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http://dx.doi.org/10.5012/bkcs.2010.31.03.645

Efficient Synthetic Method of Z-Selective 2-Halo-1,3-dienes from Reactions of Allenols Possessing Ethoxycarbonyl and Vinyl Group with Indium Trihalide  

Eom, Da-Han (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University)
Kim, Sung-Hong (Analysis Research Division Daegu Center, Korea Basic Science Institute)
Lee, Phil-Ho (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.3, 2010 , pp. 645-649 More about this Journal
Abstract
An efficient synthetic method of Z-selective 3-ethoxycarbonyl-2-halo-1,3-dienes and 3-vinyl-2-halo-1,3-dienes was developed from the reaction of allenols having ethoxycarbonyl and vinyl group with indium trihalides at room temperature in $CH_2Cl_2$.
Keywords
Allenol; 2-Halo-1,3-diene; Indium trihalide; Selectivity;
Citations & Related Records
Times Cited By KSCI : 4  (Citation Analysis)
Times Cited By Web Of Science : 2  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
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