (LiCl)-thionyl chloride $(SOCI_2)$ room-temperature molten salt (RTMS) was studied. Binder-free carbon electrodes were fabricated using electrophoretic deposition (EPD) method. The binder-free carbon anodes provided a relatively flat charge and discharge potentials $(0\;to\;0.2V\;vs.\;Li/Li^+)$ and current capabilities $(250-340mAh{\cdot}g^{-1})$ for the intercalation and deintercalation of $Li^+$. Stability of the binder-free carbon anodes for intercalation and deintercalation of 50 cycles was confirmed.