• 한국염색가공학회지
• /
• 제6권3호
• /
• pp.67-73
• /
• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

• Carbon letters
• /
• 제11권1호
• /
• pp.1-8
• /
• 2010

The adsorption of Acid Blue 92 onto three low cost and ecofriendly biosorbents viz., cow dung ash, mango stone ash and parthenium leaves ash and commercial activated carbon have discussed in this work. The ash of all the mentioned bio-wastes was prepared in the muffle furnace at $500^{\circ}C$ and all the adsorbents were stored in an air thermostat. Experiments at total dye concentrations of 10~100 mg/L were carried out with a synthetic effluent prepared in the laboratory. The parameters such as pH and dye concentration were varied. Equilibrium adsorption data followed both Langmuir and Freundlich isotherms. The results indicate that cow dung ash, mango stone ash and parthenium leaves ash could be employed as low-cost alternatives to commercial activated carbon in wastewater treatment for the removal of dye.

• 한국염색가공학회지
• /
• 제5권2호
• /
• pp.99-108
• /
• 1993

In one dyeing system of silk/synthetic blend fabrics (polyester, nylon, acetate) with acid dyes/disperse dyes, dyeability and desorptibility of disperse dyes on silk fabric and transfer from dyed silk fabrics to synthetic fabrics by color difference were examined. When silk dyed with C.I. Disperse Red 19 and C.I. Disperse Red 60 at 10$0^{\circ}C$ for 60 minutes, color difference of dyed silk were $\Delta$E=56.72, $\Delta$E=47.65 for blank silk, respectively. The desorption rate of the dyed silks were measured in boiling bath with and without dye-free synthetic fibers. The desorption rate of dyed silk was effected by affinity of synthetic fabrics contained. When silk dyed with Red 19 and Red 60 was reduced at 10$0^{\circ}C$ for 60 minutes, the decolouration rates of dyed silk were 75% and 40%, respecdtively.

• 복식
• /
• 제60권9호
• /
• pp.77-94
• /
• 2010

It was the era, from 1876 to 1910, that some dramatic changes, including an influx of foreign dyes and the beginning of the modern dyeing manufacture, happened in Korea. This paper explores what dyes were sold in the market in this period, who was the main seller of the goods, and how the dyers produced their products. A wide range of natural dye stuffs coexisted with the various kinds of aniline dyes, alizarin dye and synthetic indigo in the market. Coloring materials had been sold by hwapi-jeon, a group of official merchants who acquired a privilege of monopoly from the government. However, the dyes were also traded by sang-jeon and yakguk merchants in the nineteenth century. Most of the synthetic dyes sold in Korea were produced in Germany or in Japan later, and imported in large amount by Chinese, Japanese and German merchants. Yet there also existed Korean merchants and peddlers who sold the goods to the local consumers. Dyers were male and female who belonged to the middle class. They received the orders and payments from the government or merchants. Not only did they dye textiles, threads, cotton, paper and leather, but they also redyed clothes. Indigo dyers were differentiated from other dyers. Modern dyeing manufacture, which was presumably forced to keep pace with the productivity of the weaving process, appeared in the 1900s. It was a branch of the modern weaving manufacture.

• 한국환경과학회지
• /
• 제11권6호
• /
• pp.569-576
• /
• 2002

Anaerobic/aerobic reactor system was used to treat a synthetic wastewater with glucose as carbon sources(0.38~2.29 kg COD/m3.day) and Acid Red 14(1.05 "24.00 g Acid Red 141m3.day, color degree of 570 ~ 1710). COD removal efficiency by the anaerobic stage in operation period were above 90 % organic loading rate of 0.38 ~ 2.29 kg COD/m3.day(except, adaptation period) and the removal efficiency of the whole system were above 96 %. The decolorization of the Acid Red 14 was through the alteration of the dye structure(or cleavage of the Azo bond) during the anaerobic treatment. In the A/A system, the anaerobic stage played an essential role in removing both color and COD. In addition it also improves biodegradability of dye f3r further aerobic treatment. After operation, average MLSS concentration of anaerobic sludge reactor, anaerobic fixed-bed reactor and aerobic fixed-bed reactor were 17100mg/L, 20000mg/L, and 10000mg/L, respectively.

• 한국염색가공학회지
• /
• 제15권1호
• /
• pp.23-29
• /
• 2003

Dyeings of the most widely used to the synthetic fibers, namely polyamide and polyester, have been carried out using acid dyes and disperse dyes. The above mentioned dye types, and indeed all dyes onto substrates, rely on the reaction properties between the substrates and dye molecules. In terms of fastness properties, however, especially to washings, the satisfactory levels are not present in the results from acid and disperse dyeings. Thus, vat dyeings leaves a feasibility and are an alternative way to overcome the problem. Although attempts and works have been reported in early years, with little if any commercial achievement and success. In this context, to meet increased demands towards a high level of wash fastness from consumers and retailers, an attempt using vat dyes has been carried out in this work.

• 한국염색가공학회지
• /
• 제22권2호
• /
• pp.145-154
• /
• 2010

An alkalophilic microorganism capable of degrading dyes was developed for the treatment of alkaline dye solution. This strain was identified as Pseudomonas species. Using this microorganism, biological treatment of dye was studied in Erlenmeyer flasks. The characteristics of this microorganism were observed under various incubating-condition such as temperature, pH, nitrogen source, and macronutrients concentration. The removal effciencies of Disperse Red 60 from synthetic wastewater were 33.5 ~ 36.9% at the range of $30{\sim}40^{\circ}C$, and they were 31.1 ~ 36.7% at the range of initial pH 8 ~ pH 10, respectively. The optimal culture medium was found to be 0.25%(w/v) yeast extract, 0.25%(w/v) polypeptone, 0.1%(w/v) $KH_2PO_4$, 0.2%(w/v) $MgSO_4{\cdot}7H_2O$, and 1.0%(w/v) $Na_2CO_3$. In treatment of various dyes using Erlenmeyer flasks, the removal effciencies of Disperse Blue 87, Disperse Yellow 64, Disperse Red 60, Acid Blue 193, Acid Red 138, and Direct Yellow 23 were found to be 76%, 71%, 58%, 93%, 94%, and 90% respectively after 24hrs reaction of alkalophilic strain Pseudomonas sp. YBE-12.

• Membrane and Water Treatment
• /
• 제9권1호
• /
• pp.9-15
• /
• 2018

Coagulation process using aluminum sulfate ($Al_2(SO_4)_3$) and ferric chloride ($FeCl_3$) was employed as a treatment method for decolorization of a synthetic textile wastewater containing red dye in this paper. Factors such as initial pH, coagulant dosage, initial concentration, conductivity and mixing conditions that influence color removal efficiency were experimentally tested. It was found that $Al_2(SO_4)_3$ is more efficient than $FeCl_3$ as coagulant. When $40mgL^{-1}$ aluminum sulfate was used, results showed that color induced by the red dye was efficiently removed (> 90 %) and was obtained in a large range of initial pH from 4 to 8 with, and for a dye concentration lower than $235mg\;L^{-1}$. After addition of the coagulant, the medium had to be mixed for 30 min at 60 rpm, then allowed to settle for 40 min. The effects of water conductivity in the range $0.035-2.42mS\;cm^{-1}$ and dye concentration up to $380mg\;L^{-1}$ were also followed and discussed.

• Advances in environmental research
• /
• 제9권2호
• /
• pp.135-150
• /
• 2020

Many industries, such as textiles, chemical refineries, leather, plastics and paper, use different dyes in various process steps. At the same time, these industrial sectors are responsible for discharging contaminants that are harmful and toxic to humans and microorganisms by introducing synthetic dyes into wastewater. Of these dyes, methylene blue dye, which is classified as basic dyes, is accepted as a model dye. For this reason, methylene blue dye was selected in the study and its removal from the water was studied. In this study, two efficient biosorbents were developed from chitosan and sunflower waste, an agro-industrial waste and modified using iron nanoparticles. The biosorption efficiency was evaluated for methylene blue (MB) dye removal from aqueous solution under various parameters such as treating agent, solution pH, biosorbent dosage, contact time, initial dye concentration and temperature. We investigated the kinetic properties of dye removal from water for Chitosan-Sunflower (CS), Chitosan-Sunflower-Nanoiron (CSN). When the wavelength of MB dye was spectrophotometrically scanned, the maximum absorbance was determined as 660 nm. For the core shell biosorbents we obtained, we found that the optimum time for removal of MB from wastewater was 60 min. The pH of the best pH was determined as 5 in the studied pH. The most suitable temperature for the experiment was determined as 30℃. SEM-EDAX, TEM, XRD, and FTIR techniques were used to characterize biosorbents produced and modified in the experimental stage and to monitor the change of biosorbent after dye removal. The interactions of the paint with the surface used for removal were explained by these techniques. It was calculated that 80% of CS and 88% of CSN removed MB in optimum conditions. Also, the absorption of MB dye onto the surface was investigated by Langmiur and Frendlinch isotherms and it was determined from the results that the removal was more compatible with Langmiur isotherm.

• 한국의류산업학회지
• /
• 제20권3호
• /
• pp.323-330
• /
• 2018

This study aim is to provide new coloration method by laccase-catalyzation on natural phenolic dyeing process. In this study, silk was dyed with black tea, which is one of polyphenolic dye, extracted in distilled water. The dyed samples were catalyzed by laccase as the eco-friendly mordanting process. To optimize the conditions of laccase-catalyzed coloration, conditions were varied by different mordanting methods (one-bath, two-bath), temperature and treatment time. The dye affinity in terms of the value of K/S, $L^*$, $a^*$, $b^*$, and H, V, C was measured by Computer Color Matching System (CCM, CM-2600d, Spectra Magic NX, Korea). The effect of laccase-catalyzed coloration on washing fastness was evaluated and compared with the synthetic mordant (Al, Cu, and Fe). As the result of color analysis of dyed silk, the optimum conditions of laccase-catalyzed coloration were determined to post-mordanting by one-bath at $50^{\circ}C$ for 3 hours. Under the optimum laccase-catalyzed conditions, the dyed silk was shown the color of yellowish-red. After laccase-catalyzed coloration on the dyed silk, the improvement of washing fastness was obtained compared with mordanted silk by synthetic mordant (Al, Cu, and Fe). Therefore, the present study was demonstrated that the effective enzymatic mordanting method by laccase for phenolic natural dyeing with vivid color and good fastness.