• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1073-1079
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• 1998

The potential energy surface (PES) of the non-identical SN2 reactions, F- + CH3Cl → FCH3 + Cl and (H2O)F + CH3Cl → FCH3 + Cl-(H2O), were investigated with ab initio MO calculations. The ab initio minimum energy reaction path (MERP) of the F- + CH3Cl → FCH3 + Cl- was obtained and it was expressed with an intermediate variable t. The ab initio PES was obtained near around t. Analytical potential energy function (PEF) was determined as a function of the t in order to reproduce the ab initio PES. Based on Morse-type potential energy function, a Varying Repulsive Cores Model (VRCM) was proposed for the description of the bond forming and the bond breaking which occur simultaneously during the SN2 reaction. The MERP calculated with the PEF is well agreed with the ab initio MERP and PEF could reproduce the ab initio PES well. The potential parameters for the interactions between the gas phase molecules in the reactions and water were also obtained. ST2 type model was used for the water.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.455-460
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• 2004

There have been many speculations about the presence of cosmic ray protons (CRps) in galaxy clusters over the past two decades. However, no direct evidence such as the characteristic $\gamma$-ray signature of decaying pions has been found so far. These pions would be a direct tracer of hadronic CRp interactions with the ambient thermal gas also yielding observable synchrotron and inverse Compton emission by additionally produced secondary electrons. The obvious question concerns the type of galaxy clusters most likely to yield a signal: Particularly suited sites should be cluster cooling cores due to their high gas and magnetic energy densities. We studied a nearby sample of clusters evincing cooling cores in order to place stringent limits on the cluster CRp population by using non-detections of EGRET. In this context, we examined the possibility of a hadronic origin of Coma-sized radio halos as well as radio mini-halos. Especially for mini-halos, strong clues are provided by the very plausible small amount of required CRp energy density and a matching radio profile. Introducing the hadronic minimum energy criterion, we show that the energetically favored CRp energy density is constrained to $2\%{\pm}1\%$ of the thermal energy density in Perseus. We also studied the CRp population within the cooling core region of Virgo using the TeV $\gamma$-ray detection of M 87 by HEGRA. Both the expected radial $\gamma$-ray profile and the required amount of CRp support this hadronic scenario.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.571-574
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• 2004

Clusters of galaxies are filled with X-ray emitted hot gas with the temperature of T ${\~}$2-10 keV. Recent X-ray observations have been revealing unexpectedly that many cluster cores have complicated, peculiar X-ray structures, which imply dynamical motion of the hot gas. Moreover, X-ray spectra indicate that radiative cooling of the cool gas is suppressed by unknown heating mechanisms (the 'cooling flow problem'). Here we propose a novel mechanism reproducing both the inhomogeneous structures and dynamics of the hot gas in the cluster cores, based on state-of-the-art hydrodynamic simulations. We showed that acoustic-gravity waves, which are naturally expected during the process of hierarchical structure formation of the universe, surge in the X-ray hot gas, causing a serous impact on the core. This reminds us of tsunamis on the ocean surging into an distant island. We found that the waves create fully-developed, stable turbulence, which reproduces the complicated structures in the core. Moreover, if the wave amplitude is large enough, they can suppress the cooling of the core. The turbulence could be detected in near-future space X-ray missions such as ASTRO-E2.

• The Journal of Korean Academy of Prosthodontics
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• v.38 no.2
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• pp.255-263
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• 2000

The purpose of this study was to compare the microleakage of the composite resin cores according to surface treatment, dentin bonding agents, and thermocycling. For this study, 120 extracted premolar teeth were used. Flat occlusal surfaces were prepared with diamond disk, and treated with air-abrasion, acid-etching, combination. The composite resin core was built with Z-100 after application of Scotchbond Multi-Purpose and All-Bond 2. Prepared specimens were thermocycled for 2,000 cycles. Specimens were immersed in 1% methylene blue solution for 24hours at $37^{\circ}C$. The microleakage was measured with a inverted metallurgical microscope(BHS313, Olympus, Japan). The following conclusions were drawn from this study: 1. The microleakages in the groups treated with air-abrasion and with acid etching were greater than that of the groups treated with combination method before thermocycling(p<0.05), the microleakages of the groups treated with air-abrasion were greater than that of the groups treated with acid-etching and combination method after thermocycling(p<0.05) 2. There were no significant difference between groups using Scotchbond Multi-Purpose and the groups using All-Bond 2. 3. Thermocycling didn't affect the change of microleakage in all cases.

• Computers and Concrete
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• v.25 no.4
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• pp.327-341
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• 2020

Advanced forms of structural design (e.g., displacement-based methods) require knowledge of the non-linear force-displacement behavior of both the overall building and individual lateral load resisting elements, i.e., walls or building cores. Similarly, understanding the non-linear behaviour of the elements in a structure can also allow for a less conservative structural response to be calculated by better understanding the cracked (i.e., effective) properties of the various RC elements. Calculating the non-linear response of an RC section typically involves using 'black box' analysis packages, wherein the user may not be in complete control nor be aware of all the intricate settings and/or decisions behind the scenes. This paper introduces a user-friendly and transparent analysis program for predicting the back-bone force displacement behavior of slender (i.e., flexure controlled) RC walls, building cores or columns. The program has been validated and benchmarked theoretically against both commonly available and widely used analysis packages and experimentally against a database of 16 large-scale RC wall test specimens. The program, which is called WHAM, is written using Microsoft Excel spreadsheets to promote transparency and allow users to further develop or modify to suit individual requirements. The program is available free-of-charge and is intended to be used as an educational tool for structural designers, researchers or students.

• Nuclear Engineering and Technology
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• v.48 no.2
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• pp.318-329
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• 2016

Reducing critical boron concentration in a commercial pressurized water reactor core offers many advantages in view of safety and economics. This paper presents a preliminary investigation of a reduced-boron pressurized water reactor core to achieve a clearly negative moderator temperature coefficient at hot zero power using the newly-proposed "Burnable absorber-Integrated Guide Thimble" (BigT) absorbers. The reference core is based on a commercial OPR1000 equilibrium configuration. The reduced-boron ORP1000 configuration was determined by simply replacing commercial gadolinia-based burnable absorbers with the optimized BigT-loaded design. The equilibrium cores in this study were directly searched via repetitive Monte Carlo depletion calculations until convergence. The results demonstrate that, with the same fuel management scheme as in the reference core, application of the BigT absorbers can effectively reduce the critical boron concentration at the beginning of cycle by about 65 ppm. More crucially, the analyses indicate promising potential of the reduced-boron OPR1000 core with the BigT absorbers, as its moderator temperature coefficient at the beginning of cycle is clearly more negative and all other vital neutronic parameters are within practical safety limits. All simulations were completed using the Monte Carlo Serpent code with the ENDF/B-VII.0 library.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.05a
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• pp.266-269
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• 2009

Iron-based soft magnetic materials are widely used as cores, such as transformer transformers, motors, and generators. Reducing losses generated from soft magnetic materials of these applications results in improving energy conversion efficiency. Recently, the new P/M soft magnetic material realized an energy loss of 68 W/kg with a drive magnetic flux of 1 T, at a frequency of 1 kHz, rivaling general-purpose electromagnetic steel sheet in the low frequency range of 200 Hz to 1 kHz. In this research, the effect of rolling parameters on soft magnetic properties of Fe-based powder cores was investigated. The Fe-based soft magnetic plates were produced by the hot powder rolling process after both pure Fe and Fe-4%Si powders were canned, evacuated, and sealed in Cu can. The soft magnetic properties such as energy loss and coercive power were measured by B-H curve analyzer. The soft magnetic properties of rolled sheets were measured under conditions of a magnetic flux density of 1 T at a frequency of 200 kHz. It was found that rolling reduction ratio is the most effective parameter on reducing both energy loss and coercivity because of increasing aspect ratio with reduction ratio. By increasing aspect ratio from 1 to 9 through hot rolling of pure Fe powder, a significant loss reduction of one-third that of SPS sample was achieved.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.70.4-70.4
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• 2019

Complex organic molecules (COMs) are increasingly observed in the environs of young stellar objects (YSOs), including hot cores/corinos around high-mass/low-mass protostars and protoplanetary disks. It is widely believed that COMs are first formed in the ice mantle of dust grains and subsequently released to the gas by thermal sublimation at high temperatures (T>100 K) in strong stellar radiation fields. In this paper, we report a new mechanism that can desorb COMs from icy grain mantles at low temperatures (T<100K), which is termed rotational desorption. The rotational desorption process of COMs comprises two stages: (1) ice mantles on suprathermally rotating grains spun-up by radiative torques (RATs) are first disrupted into small fragments by centrifugal stress, and (2) COMs and water ice then evaporate rapidly from the tiny fragments (i.e., radius a <1nm) due to thermal spikes or enhanced thermal sublimation due to increased grain temperature for larger fragments (a>1 nm). We discuss the implications of rotational desorption for releasing COMs and water ice in the inner region of protostellar envelopes (hot cores and corinos), photodissociation regions, and protoplanetary disks (PPDs). In shocked regions of stellar outflows, we find that nanoparticles can be spun-up to suprathermal rotation due to supersonic drift of neutral gas, such that centrifugal force can be sufficient to directly eject some molecules from the grain surface, provided that nanoparticles are made of strong material. Finally, we find that large aggregates (a~ 1-100 micron) exposed to strong stellar radiations can be disrupted into individual icy grains via RAdiative Torque Disruption (RATD) mechanism, which is followed by rotational desorption of ice mantles and evaporation of COMs. In the RATD picture, we expect some correlation between the enhancement of COMs and the depletion of large dust grains in not very dense regions of YSOs.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.20 no.7
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• pp.1296-1302
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• 2016

A hardware implementation of ultra-lightweight block cipher algorithm PRESENT that was specified as a block cipher standard for lightweight cryptography ISO/IEC 29192-2 is described in this paper. Two types of crypto-core that support master key size of 80-bit are designed, one is for encryption-only function, and the other is for encryption and decryption functions. The designed PR80 crypto-cores implement the basic cipher mode of operation ECB (electronic code book), and it can process consecutive blocks of plaintext/ciphertext without reloading master key. The PR80 crypto-cores were designed in soft IP with Verilog HDL, and they were verified using Virtex5 FPGA device. The synthesis results using $0.18{\mu}m$ CMOS cell library show that the encryption-only core has 2,990 GE and the encryption/decryption core has 3,687 GE, so they are very suitable for IoT security applications requiring small gate count. The estimated maximum clock frequency is 500 MHz for the encryption-only core and 444 MHz for the encryption/decryption core.

• The Journal of Advanced Prosthodontics
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• v.5 no.4
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• pp.485-493
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• 2013

PURPOSE. To evaluate the effects of surface treatments on shear bond strength (SBS) between microwave and conventionally sintered zirconia core/veneers. MATERIALS AND METHODS. 96 disc shaped Noritake Alliance zirconia specimens were fabricated using YenaDent CAM unit and were divided in 2 groups with respect to microwave or conventional methods (n=48/group). Surface roughness (Ra) evaluation was made with a profilometer on randomly selected microwave (n=10) and conventionally sintered (n=10) cores. Specimens were then assessed into 4 subgroups according to surface treatments applied (n=12/group). Groups for microwave (M) and conventionally (C) sintered core specimens were as follows; $M_C$,$C_C$: untreated (control group), $M_1,C_1:Al_2O_3$ sandblasting, $M_2,C_2$:liner, $M_3,C_3:Al_2O_3$ sandblasting followed by liner. Veneer ceramic was fired on zirconia cores and specimens were thermocycled (6000 cycles between $5^{\circ}-55^{\circ}C$). All specimens were subjected to SBS test using a universal testing machine at 0.5 mm/min, failure were evaluated under an optical microscope. Data were statistically analyzed using Shapiro Wilk, Levene, Post-hoc Tukey HSD and Student's t tests, Two-Way-Variance- Analysis and One-Way-Variance-Analysis (${\alpha}$=.05). RESULTS. Conventionally sintered specimens ($1.06{\pm}0.32{\mu}m$) showed rougher surfaces compared to microwave sintered ones ($0.76{\pm}0.32{\mu}m$)(P=.046), however, no correlation was found between SBS and surface roughness (r=-0.109, P=.658). The statistical comparison of the shear bond strengths of $C_3$ and $C_1$ group (P=.015); $C_C$ and $M_C$ group (P=.004) and $C_3$ and $M_3$ group presented statistically higher (P=.005) values. While adhesive failure was not seen in any of the groups, cohesive and combined patterns were seen in all groups. CONCLUSION. Based on the results of this in-vitro study, $Al_2O_{3-}$ sandblasting followed by liner application on conventionally sintered zirconia cores may be preferred to enhance bond strength.