• 제목/요약/키워드: surface-modified

검색결과 3,044건 처리시간 0.029초

표면개질 담체를 이용한 충전탑 반응기에서 유기물 제거 및 미생물 부착 특성 (Characteristics of Organic Compounds Removal and Microbe Attachment in Packed Bed Column Reactor Using Surface-modified Media)

  • 선용호
    • KSBB Journal
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    • 제27권3호
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    • pp.145-150
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    • 2012
  • This study was accomplished using packed bed column reactors that contain nonsurface-modified polypropylene media and surface-modified media from hydrophobic surface property into hydrophilic property by ion beam irradiation. The objectives of this research was investigated the characteristics of organic compounds removal and microbe attachment from sewage of school cafeteria in these reactors. In 736.8 mg/L of the average inflow $COD_{Cr}$ concentration the reactors with and without surface modification showed 81.8% and 70.3% of average $COD_{Cr}$ removal efficiencies, respectively, which proves the $COD_{Cr}$ removal efficiency of surface-modified media reactor is higher than that of nonsurface-modified media reactor. After 90 days, there were maximum differences between modified system and non-modified system. In that time the maximum removal efficiency of $COD_{Cr}$ was 96.5% in modified system and was 85.2% in non-modified system that showed removal efficiency of surface-modified media system is 11.3% higher than that of nonsurface-modified media system. The average removal efficiency of SS was 80.4% for the surface modified system and 61.6% for the non-modified system under same condition. Also, the reactor of surface-modified media has advantage on microbe attachment and biofilm formation.

활성탄의 표면 구조 변화에 따른 흡착 특성 연구 (Adsorption properties of surface - modified activated carbon)

  • 김정렬;서문원;신창호;김영호;이근회;지상운
    • 한국연초학회지
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    • 제16권2호
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    • pp.191-197
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    • 1994
  • Relationships between surface structure and adsorption properties of smoke components were investigated in surface-modified and un-modified activated carbon filter cigarettes. Commercially available activated carbon was treated with nitric acid and hydrogen peroxide as oxidant, and their pore volume, surface structure, BET surface area, pore type and size were studied. BET surface area and pore volume were decreased by nitric acid treatment, but median pore diameter was 8.1 $\AA$, which showed better development of pore compared with that of un-modified activated carbon, 6.9 $\AA$. In case of hydrogen peroxide treatment, BET surface area and pore volume were increased. Their pore was found to be a slit type based on V-t plot analysis. Neutralization capacities for bases of different strength (NaHCO3, Na2CO3, NaOEt and NaOH) showed that the majority of the acidic surface groups are of weak acidity. Modification of the activated carbon surface led to a slight change in adsorption properties when analyzing the smoke of triple-filter cigarette with surface-modified activated carbon.

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국부 표면개질된 알루미늄 합금 판재의 성형성 (Formability of Locally Surface-Modified Aluminum Alloy Sheets)

  • 이창길;김성준;이태호;박신상;한흥남
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 추계학술대회 논문집
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    • pp.299-300
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    • 2005
  • Surface friction welding (SFW) is a newly developed technology fur joining thin metal sheets, which utilizes friction between tool and weldment. In the present study, the 5052 and 1050 Al sheets were locally surface-modified using SFW technology. Formability of the locally surface-modified sheets was superior to that of the parent material. Yield or tensile strengths of the locally surface-modified specimens were lower then those of the parent material, but elongations of the locally surface-modified specimens were higher then that of the parent material.

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Quantitative Analysis of Growth of Cells on Physicochemically Modified Surfaces

  • Chandra, Prakash;Kim, Jihee;Rhee, Seog Woo
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.524-530
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    • 2013
  • In this study, we describe the most expected behavior of cells on the modified surface and the correlation between the modified substrates and the response of cells. The physicochemical characteristics of substrates played an essential role in the adhesion and proliferation of cells. Glass and polymer substrates were modified using air plasma oxidation, and the surfaces were coated with self-assembled monolayer molecules of silanes. The PDMS substrates embedded with parallel micropatterns were used for evaluation of the effect of topologically modified substrate on cellular behaviour. BALB/3T3 fibroblast cells were cultured on different surfaces with distinct wettability and topology, and the growth rates and morphological change of cells were analyzed. Finally, we found the optimum conditions for the adhesion and proliferation of cells on the modified surface. This study will provide insight into the cell-surface interaction and contribute to tissue engineering applications.

라텍스개질 콘크리트 종류에 따른 표면 박리 저항 특성 (Surface Scaling Resistance of Latex-Modified Concretes)

  • 이훈재;김성환;홍창우;윤경구
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.757-762
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    • 2002
  • This study focused on the investigation of durability of latex modified concrete in the points of surface scaling resistance as cement types variated and latex content variated such as 5%, 10%, 15%, and 20%. An increasing the amount of latex produced concrete with increased flexural strength, but with slightly lower compressive strength. The increase in flexural strength might be attributed to the latex films between the hydrated cement and aggregates, and the decrease in compressive strength to the flexibility of the latex component named by Butadiene. The surface scaling resistance test was used to evaluate the durability of latex-modified concretes and rapid setting latex-modified concretes. The surface scaling resistance of LMC was quite good comparing to conventional concrete. Further, surface scaling resistance of RSLMC was improved with increasing the latex content.

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산성음료가 치아색 수복재의 표면에 미치는 영향 (The effect of acidic drinks on the surface of tooth-colored restorative materials)

  • 방석윤;김은정;김현정;남순현;김영진
    • 대한소아치과학회지
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    • 제33권3호
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    • pp.469-481
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    • 2006
  • 법랑질 침식의 병인 중에서 식이습관은 많은 관심을 받아왔고 특히 산성음료의 음용이 많은 주의를 끌어왔다. 산성음료의 급속한 소비량 증가는 치아뿐만 아니라 치아색 수복재료의 표면에도 많은 영향을 미칠 것으로 생각된다. 따라서 본 연구는 어린이들이 비교적 일상적으로 접하는 산성음료 중 가장 보편화된 3종을 선택하여 치아색 수복재료의 노출시간에 따른 표면의 변화를 조사할 목적으로 시행되었다. Resin-modified glass-ionomer, polyacid-modified composite resin, composite resin을 0.9% NaCl, 콜라, 오렌지 쥬스, 스포츠 음료의 각 4개 군으로 나누어 저장하였다. 저장 전과 저장 후 1일, 1-,2-,3-,4-주에 표면강도 및 표면조도를 측정하였고 다음과 같은 결론을 얻었다. 1. 산성음료에 저장했을 경우 composite resin을 제외한 치아색 수복재들은 통계학적으로 유의한 표면강도와 표면조도의 변화를 보였다(p<0.05). 2. 표면강도 및 표면조도의 변화는 resin-modified glass-ionomer, polyacid-modified composite resin composite resin 순으로 크게 나타났다. 3. 콜라나 오렌지 쥬스보다 스포츠 음료에서 표면변화는 더 크게 나타났다. 4. 산성음료에 저장한 군의 SEM 촬영에서 resin-modified glass-ionomer, polyacid-modified composite resin의 경우 충전제의 상실이 관찰되었으며 특히 resin-modified glass-ionomer의 경우 심한 균열이 관찰되었다.

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Surface properties and interception behaviors of GO-TiO2 modified PVDF hollow fiber membrane

  • Li, Dongmei;Liang, Jinling;Huang, Mingzhu;Huang, Jun;Feng, Li;Li, Shaoxiu;Zhan, Yongshi
    • Membrane and Water Treatment
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    • 제10권2호
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    • pp.113-120
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    • 2019
  • To investigate surface properties and interception performances of the new modified PVDF membrane coated with Graphene Oxide (GO) and nano-$TiO_2$ (for short the modified membrane) via the interface polymerization method combined with the pumping suction filtration way, filtration experiments of the modified membrane on Humic Acid (HA) were conducted. Results showed that the contact angle (characterizing the hydrophilicity) of the modified membrane decreased from $80.6{\pm}1.8^{\circ}$ to $38.6{\pm}1.2^{\circ}$. The F element of PVDF membrane surface decreased from 60.91% to 17.79% after covered with GO and $TiO_2$. O/C element mass ratio has a fivefold increase, the percentage of O element on the modified membrane surface increased from 3.83 wt% to 20.87%. The modified membrane surface was packed with hydrophilic polar groups (like -COOH, -OH, C-O, C=O, N-H) and a functional hydrophilic GO-polyamide-$TiO_2$ composite configuration. This configuration provided a rigid network structure for the firm attachment of GO and $TiO_2$ on the surface of the membrane and for a higher flux as well. The total flux attenuation rate of the modified membrane decreased to 35.6% while 51.2% for the original one. The irreversible attenuation rate has dropped 71%. The static interception amount of HA on the modified membrane was $158.6mg/m^2$, a half of that of the original one ($295.0mg/m^2$). The flux recovery rate was increased by 50%. The interception rate of the modified membrane on HA increased by 12% approximately and its filtration cycle was 2-3 times of that of the original membrane.

Fabrication of Large-Area Photovoltaic Crystal with Modified Surface Using Trimethoxysilyl Propyl Methacrylate (TMSPM) for Solar Cell Protection

  • Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • 제2권3호
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    • pp.84-87
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    • 2014
  • Protection of solar cell surface is important to prevent from dust, pollen, sand, etc. Therefore, development of large area antifouling film is urgent for high performance of solar cells. The surface of silica spheres was modified to fabricate large area antifouling film. The surface of monodisperse silica spheres has been modified with 3-(trimethoxysilyl) propylmethacrylate (TMSPM) to fabricate large area photonic crystal. Although the surface modification of silica spheres with TMSPM has been failed for the base catalyst, the second trial using acid catalyst showed the following results. The FTIR absorption peak at $1721cm^{-1}$ representing C=O stretching vibration indicates that the TMSPM was attached on the surface of silica spheres. The methanol solution comprised of the surface modified silica spheres (average diameter of 380 nm) and a photoinitiator was poured in the patterned silicon wafer with the dimension of 10 cm x 10 cm and irradiated UV-light during the self-assembly process. The result showed large area crack and defect free nanostructures.

소수성 알루미나막의 증가투과에 의한 에탄올의 분리 (Separation of ethanol/water mixtures with hydrophobic alumina membrane in vapor permeation)

  • 이상인;송근호;이광래
    • 산업기술연구
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    • 제20권A호
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    • pp.179-184
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    • 2000
  • The surface of porous alumina membrane was modified with silane coupling agent in order to enhance hydrophobicity. The contact angle of water to the surface-modified alumina membrane was greater than $90^{\circ}$. The surface-modified membrane was tested in vapor permeation for the concentration of aqueous ethanol. With the increase of ethanol concentration in the feed, permeation flux increased due to the greater affinity of ethanol with surface-modified alumina membrane than that of water. The experimental results showed that the permeation rate of surface-modified alumina membrane was 15~1000 times greater than that of polymer membranes.

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표면 개질된 도공안료가 도공지의 특성에 미치는 영향 (The Effects of Surface-Modified Pigment on the Properties of Coated Paper)

  • 이희명;민동진;이용규;조준형;김용식
    • 펄프종이기술
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    • 제35권3호
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    • pp.13-20
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    • 2003
  • This study was carried out to investigate the effect of surface modified pigments on the properties of coated paper. The selected core particle(clay, talc) and fine particle(TiO$_2$) were modified by hybridization. The optical properties of modified pigments, rheological properties of coating color, and optical properties of coated paper were investigated. It was found that particles formed sphere-like shape and became more uniform during the surface modification in the hybridization system. As a result, It was estimated that surface modification of TiO$_2$ turned out to be more effective in improving optical properties of pigment and coated paper than simply blending it.