• Title/Summary/Keyword: synthetic dyes

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Determination of Synthetic Food Colours by HPLC with Photodiode Array Detector (HPLC를 이용한 타르색소의 분리정량)

  • Yang, Ho-Chul;Heo, Nam-Chil
    • Korean Journal of Food Science and Technology
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    • v.31 no.1
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    • pp.30-35
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    • 1999
  • A simple, rapid, efficient method is for extraction of 13 synthetic water-soluble food colours (Tartrazine, Amarnth, Indigo carmine, New coccine, Sunset yellow FCF, Allura red AC, Eosine, Fast Green FCF, Brilliant Blue FCF, Erythrosine, Acid red, phloxine, Rose Bengal) by polyamide resin and for their quantitative by high performance liquid chromatography (HPLC). Colours (coal-tar dyes) were extracted with polyamide resin and then determinated by HPLC. The HPLC conditions using a reverse phase partition type column $(Nova-pak\;C_{18})$, photodiode array (PDA) detector and 1% Ammonium acetate / 60% acetonitrile in water as eluent, were acceptable for various kinds of colorants. By the use of the proposed method, a survey of coal-tar dyes was carried out on 20 samples and that were detected $4.76{\sim}133.47\;ppm$.

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Natural Dyeing of Polyester Fabric with Microcapsules(II) - Scutellaria baicalensis - (마이크로캡슐에 의한 폴리에스테르 직물의 천연염색에 관한 연구(II) - 황금을 중심으로 -)

  • Min, Kyung-Hae
    • Fashion & Textile Research Journal
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    • v.10 no.6
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    • pp.1045-1050
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    • 2008
  • Developing of high technology, productivity of the fiber product has being rapidly increased and also various kinds of advanced treatment process lead consumer's needs to more high functional, clean and healthy goods. Moreover, increasing in the concern of eco-friendly material and processing, it has been getting popular that the dyeing method like as using natural dyes is more eco-friendly and natural-friendly treatment process. The method, used in this study, adhesion by binding with micro-capsulized natural material to fabric has low change in quality by external influence and high ability in spray effect by broken capsule which comes to pressure and friction when it dressed. Also it has wide application from natural fiber to synthetic fiber. The purpose of this study is development of multi-functional synthetic material with micro-capsulized Scutellaria baicalensis on PET. Moreover, it was driven by comparison of colormetric properties and fastness between regular dip-dyeing method and binding with micro-capsulized material method. Dye ability was arranged mostly low exhaustion but the PET treated by micro-capsule was more or less better than the dip-dyeing PET. Through the SEM(Scanning Electron Microscope) of PET treated by micro-capsule, it has good residence of capsules even after 5 or 10 times washing. Wash and light fastness was arranged some different grade by each condition but mostly high achievement and the micro-capsulized PET was more improved than regular dip-dyed PET.

Development of the ultra/nano filtration system for textile industry wastewater treatment

  • Rashidi, Hamidreza;Sulaiman, Nik Meriam Nik;Hashim, Nur Awanis;Bradford, Lori;Asgharnejad, Hashem;Larijani, Maryam Madani
    • Membrane and Water Treatment
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    • v.11 no.5
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    • pp.333-344
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    • 2020
  • Advances in industrial development and waste management over several decades have reduced many of the impacts that previously affected ecosystems, however, there are still processes which discharge hazardous materials into environments. Among industries that produce industrial wastewaters, textile manufacturing processes play a noticeable role. This study was conducted to test a novel continuous combined commercial membrane treatment using polyvinylidene fluoride (PVDF), ultrafiltration (UF), and polyamide (PA) nanofiltration (NF) membranes for textile wastewater treatment. The synthetic textile wastewater used in this study contained sodium silicate, wax, and five various reactive dyes. The results indicate that the removal efficiency for physical particles (wax and resin) was 95% through the UF membrane under optimum conditions. Applying UF and NF hybrid treatment resulted in total effective removal of dye from all synthetic samples. The efficiency of sodium silicate removal was measured to be between 2.5 to 4.5% and 13 to 16% for UF and NF, respectively. The chemical oxygen demand in all samples was reduced by more than 85% after treatment by NF.

Decolorization Efficiency of Different Dyes by Extract from Spent Mushroom Substrates of Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 수확 후 배지추출물을 이용한 다양한 염료의 탈색효과)

  • Lim, Seon Hwa;Kwak, A Min;Min, Gyeong Jin;Kim, Sang Su;Lee, Sang Yeop;Kang, Hee Wan
    • The Korean Journal of Mycology
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    • v.42 no.3
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    • pp.213-218
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    • 2014
  • Water extract from spent mushroom substrates (SMS) of Pleurotus eryngii was utilized in decolorization of eight synthetic dyes and wastewater from a textile factory. High laccase activity was detected in the extract of P. eryngii (SMSE). The SMSE showed that decolorization rate was 34~93% after 24 h incubation without any mediator on eight dyes including Rit-blue and Rit-red used in fiber dyeing. Dye decolorization rate more than 90% was observed on bromophenol blue and remazol brilliant blue R (RBBR). Dye in textile wastewater was decolorized at room temperature after three days by addition of P. eryngii SMSE. The results suggest that biological decolorization of dyes using the P. eryngii SMSE can be used as environmental friendly materials.

Supercritical Dyeing Technology (초임계 염색 기술)

  • Kim, Taewan;Park, Geonhwan;Kong, Wonbae;Lee, Youn-Woo
    • Clean Technology
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    • v.24 no.1
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    • pp.1-8
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    • 2018
  • As the social demands for environmental pollution increase and regulations on the dyeing process wastewater are strengthened, supercritical dyeing process has been attracting attention as an alternative technology to reduce wastewater and energy consumption. In the supercritical dyeing process where carbon dioxide is used as a solvent instead of water as a solvent, there is no wastewater generated. The unfixed dyes can be reused later which makes the process environment-friendly. Also, after dyeing process, dried textiles can be obtained without additional drying process, which makes the process energy efficient. In this article, we have summarized the development of the supercritical dyeing process along with the research in Korea today and compared the principle of supercritical dyeing process with conventional dyeing process. To further explain the principle, studies of the distribution factor and mass transfer of dyes in supercritical carbon dioxide and fibers, as well as solubility between supercritical $CO_2$ and dyes are discussed. The dynamic behavior of dyes in supercritical dyeing apparatus and summary of the supercritical dyeing facilities developed around the world are also discussed. Finally, we suggest the direction of research and development for optimization of supercritical dyeing process and application to synthetic fibers and natural fibers except for polyester.

Industrial applications and characteristics of lignocellulolytic enzymes in Basidiomycetous fungi (담자균류 목질섬유소 분해효소의 특성과 산업적 이용)

  • Lim, Sun-Hwa;Kang, Hee-Wan
    • Journal of Mushroom
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    • v.14 no.2
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    • pp.51-58
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    • 2016
  • Basidiomycetous fungi are one of the most potent biodegraders because many of its species grow on dead wood or litter, in environments rich in lignocellulose. For the degradation of lignocellulose, basidiomycetes utilize their lignocellulytic enzymes, which typically include laccase (EC 1.10.3.2), lignin peroxidase (EC 1.11.1.14), xylanase (EC 3.2.1.8), and cellulase (EC 3.2.1.4). In recent years, the practical applications of basidiomycetes have ranged from the textile to the pulp and paper industries, and from food applications to bioremediation processes and industrial enzymatic saccharification of biomass. Recently, spent mushroom substrates of edible mushrooms have been used as sources of bulk enzymes to decolorize synthetic dyes in textile wastewater. In this review, the occurrence, mode of action, general properties, and production of lignocellulytic enzymes from mushroom species will be discussed. We will also discuss the potential applications of these enzymes.

The Synthesis and Light Absorption Behaviour of Novel Coumarin Chromophores

  • An, Kyoung Lyong;Shin, Seung Rim;Jun, Kun;Park, Soo Youl
    • Journal of the Korean Chemical Society
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    • v.58 no.3
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    • pp.297-302
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    • 2014
  • The synthetic route to coumarin systems is well established and one approach of particular interest leads to the intermediate 7-diethylamino-3-formylcoumarin. A combination of the N,N-diethylamino-coumarin donor with a wide range of acceptor groups of varying electron withdrawing strength should permit the synthesis of a series of extended coumarin dyes with absorption maxima range from 500 to 600 nm, or even beyond. In this communication, a novel efficient synthesis of indoles, benzothiazole and benzoxazole based on coumarin chromophores were achieved and the coloristic and fluorophoric properties of these chromophores were studied.

Dyeing of Silk with Lichen Extract (지의류 추출염액에 의한 견섬유 염색)

  • 이전숙;이득영
    • Textile Coloration and Finishing
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    • v.11 no.6
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    • pp.43-50
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    • 1999
  • Lichen had been used as dyestuffs before the discovery of synthetic dyes in Europe and by American Indians. To investigate the dyeability of Korean native lichens, 10 kinds of lichen were collected and colorants were extracted from them by boiling in water and fermenting in ammonia water. Silk fabrics were dyed with lichen extract, then the colour differences of dyed silk fabrics were measured before and after color fastness test. The most part of the lichen extracts(Fc, Hh, Me, Pl, Xm, Pr, Cj, Ld, Ry) dyed silk yellowish or reddish brown. The range of colors were 2.4Y 6.5∼10YR 6/7. Pa extract dyed silk purple(1.25RP 5/6). Color differences of laundered specimen with the silk before laundering were very small, but color of the dyed silks after exposing to light showed big differences with the specimen before exposing to light. The colors of the silks dyed with lichens changed from yellowish or reddish brown to greenish brown by laundering and by exposing to light. But the specimen dyed Pa extract changed from purple to blueish purple by laundering and reddish purple by exposing to light.

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New Synthetic Approach to Squarylium Near Infrared Dyes

  • Park, Soo-Youl;Oh, Sea-Wha
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.29-31
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    • 2003
  • The 1,3-bis(4-aminoaryl)squaraines showed colour change behaviour, they were found to undergo reduction with sodium borohydride in solution to give colourless leuco compounds, which oxidised readily in air back to the coloured squaraine dye. We have shown that oxidation of the parent leuco-squaraines gives the neutral squaraine system. Initial observations indicated that the derivatives gave new long-wavelength absorbing chromophores, and It is interesting to note that the onidation of the leuco squaraines did initially produce a species absorbing at longer wavelengths than the parent squaraine dye. This colour-change redox behaviour has potential in the area of peroxidase-based bioassays and artificial camouflage.

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Synthesis and Luminescent Properties of Light Harvesting Dendrimers Encapsulated Fluorescent Dyes

  • Choi, Dong-Hoon;Kim, Hong-Suk;Kim, Go-Woon;Cho, Min-Ju;Jin, Jung-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.980-983
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    • 2006
  • New blue light emitting branched molecules were synthesized by reacting 3,5-bis-(3,5-bis-benzyloxy)- benzoic moiety or 3,5-bis-(3,5-bis-benzyloxy-benzyloxy)- benzoic moiety with biscarbazolyl vinyl biphenyl moiety by dicyclohexylcarbodiimide (DCC) catalyzed esterification. Similar synthetic strategy was also applied to prepare a red light emitting dendrimer. In this paper, we described two blue emitting dendrimers for investigating the effect of the dendronized structures on photoluminescence (PL) and electroluminescence (EL). EL properties of the dendrimers were investigated using heterostructured samples in detalil.

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