• Korean Journal of Chemical Engineering
• /
• v.35 no.11
• /
• pp.2290-2295
• /
• 2018

An acceleration stress test (AST) was performed to evaluate the durability of a polymer membrane in a polymer electrolyte membrane fuel cell (PEMFC) for 500 hours. Previous studies have shown that hydrogen crossover measured by linear sweep voltammetry (LSV) increases when the polymer membrane deteriorates in the AST process. On the other hand, hydrogen crossover of the membrane often decreases in the early stages of the AST test. To investigate the cause of this phenomenon, we analyzed the MEA operated for 50 hours using the AST method (OCV, RH 30% and $90^{\circ}C$). Cyclic voltammetry and transmission electron showed that the electrochemical surface area (ECSA) decreased due to the growth of electrode catalyst particles and that the hydrogen crossover current density measured by LSV could be reduced. Fourier transform infrared spectroscopy and thermogravimetric/differential thermal analysis showed that -S-O-S- crosslinking occurred in the polymer after the 50 hour AST. Gas chromatography showed that the hydrogen permeability was decreased by -S-O-S- crosslinking. The reduction of the hydrogen crossover current density measured by LSV in the early stages of AST could be caused by both reduction of the electrochemical surface area of the electrode catalyst and -S-O-S- crosslinking.

• The Transactions of the Korean Institute of Electrical Engineers A
• /
• v.51 no.1
• /
• pp.15-22
• /
• 2002

This paper proposes a new power flow method for distribution system analysis by modifying the conventional back/forward sweep method using symmetrical components. Since the proposed method backward and forward sweeps with the variables expressed by symmetrical components, this method reduces computation time for matrix calculations; therefore, it is able to reduce the computational burden for real-time distribution network analysis. The proposed method was also developed to effectively analyze the unbalanced distribution system installing AVR(Auto Voltage Regulator), shunt capacitors. The proposed algorithm was compared with the conventional Back/forward Sweep method by applying both methods to three phase unbalanced distribution system of IEEE 123-bus model, and the test results showed that the proposed method would outperformed the conventional method in real-time distribution system analysis.

• Nuclear Engineering and Technology
• /
• v.35 no.2
• /
• pp.91-107
• /
• 2003

Since DBA(Design Basis Accidents) has been studied rather separately from SA(Severe Accidents) in the conventional nuclear reactor safety analysis, the thermal hydraulics during transition between DBA and SA has not been identified so much as each accident itself. Thus, in this study, the thermal hydraulic behavior from DBA to the commencement of SA has been experimentally and analytically investigated for the long-term cooling phase of LB-LOCA(Large-Break Loss-of-Coolant Accident). Experiments were conducted for both cases of the loop seal open and closed in an integral test loop, named as SNUF (Seoul National University Facility), which was scaled down to l/6.4 in length and 1/178 in area of the APR1400 (Advanced Power Reactor 1400MWe). The core mixture level was a main measured value since it took major role in the fuel heat-up rate, the location of fuel melting initiation and the channel blockage by melting material during SA. Experimental results were compared to MAAP4.03 to assess its model of calculating the core mixture level. MAAP4.03 overestimates the core two- phase mixture level because sweep-out and spill-over and the measures to simulate the status of loop seal are not included, which is against the conservatism. Thus, it is recommended that MAAP4.03 should be improved to simulate the thermal hydraulic phenomena, such as sweep-out, spill-over and the status of loop seal.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.4
• /
• pp.2436-2441
• /
• 2015

BSR noise from automobiles is largely issued in recent as an emotional quality. This study describes the two test methods for determining BSR noise occurred in automotive seat system. First, the sine sweep test is found to be an effective excitation method for determining BSR noise with high frequency. Second, BSR operation test is introduced in such a way that BSR noise during operation of seat height system is measured by several accelerometer at each 800 cycles until 6400 cycles. The periodic noise signal is captured during one cycle after many cycles of operation. Two test method presented in this paper can be analyzed more efficiently BSR noise of the seat.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2004.10a
• /
• pp.839-840
• /
• 2004

• 제어로봇시스템학회:학술대회논문집
• /
• 1996.10b
• /
• pp.1384-1387
• /
• 1996

SCPI(Standard Commands for Programmable Instrument) is a standard command sets designed for controlling various types of instruments. In order to control FFT(Fast Fourier Transform) analyzing device using SCPI it is required to support sweep measurement function. We defined SCPI command set for FFT analysis and developed parser of defined command set using lex(Lexical Analyzer Generator) and yacc(Yet Another Compiler Compiler). After developing FFT analyzing test was performed with that parser. Up to audible signal frequency the result of FFT analysis was accurate and that result was agree with that of conventional FFT analyzer. As a result it is proved that various types of instruments including sweep measurement instrument can be controlled with appropriate SCPI command sets. Also when developing new instruments the method used in this experiment will contribute to reducing the time required to develop the SCPI parser and increasing reliability.

• Journal of Mechanical Science and Technology
• /
• v.18 no.3
• /
• pp.347-356
• /
• 2004

The flexural vibration characteristics of a sandwich beam system with a partially inserted viscoelastic layer were quantitatively studied using the finite element analysis in combination with the sine-sweep experiment. Asymmetric mode shapes of the flexural vibration were visualized by holographic interferometry, which agreed with those obtained by the finite element simulation. Effects of the length and the thickness of the partial viscoelastic layer on the system loss factor (η$\_$s/) and resonant frequency (f$\_$r/) were significantly large for both the symmetric and asymmetric modes of the beam system.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.27 no.8
• /
• pp.30-35
• /
• 2013

This paper describes the assessment method of deterioration condition for a power transformer using SFRA. Frequency Response Analysis(FRA) is a method to evaluate the mechanical and geometrical integrity of the core and windings within a power transformer by measuring the electrical transfer functions over a wide frequency range. SFRA is sweep frequency response analyzer for power transformer winding diagnosis. The FRA is a comparative method, that evaluates the transformer condition by comparing the obtained set of FRA results to reference results on the same, or a similar, unit. FRA techniques were widely used and much more sensitive than the traditional and internationally accepted method of impedance measurements, but that work was required on standardization and interpretation. In order to analyze the deterioration condition for power transformer, overvoltage test and mechanical distortion test were carried out. The deterioration condition for power transformer was evaluated by SFRA. It is intended to present the elemental technology of assessment method for power transformer using SFRA.

• Elastomers and Composites
• /
• v.51 no.1
• /
• pp.24-30
• /
• 2016

Sole in the footwear usually modified with foaming agent on the polymer resin to improve the lightweightness and crush-cushion effect. In this study, we investigated rheological properties for polymer resin filled with the different type and concentration of foaming agent, capsule type foaming agent and organo-chemical foaming agent, under the time sweep test. Curing times of each polymer resin with different kind of foaming agent are delayed than reference material (epoxy resin with curing agent). In case of adding capsule type foaming agent, however, there is appropriate concentration to reduce the curing time, relatively. When foaming agent is activated, foaming force inflates the sample in contrast to condensation force of curing and then axial normal force develop to the (+) direction. Interestingly, by increase concentration of foaming agent, there is a specific point to break down the axial normal force development. The reason for this phenomenon is that coalescence of foams induce the blocking of axial normal force development.

• Elastomers and Composites
• /
• v.54 no.3
• /
• pp.225-231
• /
• 2019

Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.