• Title/Summary/Keyword: synthesis gas

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Trends in Reports on Climate Change in 2009-2011 in the Korean Press Based on Daily Newspapers' Ownership Structure

  • Lee, Jihye;Hong, Yeon-Pyo;Kim, Hyunsook;Hong, Youngtak;Lee, Weonyoung
    • Journal of Preventive Medicine and Public Health
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    • v.46 no.2
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    • pp.105-110
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    • 2013
  • Objectives: The mass media play a crucial role in risk communication regarding climate change. The aim of this study was to investigate the trend in journalistic reports on climate change in the daily newspapers of Korea. Methods: We selected 9 daily newspapers in Korea, which according to the ABC Association, represented 77% of newspaper circulation, out of a total of 44 Korean daily newspapers. The collected articles were from 2009 to 2011. All of the articles were sorted into the following 8 categories: greenhouse gas, climate change conventions, sea level rise, Intergovernmental Panel on Climate Change synthesis reports, expected damage and effect, use of fossil fuels, global warming, and mitigation or adaptation. A chi-squared test was done on the articles, which were counted and classified into cause, effect, and measurement of climate change according to the newspaper's majority or minority ownership structure. Results: From the 9 selected newspapers, the number of articles on climate change by month was greatest in December 2009. Generally, the articles vague about climate change (lack of precise data, negative or skeptical tone, and improper use of terminology) were much more common than the articles presenting accurate knowledge. A statistical difference was found based on ownership structure: the majority-owned newspapers addressed the cause of climate change, while the minority-owned newspapers referred more to climate change measurement. Conclusions: Our investigation revealed that generally Korean daily newspapers did not deliver accurate information about climate change. The coverage of the newspapers showed significant differences according to the ownership structure.

Hypoglycemic Effect of Mulberry Leaves with Anaerobic Treatment in Alloxan-induced Diabetic Mice (혐기처리한 뽕잎의 혈당강하 효과)

  • Ryu, Kang-Sun;Lee, Won-Chu;Ku, Hyun-Ok;Lee, Hoi-Seon;Lee, Kang-Ro;Kim, Sun-Yeou
    • Korean Journal of Pharmacognosy
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    • v.30 no.2
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    • pp.123-129
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    • 1999
  • The hypoglycemic effect of mulberry leaves using alloxan-induced diabetic mice was investigated. The hypoglycemic effect of mulberry leaves was significantly affected with anaerobic incubation up to for 6 hrs. The body weight of mice treated with 20% anaerobic conditioned mulberry leaves was higher than that in the control group. Mulberry leaves which were treated with anaerobic condition significantly decreased blood glucose level in alloxan-induced type I diabetes mice. Furthermore, glucose tolerance was significantly recovered by feeding mulberry leaves anaerobically treated. Pathological analysis revealed that the disappearance of insulin-secreting beta-cells in the islets of Langerhans from the alloxan induced diabetic mice was strongly inhibited in the mulberry leaves feeding group. The content of 1-deoxynojirimycin increased up to 5% in detached mulberry leaves incubated under nitrogen gas for 6 hrs. Nevertheless, it is not clear whether the synthesis of 1-deoxynojirimycin is increased or the degradation of it is decreased. Overall, results obtained from this study indicate that the hypoglycemic effect was increased by the mulberry leaves with anaerobic treatment.

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Synthesis and Surface Characterization of Carbon Nanotubes by Hot-Filament Plasma Enhanced Chemical Vapor Deposition (Hot-filament 화학기상 증착법에 의한 탄소나노튜브의 성장 및 표면 특성)

  • Choi, Eun-Chang;Kim, Jung-Tae;Park, Yong-Seob;Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Vacuum Society
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    • v.16 no.3
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    • pp.187-191
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    • 2007
  • In this paper, the catalyst layer is deposited on silicon substrate using magnetron sputtering system and carbon nanotubes(CNTs) were grown in $NH_3\;and\; C_2H_2$ gas by hot-filament plasma enhanced chemical vapor deposition (HFPECVD) system. A growth temperature of carbon nanotubes was changed from $350^{\circ}C\;to\;650^{\circ}C\;by\;100^{\circ}C$. We observed the shape of CNTs by a field-emission scanning electron microscope(FE-SEM) measurement and analyzed the surface characteristic of CNTs layer by contact angle measurement. That is, the growth temperature of CNTs is the important factor leads to the variation of the properties.

Electrodeposition of Silicon in Ionic Liquid of [bmpy]$Tf_2N$

  • Park, Je-Sik;Lee, Cheol-Gyeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.30.1-30.1
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    • 2011
  • Silicon is one of useful materials in various industry such as semiconductor, solar cell, and secondary battery. The metallic silicon produces generally melting process for ingot type or chemical vapor deposition (CVD) for thin film type. However, these methods have disadvantages of high cost, complicated process, and consumption of much energy. Electrodeposition has been known as a powerful synthesis method for obtaining metallic species by relatively simple operation with current and voltage control. Unfortunately, the electrodeposition of the silicon is impossible in aqueous electrolyte solution due to its low oxidation-reduction equilibrium potential. Ionic liquids are simply defined as ionic melts with a melting point below $100^{\circ}C$. Characteristics of the ionic liquids are high ionic conductivities, low vapour pressures, chemical stability, and wide electrochemical windows. The ionic liquids enable the electrochemically active elements, such as silicon, titanium, and aluminum, to be reduced to their metallic states without vigorous hydrogen gas evolution. In this study, the electrodeposion of silicon has been investigated in ionic liquid of 1-butyl-3-methylpyrolidinium bis (trifluoromethylsulfonyl) imide ([bmpy]$Tf_2N$) saturated with $SiCl_4$ at room temperature. Also, the effect of electrode materials on the electrodeposition and morphological characteristics of the silicon electrodeposited were analyzed The silicon electrodeposited on gold substrate was composed of the metallic Si with single crystalline size between 100~200nm. The silicon content by XPS analysis was detected in 31.3 wt% and the others were oxygen, gold, and carbon. The oxygen was detected much in edge area of th electrode due to $SiO_2$ from a partial oxidation of the metallic Si.

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Design of Turbulent In-situ Mixing Mixer and Fabrication of Cu-TiB2 Nanocomposities (난류 용탕 In-situ 합성 믹서의 설계 및 Cu-TiB2 나노 복합재료의 제조)

  • Choi, Baek-Boo;Park, Jung-Su;Yun, Ji-Hun;Ha, Man-Young;Park, Yong-Ho;Park, Ik-Min
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.11-17
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    • 2007
  • Turbulent in-situ mixing process is a new material process technology to get dispersed phase in nanometer size by controlling reaction of liquid/solid, liquid/gas, flow ana solidification speed simultaneously. In this study, mixing which is the key technology to this synthesis method was studied by computational fluid dynamics. For the simulation of mixing of liquid metal, static mixers investigated. Two inlets for different liquid metal meet ana merge like 'Y' shape tube having various shapes and radios of curve. The performance of mixer was evaluated with quantitative analysis with coefficient of variance of mass fraction. Also, detailed plots of intersection were presented to understand effect of mixer shape on mixing. The simulations show that the Reynolds number (Re) is the important factor to mixing and dispersion of $TiB_2$ particles. Mixer was designed according to the simulation, and $Cu-TiB_2$ nano composites were evaluated. $TiB_2$ nano particles were uniformly dispersed when Re was 1000, and cluster formation and reduction in volume fraction of $TiB_2$ were found at higher Re.

Synthesis of TiN-Coated cBN Powder by Sol-Gel Method Using Titanium (IV) Isopropoxide (티타늄 이소프로폭사이드를 이용한 졸-겔법에 의한 TiN 코팅 cBN 분말 합성)

  • Lee, Youn Seong;Kim, Sun Woog;Lee, Young Jin;Lee, Ji Sun;Shin, Dongwook;Kim, Sae-Hoon;Kim, Jin Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.373-379
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    • 2020
  • In this study, TiN-coated cBN (cubic-structure boron nitride) powders were successfully synthesized by a sol-gel method using titanium (IV) isopropoxide (TTIP) and by controlling the heat treatment conditions. After the sol-gel process, amorphous nano-sized TiOx was uniformly coated on the surface of cBN powder particles. The obtained TiOx-coated cBN powders were heated at 1,000~1,300℃ for 1 or 6 h in a flow of 95%N2-5%H2 mixed gas. With increasing temperature, the chemical composition of the TiOx coating layer changed in the order of TiO2→Ti6O11→Ti4O7→TiN due to reduction of the Ti ions. The TiN coating layer was observable in the samples heated at 1,200℃ and appeared as the main phase in the sample heated at 1,300℃. The resulting thickness of the TiN coating layer of the sample heated at 1,300℃ was approximately 45~50 nm.

Physical Properties and Sulfur Absorption Capacity of Spray-dried Solid Sorbents for Desulfurization of Syngas (합성가스 중 $H_2S$ 정제용 탈황제의 물성 및 반응특성)

  • Baek, Jeom-In;Lee, Joong-Beom;Kim, Ji-Woong;Eom, Tae-Hyoung;Ryu, Jeong-Ho;Jeon, Won-Sik;Ryu, Chong-Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.880-883
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    • 2009
  • 석탄가스화복합발전(IGCC) 시스템에서 합성가스 중에 포함된 황화수소($H_2S$)는 후단의 가스 터빈과 같은 장치의 부식을 방지하고, 합성가스를 이용하는 연료전지 등의 연계 공정에서 요구하는 수준에 맞추어 정제되어야 한다. 본 연구에서는 $H_2S$ 정제공정 추가에 따른 IGCC 시스템의 효율저하를 최소화하기 위하여 고온고압에서 사용가능한 탈황제를 분무건조법을 이용하여 제조하고 제조된 탈황제에 대해 물성 및 황 흡수능 시험을 실시하였다. 형상, 내마모도, 평균입자크기, 충진밀도와 함께 제조된 탈황제가 적용되는 유동층 공정에 적합한 강도를 보유하는지 여부를 미국표준시험방법에 의하여 측정하였다. 황 흡수능은 열중량분석기를 반응기로 사용하여 모사 합성 가스 분위기에서 측정하였다. 분무건조 성형된 탈황제의 일부가 구형이 아닌 타원형 또는 도넛 형태를 나타내고 있어 형상 개선을 위한 제조방법 개선이 필요한 것으로 나타났다. 제조된 탈황제는 기공도가 65% 이상으로 macropore가 기공부피의 대부분을, mesopore가 비표면적의 대부분을 제공하고 있었다. 소성온도를 650 $^{\circ}C$에서 750 $^{\circ}C$로 증가시킴에 따라 대체로 강도가 감소하는 경향을 나타내었다. 열중량분석기로 측정된 황 흡수능은 약 10 wt%로 나타났다. 제조된 탈황제 중 일부는 유동층 공정에 적합한 물성을 보유하고 있었으며 반응성 또한 기존에 개발된 탈황제에 버금가는 성능을 나타내어 향후 공정 적용이 가능할 것으로 분석되었다.

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Synthesis of CNT on a Camphene Impregnated Titanium Porous Body by Thermal Chemical Vapor Deposition (티타늄 다공체에 담지된 Camphene과 화학기상증착법을 이용한 CNT 합성)

  • Kim, Hogyu;Choi, Hye Rim;Byun, Jong Min;Suk, Myung-Jin;Oh, Sung-Tag;Kim, Young Do
    • Journal of Powder Materials
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    • v.22 no.2
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    • pp.122-128
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    • 2015
  • In this study, titanium(Ti) meshes and porous bodies are employed to synthesize carbon nanotubes(CNTs) using methane($CH_4$) gas and camphene solution, respectively, by chemical vapor deposition. Camphene is impregnated into Ti porous bodies prior to heating in a furnace. Various microscopic and spectroscopic techniques are utilized to analyze CNTs. It is found that CNTs are more densely and homogeneously populated on the camphene impregnated Ti-porous bodies as compared to CNTs synthesized with methane on Ti-porous bodies. It is elucidated that, when synthesized with methane, few CNTs are formed inside of Ti porous bodies due to methane supply limited by internal structures of Ti porous bodies. Ti-meshes and porous bodies are found to be multi-walled with high degree of structural disorders. These CNTs are expected to be utilized as catalyst supports in catalytic filters and purification systems.

Application of Enzymatic method to Determine Choline Concentration in Bovine Blood and Muscle (소의 혈액 및 근육 중 choline 농도 분석을 위한 효소측정법의 적용기법의 개발)

  • Kim, Young-Il;Jung, Won-Chul;Shon, Ho-Yeong;Kim, Suk;Hur, Yoen;Lee, Hu-Jang
    • Journal of Food Hygiene and Safety
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    • v.23 no.3
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    • pp.271-275
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    • 2008
  • Choline is important an organic compound for normal membrane function, acetylcholine synthesis, lipid transport, and methyl metabolism. In biological tissues and foods, there are multiple choline compounds that contribute to choline content. There are so many analytical methods for choline determination, such as radioisotopic, high-performance liquid chromatography, and gas chromatography/mass spectrometry. However, these existing methods are expensive, unmanageable, and time-consuming. In this study, we modified enzymatic method, which is applicable for the determination of choline in milk and infant formulas, and applied to bovine serum and muscle. The calibration curves were linear with higher correlation coefficients than 0.994. Recoveries obtained by calibration curves from the spiked bovine serum and muscle samples varied between 70.6 and 85.2%. The method may be suitable for use as a routine method in the determination of choline for biological tissue and food samples.

Purification and Characterization of Anabaena flos-aquae Phenylalanine Ammonia-Lyase as a Novel Approach for Myristicin Biotransformation

  • Arafa, Asmaa M.;Abdel-Ghany, Afaf E.;El-Dahmy, Samih I.;Abdelaziz, Sahar;El-Ayouty, Yassin;El-Sayed, Ashraf S.A.
    • Journal of Microbiology and Biotechnology
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    • v.30 no.4
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    • pp.622-632
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    • 2020
  • Phenylalanine ammonia-lyase (PAL) catalyzes the reversible deamination of phenylalanine to cinnamic acid and ammonia. Algae have been considered as biofactories for PAL production, however, biochemical characterization of PAL and its potency for myristicin biotransformation into MMDA (3-methoxy-4, 5-methylenedioxyamphetamine) has not been studied yet. Thus, PAL from Anabaena flos-aquae and Spirulina platensis has been purified, comparatively characterized and its affinity to transform myristicin was assessed. The specific activity of purified PAL from S. platensis (73.9 μmol/mg/min) and A. flos-aquae (30.5 μmol/mg/min) was increased by about 2.9 and 2.4 folds by gel-filtration comparing to their corresponding crude enzymes. Under denaturing-PAGE, a single proteineous band with a molecular mass of 64 kDa appeared for A. flos-aquae and S. platensis PAL. The biochemical properties of the purified PAL from both algal isolates were determined comparatively. The optimum temperature of S. platensis and A. flos-aquae PAL for forward or reverse activity was reported at 30℃, while the optimum pH for PAL enzyme isolated from A. flos-aquae was 8.9 for forward and reverse activities, and S. platensis PAL had maximum activities at pH 8.9 and 8 for forward and reverse reactions, respectively. Luckily, the purified PALs have the affinity to hydroaminate the myristicin to MMDA successfully in one step. Furthermore, a successful method for synthesis of MMDA from myristicin in two steps was also established. Gas chromatography-mass spectrometry (GC-MS) analysis was conducted to track the product formation.