• Title/Summary/Keyword: surface treatment material

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Production of Activated Carbon from Woody Fishing Port Wastes Using Sulfuric Acid as Activating Agent (목질(木質) 어항(漁港) 폐기물(廢棄物)을 원료(原料)로 한 황산(黃酸)에 의한 활성탄(活性炭) 제조(製造))

  • Kim, Dong-Su;Lee, Jung-Eun
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.50-57
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    • 2006
  • Production of activated carbon from woody fish parking cases has been studied using waste sulfuric acid as an activating agent for the purpose or promoted recycling of woody fishing port wastes. The adsorption capacity of produced activated carbon was observed to increase with activation temperature and reached its maximum at ca. $650^{\circ}C$ under the experimental conditions. However, the adsorption capacity of activated carbon became deteriorated above this temperature due to the thermal degeneration of its structure. Optimal activation time was found to be about 120 minutes and 1:3 weight ratio of raw material and activating agent was appropriate for increased adsorption capacity of activated carbon under the conditions of $550^{\circ}C$ and 60 minutes of activation time. Regarding the effect of the concentration of activating agent on activation, ca. 1.2 M of sulfuric acid was observed to be proper for an optimal activation or raw material. Comparison of the activation power of sulfuric acid with nitric acid showed that sulfuric acid was superior to nitric acid, however, with regard to the yield of activated carbon there was no significant difference between the two activating agents. The degree of dispersion of carbon particles was shown to be relatively high in neutral condition and the produced activated carbon was considered to be effectively employed for the treatment of metal ions in wastewater due to its negative surface charge in aqueous condition.

Synthesis and characterization of Mg-Si thermoelectric compound subjected to mechanical alloying (기계적 합금화에 의한 Mg-Si계 열전화합물의 합성 및 평가)

  • Lee, Chung-Hyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.121-127
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    • 2007
  • We have applied mechanical alloying (MA) to get $Mg_2Si$ thermoelectric material with nano-sized grains. An optimal milling and heat treatment conditions to obtain the single phase of $Mg_2Si$ compound with fine microstructure were investigated by X-ray diffraction and differential scanning calorimetry (DSC) measurement. The $Mg_{66.7}Si_{33.3}$ MA samples ball-milled for $20{\sim}180\;hrs$ exhibit two broad exothermic heat releases around $220^{\circ}C$ and $570^{\circ}C$. On the other hand, MA sample ball-milled far 260 hrs exhibits only a sharp exothermic peak at $230^{\circ}C$ Single phase Mg2Si powder can be obtained by MA of $Mg_{66.7}Si_{33.3}$ mixture for 60 hours and subsequently heated up to $620^{\circ}C$. Sintering of the MA powders was performed in a spark plasma sintering (SPS) machine using graphite dies at $800{\sim}900^{\circ}C$ under 50 MPa. The shrinkage of sintering sample during SPS was significant at about $200^{\circ}C$. All compact bodies have a high relative density above 94% with metallic glare on the surface.

Study on Fiber Laser Annealing of p-a-Si:H Deposition Layer for the Fabrication of Interdigitated Back Contact Solar Cells (IBC형 태양전지 제작을 위한 p-a-Si:H 증착층의 파이버 레이저 가공에 관한 연구)

  • Kim, Sung-Chul;Lee, Young-Seok;Han, Kyu-Min;Moon, In-Yong;Kwon, Tae-Young;Kyung, Do-Hyun;Kim, Young-Kuk;Heo, Jong-Kyu;Yoon, Ki-Chan;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.430-430
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    • 2008
  • Using multi plasma enhanced chemical vapor deposition system (Multi-PECVD), p-a-Si:H deposition layer as a $p^+$ region which was annealed by laser (Q-switched fiber laser, $\lambda$ = 1064 nm) on an n-type single crystalline Si (100) plane circle wafer was prepared as new doping method for single crystalline interdigitated back contact (IBC) solar cells. As lots of earlier studies implemented, most cases dealt with the excimer (excited dimer) laserannealing or crystallization of boron with the ultraviolet wavelength range and $10^{-9}$ sec pulse duration. In this study, the Q-switched fiber laser which has higher power, longer wavelength of infrared range ($\lambda$ = 1064 nm) and longer pulse duration of $10^{-8}$ sec than excimer laser was introduced for uniformly deposited p-a-Si:H layer to be annealed and to make sheet resistance expectable as an important process for IBC solar cell $p^+$ layer on a polished n-type Si circle wafer. A $525{\mu}m$ thick n-type Si semiconductor circle wafer of (100) plane which was dipped in a buffered hydrofluoric acid solution for 30 seconds was mounted on the Multi-PECVD system for p-a-Si:H deposition layer with the ratio of $SiH_4:H_2:B_2H_6$ = 30:120:30, at $200^{\circ}C$, 50 W power, 0.2 Torr pressure for 20 minutes. 15 mm $\times$ 15 mm size laser cut samples were annealed by fiber laser with different sets of power levels and frequencies. By comparing the results of lifetime measurement and sheet resistance relation, the laser condition set of 50 mm/s of mark speed, 160 kHz of period, 21 % of power level with continuous wave mode of scanner lens showed the features of small difference of lifetime and lowering sheet resistance than before the fiber laser treatment with not much surface damages. Diode level device was made to confirm these experimental results by measuring C-V, I-V characteristics. Uniform and expectable boron doped layer can play an important role to predict the efficiency during the fabricating process of IBC solar cells.

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Acute Hydrofluoric Acid Exposure: Our Clinical Experience at Emergency Centers in Two University Teaching Hospitals (2개 대학병원 응급센터에 내원한 급성 불화수소산 노출 환자에 대한 임상적 경험)

  • Han, Kyu-Hong;Yang, Jung-Il;Jo, Seung-Yook;Cho, Yong-Chul;Ryu, Seung;Lee, Jin-Woong;Kim, Seung-Whan;Yoo, In-Sool;You, Yeon-Ho;Park, Jung-Soo
    • Journal of The Korean Society of Clinical Toxicology
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    • v.7 no.2
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    • pp.121-126
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    • 2009
  • Purpose: We investigated the clinical characteristics and demographics of patients who suffered from hydrofluoric acid chemical injury and the mechanism of damage. Methods: We retrospectively reviewed the medical records of patients who were exposed to hydrofluoric acid from March 2004 to March 2009 and who were seen at the emergency centers in two university teaching hospitals. Results: Forty four patients out of 47 patients suffered from chemical burn, while the injuries of the remaining 3 could not be identified by the medical records. A total of 17 hydrofluoric acid chemical injury patients were enrolled during the study period, and their mean age was $29.6{\pm}7.0$. All the patients were accidentally injured by contact with the material and none of them inhaled or ingested the material. Only 6 patients wore appropriate protective equipments and 5 underwent the water irrigation for more than 10 minutes. The most common exposure area was the hand and forearm (70.5%). Less than 1% of all of the patients had their total body surface (TBS) exposed to hydrofluoric acid (mean=0.35%). The mean time interval from calcium gluconate administration to pain relief was $33.6{\pm}8.8$ hours. Conclusion: When exposed to hydrofluoric acid, it is important to wear protective equipment and undergo water irrigation for more than 10 minutes. Pain and skin damage were observed in all the patients. After treatment, we concluded that administration of calcium gluconate and pain killers was successful in relieving pain, and the prognosis was also positive for the admitted and followed up patients when less than 1% of the TBS was exposed.

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Effect of Yield and Quality for Cultivation Type and Mulching Materials on Gastrodia elata Blume (재배방식과 피복재료가 천마의 수량과 품질에 미치는 영향)

  • Kim, Chang Su;Yu, In Young;Kim, Dong Won;Kim, Jong Yeob;Kim, Jeong Man;Lee, Wang Hyu
    • Korean Journal of Plant Resources
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    • v.30 no.1
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    • pp.78-87
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    • 2017
  • This study was compared to outdoor field (OF) and rain shelter greenhouse (RSG) according to cultivation type of Gastrodia elata Blume. Also, the effects of yield and quality for mulching materials in RSG were compared. The yield of G. elata was investigated good merchantable quality, and the quality was investigated hardness, chromaticity, weight loss and the contents of the major functional components. The cultivation of RSG was increased the yield, hardness, gastrodin, and vanillyl alcohol compared to OF, and the weight loss, chromaticity, and ergothioneine were almost equal. Rice straw treatment showed higher than those of the control and other treatments on the yield and hardness. As a result, the yield and the quality of RSG, which can control the soil moisture, were better than that of OF. And the lower the soil moisture content according to the mulching material, the harder the surface and the higher the hardness.

Direct Bonding of SillSiO2/Si3N4llSi Wafer Fairs with a Fast Linear Annealing (선형가열기를 이용한 SillSiO2/Si3N4llSi 이종기판쌍의 직접접합)

  • 이상현;이상돈;송오성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.301-307
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    • 2002
  • Direct bonded SOI wafer pairs with $Si ll SiO_2/Si_3N_4 ll Si$ the heterogeneous insulating layers of SiO$_2$-Si$_3$N$_4$are able to apply to the micropumps and MEMS applications. Direct bonding should be executed at low temperature to avoid the warpage of the wafer pairs and inter-diffusion of materials at the interface. 10 cm diameter 2000 ${\AA}-SiO_2/Si(100}$ and 560 $\AA$- ${\AA}-Si_3N_4/Si(100}$ wafers were prepared, and wet cleaned to activate the surface as hydrophilic and hydrophobic states, respectively. Cleaned wafers were pre- mated with facing the mirror planes by a specially designed aligner in class-100 clean room immediately. We employed a heat treatment equipment so called fast linear annealing(FLA) with a halogen lamp to enhance the bonding of pre mated wafers We kept the scan velocity of 0.08 mm/sec, which implied bonding process time of 125 sec/wafer pairs, by varying the heat input at the range of 320~550 W. We measured the bonding area by using the infrared camera and the bonding strength by the razor blade clack opening method, respective1y. It was confirmed that the bonding area was between 80% and to 95% as FLA heat input increased. The bonding strength became the equal of $1000^{\circ}C$ heat treated $Si ll SiO_2/Si_3N_4 ll Si$ pair by an electric furnace. Bonding strength increased to 2500 mJ/$\textrm{m}^2$as heat input increased, which is identical value of annealing at $1000^{\circ}C$-2 hr with an electric furnace. Our results implies that we obtained the enough bonding strength using the FLA, in less process time of 125 seconds and at lowed annealing temperature of $400^{\circ}C$, comparing with the conventional electric furnace annealing.

Research Trends in Flotation of Waste-plastics and Its Use as Functional Materials (폐플라스틱의 부유선별 및 기능성 소재로의 활용 연구동향)

  • Han, Yosep;Kim, Rina;Hong, Hye-Jin;Park, In-Su;Kim, Dong-Gyun;Kim, Yun Ho;Jeon, Ho-Seok;Chang, Hankwon
    • Resources Recycling
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    • v.29 no.6
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    • pp.15-26
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    • 2020
  • In recent years, there is an increasing interest in environmental friendly treatment of waste-plastics in terms of the generation of microplastics. Accordingly, the recycling of waste-plastics is very important because it provides advantages of volume reduction, mitigation of carbon dioxide emission, and reproduction of value-added products. In particular, in order to recycle the eco-friendly waste-plastics, it is necessary to use a physical separation methods, and among them, flotation separation, which can separate material (i.e., polymer component) in waste-plastics is well known as a very effective separation method in terms of material recycle. Therefore, in this review, the research trend of flotation separation for effective separation of mixture waste-plastics was investigated. In addition, through the reported research results, approaches to use as new functional materials from polymers, which are raw materials for waste-plastics, are summarized.

Phonetic improvement by adjusting the shape of the anterior palate of the maxillary complete denture: a case report (상악 총의치 전방 구개 부위 형태 조정을 통한 발음개선 증례)

  • Yoon, Myeong Ah;Lee, HagYoung;Kim, Jee Hwan
    • The Journal of Korean Academy of Prosthodontics
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    • v.60 no.1
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    • pp.37-43
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    • 2022
  • Patients tend to return to normal pronunciation patterns after fitting new dentures. However, for some patients, it takes a long time to adapt the new complete denture. In this case, the patient came to the hospital at the address of wanting to remake dentures due to wear and tear. After diagnosis through clinical and radiological examination, the maxillary complete denture and mandibular removable partial denture were remade. The patient complained whistling /s/ sound at the first check-up after placement of the new denture. The anterior palatal area of polished surface of the new maxillary complete denture was concave comparing to old denture, and this was the cause of the whistling /s/ sound. A tissue conditioning material was applied to the maxillary complete denture and patient made /s/ sound. The tissue conditioning material was replaced with self-curing type denture base resin, and the patient was immediately satisfied with clear /s/ sound. As an objective assessment, palatogram and speech analytics software was applied. In this case, a patient who received denture treatment complaining of difficulty in pronunciation underwent immediate denture repair, which resulted in patient satisfaction and improved pronunciation through objective evaluation.

Horizontal 2-D Finite Element Model for Analysis of Mixing Transport of Heat Pollutant (열오염 혼합 거동 해석을 위한 수평 2차원 유한요소모형)

  • Seo, Il Won;Choi, Hwang Jeong;Song, Chang Geun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.6B
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    • pp.507-514
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    • 2011
  • A numerical model has been developed by employing a finite element method to simulate the depth-averaged 2-D dispersion of the heat pollutant, which is an important pollutant material in natural streams. Among the finite element methods, the Streamline Upwind/Petrov Galerkin (SUPG) method was applied. Also both linear and quadratic elements can be applied so that irregular river boundaries can be easily represented. To show the movement of heat pollutants, the reaction term describing heat transfer was represented as an equation in which sink/source term is proportional to the difference between the equilibrium temperature and water surface temperature. The equation was expressed so that the water surface temperature changes according to the temperature transfer coefficient and the equilibrium temperature. For the calibration of the model developed, analytic and numerical results from a case of rectangular channel with full width continuous injection have been compared in a steady state. The comparisons showed that the numerical results were in good agreement with analytical solutions. The application site was selected from the downstream of Paldang dam to Jamsil submerged weir, and overall length of this site is about 22.5 km. The change of water temperature caused by the discharge from the Guri sewage treatment plant has been simulated, and results were similar to the observed data. Overall it is concluded that the developed model can represent the water temperature changes due to heat transport accurately. But the verification using observed data will further enhance the validity of the model.

A COMPARATIVE STUDY ON THE SHEAR BOND STRENGTH OF DICOR AND G-CERA PORCELAIN LAMINATE VENEER (DICOR와 G-CERA PORCELAIN LAMINATE VENEER의 전단결합강도에 관한 비교연구)

  • Cho Mi-Sook;Yang Jae-Ho;Lee Sun-Hyung
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.3
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    • pp.33-41
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    • 1991
  • Cermic has been widely used because of its excellent esthetics and strength. The recently introduced castable ceramic system is regarded as the more esthetic and biocompatible restorative material. The purpose of this study was to compare the shear bond strength of Dicer & G-Cera porcelain laminate veneer according to the type of cement and surface treatment and to observe the surface of bonding failure with SEM. Total forty disks(3.5mm $diam.\times2.0mm$ thickness) were prepared. Forty extracted human maxillary central incisor teeth were stored in saline solution. Ten teeth were bonded to Dicer specimen with Dicer ZPC cement and ten teeth were bonded with Dicer resin cement. Ten silicoated G-Cera specimen and ten non-silicoated G-Cera specimen were bonded to teeth with G-Cera resin cement. Bonded units were mounted in a plastic tube with hard stone and stored in a humidor at $37^{\circ}C$ for 24 hours. Shear bond strength was measured by Instron Universal Testing Machine (Model 1125) and all the specimen were observed with SEM(JEOL, JSM-T2000)and modes of failure were recorded. The obtained results were as follows: 1. The mean shear bond strength of Dicer bonded with Dicer resin cement was 11.62 MPa and that bonded with Dicor ZPC cement was 0.88 MPa : Shear bond strength of Dicer bonded with Dicer resin cement was significantly increased(P<0.05). 2. The mean shear bond strength of silicoated G-Cera was 13.10 MPa and that of non silicoated G-Cera was 10.93 MPa : Shear bond strength of silicoated G-Cera was not significantly increased (P>0.05). 3. Shear bond strength of Dicer and G-Cera porcelain laminate veneer was not significantly different (P>0.05). 4. In observation of bond failure with SEM, Dicer bonded with Dicer ZPC cement exhibited adhesive failure. Dicer bonded with Dicer resin cement and silicoated and non silicoated G-Cera exhibited cohesive failure.

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