• Title/Summary/Keyword: synthetic analysis

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Study on Chemical Stabilities with R-1234yf Refrigerant of Polyol Ester Refrigerant Oil for Electric Vehicles (전기 자동차용 폴리올 에스테르계 냉동기유의 R-1234yf 냉매와의 적합성 연구)

  • Hong, J.S.;Chung, K.W.;Kim, N.K.;Shin, J.H.;Kim, Young Woon;Lee, E.H.;Go, B.S.;Hwang, S.Y.
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.139-146
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    • 2020
  • Global warming has led to an increase in demand of eco-friendly vehicles, such as electric cars, for reducing greenhouse gas emissions, and especially, regulating carbon dioxide generation. In addition, electric vehicles are equipped with an electric drive-type hermetic scroll compressor and a refrigerant, which exhibit current and future trends of using environmentally friendly refrigerants, including R-1234yf. In this study, polyol ester-based refrigeration oils are prepared via condensation esterification of polyol and fatty acids. The oils can be combined with R-1234yf refrigerant for applications in air conditioning and cooling systems of electric vehicles. The structure of synthetic polyol esters is confirmed via 1H-NMR and FT-IR spectrum analysis, and the composition of the polyol ester is analyzed via gas chromatogram analysis. Furthermore, kinematic viscosity, viscosity index, total acid value, pour point, and color are analyzed as fundamental physical properties of the synthetic polyol esters. The compatibility and chemical stability of the synthetic polyol ester combined with the R-1234yf refrigerant are obtained via high temperature and high pressure oil-resistant refrigerant tests. The changes in the oil color and catalyst activity are observed before and after the experiment to determine whether it is suitable as a refrigerator oil.

System Performance Analysis for Multi-Band SweepSAR Operating Mode (다중대역 SweepSAR 운용 모드의 시스템 성능 분석)

  • Yoon, Seong-Sik;Lee, Jae-Wook;Lee, Taek-kyung;Ryu, Sang-Burm;Lee, Hyeon-Cheol;Kang, Eun-Su;Lee, Sang-Gyu
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.3
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    • pp.186-194
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    • 2017
  • In this paper, we analyze the main performance of satellite's Synthetic Aperture Radar system for high resolution and wide swath. We have used the radiation pattern of reflector antenna with array feed and comparison between the conventional ScanSAR mode and SweepSAR mode has been carried out. The SweepSAR mode is a high-resolution wide-swath mode that transmits beams over a wide range and receives echo signals through sequential beamforming based on SCORE(SCan On REceive). In this paper, we analyzed the operating principle and characteristics of satellite's SweepSAR mode and simulate system performances. In addition, in order to increase the utilization of image, performances analysis for multiple frequency bands(C-band, X-band) has been considered.

Hydrothermal Synthesis of Smectite from Zeolite (제올라이트로부터 스멕타이트 수열 합성에 대한 연구)

  • Chae, Soo-Chun;Kim, You-Dong;Jang, Young-Nam;Bae, In-Kook;Ryu, Kyung-Won;Lee, Sung-Ki
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.301-310
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    • 2006
  • Smectites were synthesized from Na-P type and Na-A type zeolites by the hydrothermal synthetic method, and their physicochemical properties were studied. The optimal synthetic conditions for producing smectite were $290^{\circ}C$, 72 hr and $75{\sim}100kgf/cm^2$ in autogenous pressure. pHs of initial reaction solutions for the synthesis of smectites from Na-P type and Na-A type zeolite s were pH 6 and pH 10, respectively. The synthetic smectite was confirmed as $12{\AA}$-beidellite by a series of analysis such as X-ray diffraction analysis with random and oriented mounts, ethylene glycol treatment, and Greene-Kelly test, and their several physicochemical properties were studied.

Study on the Inclusion Behavior of Sulfobutylether-β-Cyclodextrin with Perphenazine by Flow Injection Chemiluminescence

  • Shen, Minxia;Lv, Hairu;Song, Zhenghua
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3199-3205
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    • 2013
  • The inclusion behavior of sulfobutylether-${\beta}$-cyclodextrin (SBE-${\beta}$-CD) with perphenazine (PPH) was first studied by flow injection (FI)-chemiluminescence (CL) analysis with proposed $lg[(I_0-I_s)/I_s]=lgK_{P-CD}+nlg[C_{PPH}]$ model and molecular docking. Results showed that a 1:1 complex of SBE-${\beta}$-CD/PPH could online form, with the formation constant $K_{P-CD}$ of $2.57{\times}10^7Lmol^{-1}$ at 298 K. The thermodynamic parameters showed that the inclusion behavior of SBE-${\beta}$-CD/PPH was a spontaneous process by hydrophobic interaction. The molecular docking results revealed PPH entered into the larger cavity of SBE-${\beta}$-CD with two hydrogen bonds. Based on the linear relationship of the decrement of luminol/SBE-${\beta}$-CD/PPH CL intensity against the logarithm of PPH concentration ranging from 0.03 to 30.0 ng $mL^{-1}$, the present FI-CL analysis using luminol/SBE-${\beta}$-CD/PPH system was successfully applied to PPH determination in biological fluids and tablets with recoveries from 94.5 to 105.6% and RSDs less than 2.6% (n = 5).

Performance Analysis of SAR System Using Radar Target Simulation Equipment (표적모의장치를 이용한 SAR 장비의 성능 분석)

  • Kweon, Soon-Koo;Yeo, Hwan-Yong;Park, Sung-Min;Han, Ji-Hoon;Jung, Chang-Sik;Kim, Ki-Wan;Shin, Hyun-Ik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.2
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    • pp.118-127
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    • 2018
  • In this work, we have designed and manufactured radar target simulation equipment for the performance analysis of synthetic aperture radar(SAR) systems. First, we have explained the function and performance specification of the target simulation equipment and point target scenario generation for validation of the SAR system. In addition, we have developed a simple and accurate calibration method for the time delay of the SAR system using the manufactured target simulation equipment. We have analyzed the point target impulse response function of the SAR image acquired using the SAR system and the target simulation equipment. It was observed that the measured peak to side lobe ratio(=-13.25 dB) and resolution(=0.49 m) are in good agreement with the corresponding theoretical values.

Generation of Antibodies Against Rice stripe virus Proteins Based on Recombinant Proteins and Synthetic Polypeptides

  • Lian, Sen;Jonson, Miranda Gilda;Cho, Won-Kyong;Choi, Hong-Soo;Je, Yeon-Ho;Kim, Kook-Hyung
    • The Plant Pathology Journal
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    • v.27 no.1
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    • pp.37-43
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    • 2011
  • Rice stripe virus (RSV) is one of serious epidemic pathogens for rice species grown in many Asian countries. Therefore, it is necessary to produce a diagnostic detection kit applicable in fields for RSV detection. In this study, RSV proteins that were derived from recombinant proteins and synthetic polypeptides as antigens were generated and were raised in rabbits for antiserum production. Among seven proteins in RSV, genes that code for NCP and NS3 proteins were cloned and subcloned into vector carrying His-tag protein and were expressed in E. coli. Of two recombinant proteins, only anti-NCP displayed stable hybridization signals in western blot analysis. Alternately, synthetic RSV polypeptides for CP, NCP, NS3 and NSvc4 we also generated and only antibodies against CP and NCP were very effective to detect RSV in both RSV infected rice and weed plants. However, antibodies against NS3 and NSvc4 showed weak specific bands as well as strong non-specific background due to the difference of viral proteins produced in the infected leaves. In summary, the antibodies generated against RSV proteins produced in this study will be useful for various assays such as for RSV diagnostic detection, immunoprecipitation, protein purification, and western blot analysis.

Evaluation of Seismic Fragility Curve of Seismically Isolated Nuclear Power Plant Structures for Artificial Synthetic Earthquakes Corresponding to Maximum-Minimum Spectrum (최대-최소 스펙트럼에 대응하는 인공합성지진에 대한 면진된 원전구조물의 지진취약도 곡선 평가)

  • Kim, Hyeon-Jeong;Song, Jong-Keol
    • Journal of the Earthquake Engineering Society of Korea
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    • v.23 no.2
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    • pp.89-99
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    • 2019
  • In order to increase the seismic safety of nuclear power plant (NPP) structures, a technique to reduce the seismic load transmitted to the NPP structure by using a seismic isolation device such as a lead-rubber bearing has recently been actively researched. In seismic design of NPP structures, three directional (two horizontal and one vertical directions) artificial synthetic earthquakes (G0 group) corresponding to the standard design spectrum are generally used. In this study, seismic analysis was performed by using three directional artificial synthetic earthquakes (M0 group) corresponding to the maximum-minimum spectrum reflecting uncertainty of incident direction of earthquake load. The design basis earthquake (DBE) and the beyond design basis earthquakes (BDBEs are equal to 150%, 167%, and 200% DBE) of G0 and M0 earthquake groups were respectively generated for 30 sets and used for the seismic analysis. The purpose of this study is to compare seismic responses and seismic fragility curves of seismically isolated NPP structures subjected to DBE and BDBE. From the seismic fragility curves, the probability of failure of the seismic isolation system when the peak ground acceleration (PGA) is 0.5 g is about 5% for the M0 earthquake group and about 3% for the G0 earthquake group.

A Study on Variable Conductance Radiator using Liquid Metal for Highly Efficient Satellite Thermal Control (인공위성의 고효율 열제어 구현을 위한 액체금속형 가변 전도율 방열판에 관한 연구)

  • Park, Gwi-Jung;Go, Ji-Seong;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • v.13 no.2
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    • pp.66-72
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    • 2019
  • The observation satellites which uses high heat-dissipating equipment such as synthetic aperture radar (SAR) satellites require a radiator to transmit heat from the equipment into outer space. However, during cold conditions it requires a heater to maintain the temperature of equipment within the allowable minimum limit when it is not in operation. In this study, we proposed a variable conductivity radiator that changes its thermal conductivity value through movement of the liquid metal between two reservoirs based on the temperature condition. This reduces the power consumption of the heater by limiting heat transfer path to the radiator in cold condition, while effectively transferring heat to the radiator during hot condition. The feasibility of the proposed radiator was validated through comparison of the thermal control performance with the conventional fixed conductivity radiator via a thermal analysis.

Quantitative Analysis by Derivative Spectrophotometry (III) -Simultaneous quantitation of vitamin B group and vitamin C in by multiple linear regression analysis-

  • Park, Man-Ki;Cho, Jung-Hwan
    • Archives of Pharmacal Research
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    • v.11 no.1
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    • pp.45-51
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    • 1988
  • The feature of resolution enhancement by derivative operation is linked to one of the multivariate analysis, which is multiple linear regression with two options, all possible and stepwise regression. Examined samples were synthetic mixtures of 5 vitamins, thiamine mononitrate, riboflavin phosphate, nicotinamide, pyridoxine hydrochloride and ascorbic acid. All components in mixture were quantified with reasonably good accuracy and precision. Whole data processing procedure was accomplished on-line by the development of three computer programs written in APPLESOFT BASIC language.

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Efficient Synthetic Method of Z-Selective 2-Halo-1,3-dienes from Reactions of Allenols Possessing Ethoxycarbonyl and Vinyl Group with Indium Trihalide

  • Eom, Da-Han;Kim, Sung-Hong;Lee, Phil-Ho
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.645-649
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    • 2010
  • An efficient synthetic method of Z-selective 3-ethoxycarbonyl-2-halo-1,3-dienes and 3-vinyl-2-halo-1,3-dienes was developed from the reaction of allenols having ethoxycarbonyl and vinyl group with indium trihalides at room temperature in $CH_2Cl_2$.