• Title/Summary/Keyword: temperature cycles

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Fabrication of ZnO thin film gas sensor for detecting $(CH_3)_3N$ gas ($(CH_3)_3N$ 가스 감지용 ZnO 박막 가스 센서의 제조)

  • 신현우;박현수;윤동현;홍형기;권철한;이규정
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.21-26
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    • 1995
  • Highly sensitive and mechanically stable gas sensors have been fabricated using the microfabrication and micromaching techniques. The sensing material used to detect the offensive trimethylarnine ((CH$_{3}$)$_{3}$N) gas is 6 wt% $Al_{2}$O$_{3}$-doped, 1000.angs.-thick ZnO deposited by r. f. magnetron sputtering. The optimum operating temperature of the sensor is 350.deg.C and the corresponding heater power is about 85mW. Excellent thermal insulation is achieved by the use of a double-layer structure of 0.2.mu.m -thick silicon nitride and 1.4.mu.m-thick phosphosilicate glass(PSG) prepared by low pressure chemical vapor deposition(LPCVD) and atmospheric pressure chemical vapor deposition(APCVD), respectively. The sensors are mechanically stable enough to endure at least 43, 200 heat cycles between room temperature and 350.deg. C.

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temperature synthesis and ferroelectric properties of (117)-oriented $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films on $LaNiO_3$ electrodes

  • Kim, Kyoung-Tae;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.264-267
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    • 2004
  • [ $Bi_{3.25}La_{0.75}Ti_3O_{12}$ ] (BLT) thin films were prepared by using metal organic decomposition method onto the $LaNiO_3$ (LNO) bottom electrode. Both the structure and morphology of the films were analyzed by x-ray diffraction (XRD) and atomic force microscope (AFM). Even at low temperatures ranging from 450 to $650^{\circ}C$, the BLT thinfilms were successfully deposited on LNO bottom electrode and exhibited (117) orientation. The BLT thin films annealed as low as $600^{\circ}C$ showed excellent ferroelectricity, higher remanent polarization and no significant degradation of switching charge at least up to $5{\times}10^9$ switching cycles at a frequency of 100 kHz and 5 V. For the annealing temperature of $600^{\circ}C$, the remanent polarization Pr and coercive field were $23.5\;C/cm^2$ and 120 kV/cm, respectively.

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Dielectric Cure Monitoring for Glass/Polyester Prepreg Composites (유리섬유/폴리에스터 복합재료를 위한 유전 경화 모니터링)

  • Kim, Hyoung-Geun;Kim, Jin-Kook;Lee, Dai-Gil
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.797-803
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    • 2001
  • The on-line cure monitoring of fiber reinforced thermosetting resin matrix composite material was performed for the better quality and productivity during manufacturing. Since the dissipation factor measured by dielectrometry method is dependent on the degree of cure and temperature of resin, in this study, a new method to obtain the degree of cure during on-line cure monitoring for glass/polyester composites was developed by employing a combination function of the temperature and the dissipation factor. Two sensor signals from a K-type thermocouple and an interdigitated dielectric sensor were processed during curing process under various cure cycles. The DSC (Differential Scanning Calorimetry) data was also used for the reference of degree of cure.

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Dynamic characteristics of a CSTR with MMA polymerization

  • Ahn, Jong-Pil;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10b
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    • pp.100-105
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    • 1992
  • A mathematical model is developed for a CSTR in which free radical solution polymerization of methyl methacrylate(MMA) takes place. It turns out that five ordinary differential equations are to be treated simultaneously in order to predict the reactor performance. Although the reaction proceeds under the conditions of relatively low temperature and pressure, the system shows very complex bifurcation features due to the diffusion limitation (gel effect) and the temperature dependence of the kinetic parameters and physical properties. The effects of various system parameters on the reactor performance as well as on the polymer properties are investigated by using the bifurcation analysis. The application of the singularity theory enables us to divide the parameter space into several different regions, in each of which the system takes a unique steady state structure. Under certain circumstances, complex dynamic features such as HB points and limit cycles are observed and these should be taken into consideration in the reactor design.

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Simulation of the performance characteristics of the double effect Parallel flow cycle with secondary heat at the low temperature qenerator (저온재생기2열원2중효용(低溫再生器2熱源2重效用) Parallel Flow Cycle의 특성(特性) 해석(解析))

  • Choi, K.K.;Rie, D.H.
    • Solar Energy
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    • v.17 no.3
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    • pp.43-49
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    • 1997
  • Cycle simulaton of the double effect parallel flow model is applied to a Lithium-Bromide/water system, with the objective of evaluation the possibilities of effectively utilizing waste-heat as a secondary heat source for the low-temperature generator. In this study, cycle simulation has been carried out to clarify the effect heat exchange in order to predict the performance of absorption refrigeration cycles using waste heat.

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Thermal Storage Characteristics of $H_2O$-NaCl Mixtures for the Low Temperature Storage of Agricultural Products (농산물 저온 저장을 위한 $H_2O$-NaCl 혼합물의 축열 특성)

  • Song, H.K.;Ryou, Y.S.;Park, J.K.;Ro, J.G.
    • Solar Energy
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    • v.17 no.3
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    • pp.23-33
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    • 1997
  • The theory on phase change temperature control and nucleation of PCM was suggested in this research. The crystallization model of PCM was established. And H2O-NaCl mixtures were selected as cold storage materials for agricultural products and thermo-physical properies of the PCM were analyzed with experimental processes including freeze-thaw cycles.

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Exchange Bias in Cr2O3/Fe3O4 Core/Shell Nanoparticles

  • Yun, B.K.;Koo, Y.S.;Jung, J.H.
    • Journal of Magnetics
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    • v.14 no.4
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    • pp.147-149
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    • 2009
  • We report the exchange bias in antiferromagnet/ferrimagnet $Cr_2O_3/Fe_3O_4$ core/shell nanoparticles. The magnetic field hysteresis curve for $Cr_2O_3/Fe_3O_4$ nanoparticles after field-cooling (FC) clearly showed both horizontal ($H_{EB}{\sim}$610 Oe) and vertical (${\Delta}M{\sim}$5.6 emu/g) shifts at 5 K. These shifts disappeared as the temperature increased toward the Neel temperature of $Cr_2O_3\;(T_N{\sim}$307 K). The $H_{EB}\;and\;{\Delta}M$ values were sharply decreased between the $1^{st}\;and\;the\;2^{nd}$ magnetic field cycles, and then slowly decreased with further cycling. These results are discussed in terms of the formation of single domains with pinned, uncompensated, antiferromagnetic spin and their evolution into multi-domains with cycling.

The Properties of the Metal Hydride electrodes prepared by Silicon Sealant (Si-sealant를 이용하여 제조한 금속수소화물 전극의 특성)

  • CHOI, Jeon;PARK, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.4 no.2
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    • pp.23-28
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    • 1993
  • The $(LM)Ni_{4.5}Co_{0.1}Mn_{0.2}Al_{0.2}$ hydrogen storage alloy powders were conducted 25wt% electroless copper plating in an acidic bath. For the preparation of a hydride electrodes, the copper coated alloy powder was mixed with Si-sealant(organosilicon) and compacted with $6t/cm^2$ at room temperature. The electrode characteristics were examined through electrochemical measurements in a half cell. As a sealant contents increased, the initial discharge capacity of si-sealant bounded electrode was lower and the activation rate in high current density was slower. For extended cycles, however, the electrodes with the Si-sealant were superior in a high rate discharge and useful range of temperature over the sealant-free electrode. In addition, the cycle life increased with increasing the amount of Si-sealant added. It can be suggested from the results that the Si-sealant as a binder could be applied to the preparation of the metal hydride electrode.

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Experimental Test and Numerical Simulation on the SMA Characteristics and Behaviors for Repeated Actuations (반복적인 작동을 위한 형상기억합금의 특성 실험과 거동 전산 모사)

  • Kim, Sang-Haun;Cho, Maeng-Hyo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.3 s.258
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    • pp.373-379
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    • 2007
  • In this study, we observe the application of shape memory alloy(SMA) into smart structures for repeatable actuation, because SMA changes its material properties and characteristics progressively under cyclic loading conditions and finally reaches stable path(state) after a certain number of stress/temperature loading-unloading cycles, so called 'training'. In this paper, SMA wires that have been in a stable state through the training are used. Stress-strain curve of the SMA wire at different temperature levels are measured. In addition, we observe other important effects such as the rate effect according to strain rates for rapid actuation response. The current work presents the experimental test using SMA wire after training completion by mechanical cycling. Through these tests, we measure the characteristics of SMA. With the estimated SMA properties and effects, we compare the experimental results with the simulation results based on the SMA constitutive equations.

A Study on Thermal Stability of Unidirectionally Solidified $Al-CuAl_2$ Eutectic Composite (일방향응고시킨 $Al-CuAl_2$공정복합재료의 열적안정성에 관한 연구)

  • Hong, Young-Hwan;Hong, Jong-Hwi
    • Journal of Korea Foundry Society
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    • v.10 no.5
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    • pp.399-407
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    • 1990
  • The effect of thermal cycling and isothermal exposure on the high temperature microstructural stability of unidirectionally solidified $Al-CuAl_2$ eutectic composite has been studied. A coarsening procedures of lamellar eutectic structures were initiated at growth fault region because of diffusion through low angle boundary at this region. It was considered that thermally induced residual stresses produced by thermal cycling were high enough to increase the dislocation density in Al-rich matrix phase. However, it was also considered that dislocations generated by these high thermal stresses were annihilated at high temperature by stress relaxation. Consequently, the thermal cycling up to 1440 cycles between 20 and $520^{\circ}C$ did not affect the microstructural stability.

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